cis-[PtClMe(triphenylphosphine)2] | 15278-39-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-[PtClMe(triphenylphosphine)2]
• 英文别名: cis-[PtClMe(PPh3)2]；cis-Pt(Me)Cl(triphenylphosphine)2；cis-[platinum(II)chloride(methyl)(PPh3)2]；carbanide;chloroplatinum(1+);triphenylphosphane
• CAS: 15278-39-4
• 化学式: C₃₇H₃₃ClP₂Pt
• 分子量: 770.15
• InChiKey: BVIPIYHHLNXGFX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[PtClMe(triphenylphosphine)2] 、 2-((diphenylphosphino)amido)pyridine 以 二氯甲烷 为溶剂， 以88%的产率得到cis-[PtMe(2-(diphenylphosphinoamino)pyridine-P,N)(PPh3)]Cl
  参考文献：
  名称：

  The co-ordination chemistry of 2-(diphenylphosphinoamino)pyridine †

  摘要：

  2-(二苯膦氨基)吡啶，dppap [Ph2PNHpy]，以及超过40个示例性的其配合物已被制备。在一系列钯、铂和金配合物中，示例了中性（以及双齿去质子化配体）的单齿、双齿和桥联配位方式。十个示范性例子通过单晶X射线衍射进行了表征。Ph2PNHpy以氢键结合的二聚体对形式存在；cis-[PtCl(Ph2PNHpy-P,N){Ph2PNHpy-P}]Cl通过氢键形成无限链；cis-[Pt(Ph2PNpy-P,N)2]和cis-[Pd(Ph2PNpy-P,N)2]是同构的。cis-[Pd(Ph2PNHpy-P,N)2][BF4]2、[AuCl(Ph2PNHpy-P)]、[Pt(C8H12OMe)(Ph2PNpy-P,N)]·H2O展示了氢键结合，cis-[PtCl(Ph2PNHpy-P,N)(PMe3)]Cl、cis-[PtCl(Ph2PNpy-P,N)(PMe3)]和cis-[PtCl(Ph2PNHpy-P,N)(P(OPh)3)]Cl的结构也被报道。

  DOI：

  10.1039/b003294h
• 作为产物：
  描述：

  [(1,5-cyclooctadiene)Pt(Me)Cl] 、 三苯基膦 以 氘代氯仿 为溶剂， 生成 trans-chloro(methyl)bis(triphenylphosphine)platinum(II) 、 cis-[PtClMe(triphenylphosphine)2]
  参考文献：
  名称：

  Cobley, Christopher J.; Pringle, Paul G., Inorganica Chimica Acta, 1997, vol. 265, # 1-2 PART II, p. 107 - 115

  摘要：

  DOI：

文献信息

• Structure and solution behaviour of cyclooctadiene complexes of platinum(II)
  作者：Stefanus Otto

  DOI：10.1016/j.ica.2010.06.020

  日期：2010.10

  The substitution behaviour of [PtCl(R)(COD)] (R- = Me and Fc) complexes, by the stepwise addition of phosphine ligands, L (L = PPh3, PEt3 and P(NMe2)(3)), were investigated in situ by H-1 and P-31 NMR spectroscopy. Addition of less than two equivalents of the phosphine ligand results in the formation of dimeric molecules with the general formula trans-[Pt(R)(mu-Cl)(L)](2) for the sterically demanding systems where R- = Me/L = P(NMe2)(3) and R- = Fc/L = PEt3, PPh3 and P(NMe2)(3) while larger quantities resulted in cis-and trans mixtures of mononuclear complexes being formed. In the case of the relatively small steric demanding, strongly coordinating, PEt3 ligand the trans-[PtCl(R)(PEt3)(2)] mononuclear complexes were exclusively observed in both cases. The crystal structures of the two substrates, [PtCl(R)(COD)] (R- = Me or Fc), as well as the cis-[PtCl(Fc)(PPh3)(2)] substitution product are reported. (C) 2010 Elsevier B.V. All rights reserved.