(o-aminophenyl)diazomethane | 148291-93-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (o-aminophenyl)diazomethane
• 英文别名: 2-(diazomethyl)phenylamine；2-[(E)-diazomethyl]aniline
• CAS: 148291-93-4
• 化学式: C₇H₇N₃
• 分子量: 133.153
• InChiKey: OGTCXJWDNDLBAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (o-aminophenyl)diazomethane 生成 6-Methylene-2,4-cyclohexadien-1-imine
  参考文献：
  名称：

  Matrix isolation of a reactive o-quinoid compound - 6-methylene-2,4-cyclohexadien-1-imine

  摘要：

  Photolysis of (o-aminophenyl)diazomethane (5) in argon at 10 K or flash vacuum pyrolysis of o-aminobenzylalcohol (2) with subsequent trapping in solid argon produces mixtures of 6-methylene-2,4-cyclohexadien-1-imine (1) and benzazetine (3) in ratios depending on the experimental conditions.

  DOI：

  10.1016/s0040-4039(00)91961-0
• 作为产物：
  描述：

  2-aminobenzaldehyde tosylhydrazone 在 甲基锂 作用下， 生成 (o-aminophenyl)diazomethane
  参考文献：
  名称：

  Intramolecular Hydrogen Transfer in (2-Aminophenyl)carbene and 2-Tolylnitrene. Matrix Isolation of 6-Methylene-2,4-cyclohexadien-1-imine

  摘要：

  Flash vacuum pyrolysis (FVP) or matrix photolysis of 2-(diazomethyl)phenylamine, 1-azido-2-methylbenzene (2-tolyl azide), o-aminobenzyl alcohol, or 2-indolinone provide entries into the C7H7N hypersurface. The matrix-isolated (argon, 10 K products have been characterized by IR and UV-vis spectroscopy in combination with high level (MP2/6-31G(d) and HF/6-31G(d,p)) ab-initio calculations. FVP (500-800 degrees C) of the first three of these precursors produces high yields of E/Z-mixture s of 6-methylene-2,4-cyclohexadien-1-imine (o-iminoquinone methide), while the bicyclic isomer benzoazetine is not formed under these conditions. FVP of 2-tolyl azide at very high temperatures (> 900 degrees C) leads to the formation of benzaldimine and benzonitrile, Photolysis of the matrix-isolated precursors allows one to selectively generate the E- and Z-isomer of the iminoquinone methide as well as benzoazetine. In addition, 2-tolylnitrene and 1-aza-3-methyl-1,2,4,6-cycloheptatetraene are produced as intermediates in the photolysis of 2-tolyl azide. The nitrene is thermally stable up to 80 K (in xenon matrix), although the hydrogen migration to give (E)-o-iminoquinone methide is calculated to be exothermic by 42 kcal/mol. Irradiation of 2-(diazomethyl)phenylamine directly yields the quinone methide while io-aminophenyl)carbene, which is the most reasonable intermediate, is not observed.

  DOI：

  10.1021/jo00125a024

文献信息

• A FULLY BONDED SINGLE-LAYER WATERBAR
  申请人：SIKA TECHNOLOGY AG

  公开号：EP3926116A1

  公开（公告）日：2021-12-22

  The invention is directed to a method for producing a single-layer waterbar, the method comprising extruding a melt-processed starting composition through an extruder die to form an extruded profile, wherein the starting composition comprises 35 - 75 wt.-% of at least one polymer and 25 - 65 wt.-% of at least one solid particulate filler. The invention also relates to use of a single-layer extruded profile as a waterbar, to a method for sealing an internal or an external joint between two sections of concrete, and to a sealed construction.

  本发明涉及一种生产单层水条的方法，该方法包括将熔融加工的起始组合物通过挤出机模头挤出以形成挤出型材，其中起始组合物包括 35 - 75 wt.-% 的至少一种聚合物和 25 - 65 wt.-% 的至少一种固体颗粒填料。本发明还涉及将单层挤压型材用作防水条、密封两段混凝土之间的内部或外部接缝的方法以及密封结构。
• Manufacturing process and composition for foamed PVC-P rock shields
  申请人：SIKA TECHNOLOGY AG

  公开号：US10344157B2

  公开（公告）日：2019-07-09

  A plasticized PVC formulation for foam extrusion including polyvinyl chloride, at least one plasticizer, at least one nucleating agent and a chemical blowing agent, wherein the plasticized PVC formulation is a dry blend containing 0.5 to 5% by weight of one or more nucleating agents and 0.1 to 3% by weight of the chemical blowing agent, wherein the blowing agent is sodium bicarbonate and the nucleating agent is talcum, and a foam extrusion method using said formulation. The extruded plasticized PVC foam is particularly suitable for rock shield pads used for pipeline protection. The foams are lightweight and require less consumption of materials with comparable properties to corresponding solid articles.

  一种用于挤出泡沫塑料的增塑聚氯乙烯配方，包括聚氯乙烯、至少一种增塑剂、至少一种成核剂和一种化学发泡剂，其中增塑聚氯乙烯配方是一种干混料，含有 0.5%至 5%（按重量计）的一种或多种成核剂和 0.1%至 3%（按重量计）的化学发泡剂，其中发泡剂为碳酸氢钠，成核剂为滑石粉，以及一种使用所述配方的泡沫塑料挤出方法。挤压塑化聚氯乙烯泡沫特别适用于用于保护管道的岩石防护垫。这种泡沫重量轻，所需的材料消耗少，性能与相应的固体物品相当。
• Contact layer with a solid filler component
  申请人：SIKA TECHNOLOGY AG

  公开号：US10655323B2

  公开（公告）日：2020-05-19

  A contact layer used in waterproofing and roofing applications. The contact layer includes a solid filler component F and a thermoplastic polymer component P. Also directed to a method for producing the contact layer, to a method for binding two substrates to each other, to a method for waterproofing a substrate, to a waterproofed structure, to a method for sealing a surface against water penetration, to a sealed construction for sealing a substrate against water penetration and to use of the contact layer as waterproofing membrane.

  一种用于防水和屋顶应用的接触层。该接触层包括固体填料成分 F 和热塑性聚合物成分 P。还涉及生产该接触层的方法、将两种基材相互结合的方法、基材防水方法、防水结构、密封表面防止水渗透的方法、密封基材防止水渗透的密封结构以及将该接触层用作防水卷材。
• Diisopentyl terephthalate
  申请人：Evonik Degussa GmbH

  公开号：US10787414B2

  公开（公告）日：2020-09-29

  A mixture of isomeric dipentyl terephthalates, pentyl radicals of which are n-pentyl radicals to an extent of less than 60 mol %, characterized by a low viscosity which does not increase significantly even at temperatures below 40° C. Plastisols comprising these mixtures have a low plastisol viscosity which moreover increases only to a minor degree with time.

  一种对苯二甲酸二戊酯异构体混合物，其中的戊基是正戊基，含量小于 60 摩尔%，其特点是粘度低，即使在低于 40°C 的温度下也不会显著增加。
• Manufacturing process and composition for foamed PVC-p rock shields
  申请人：SIKA TECHNOLOGY AG

  公开号：US10920058B2

  公开（公告）日：2021-02-16

  A plasticized PVC formulation for foam extrusion including polyvinyl chloride, at least one plasticizer, at least one nucleating agent and a chemical blowing agent, wherein the plasticized PVC formulation is a dry blend containing 0.5 to 5% by weight of one or more nucleating agents and 0.1 to 3% by weight of the chemical blowing agent, wherein the blowing agent is sodium bicarbonate and the nucleating agent is talcum, and a foam extrusion method using said formulation. The extruded plasticized PVC foam is particularly suitable for rock shield pads used for pipeline protection. The foams are lightweight and require less consumption of materials with comparable properties to corresponding solid articles.

  一种用于挤出泡沫塑料的增塑聚氯乙烯配方，包括聚氯乙烯、至少一种增塑剂、至少一种成核剂和一种化学发泡剂，其中增塑聚氯乙烯配方是一种干混料，含有 0.5%至 5%（按重量计）的一种或多种成核剂和 0.1%至 3%（按重量计）的化学发泡剂，其中发泡剂为碳酸氢钠，成核剂为滑石粉，以及一种使用所述配方的泡沫塑料挤出方法。挤压塑化聚氯乙烯泡沫特别适用于用于保护管道的岩石防护垫。这种泡沫重量轻，所需的材料消耗少，性能与相应的固体物品相当。