9,10-dibromo-2,7-di-tert-butylanthracene | 332083-46-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-dibromo-2,7-di-tert-butylanthracene
• 英文别名: 2,7-di-t-butyl-9,10-dibromoanthracene；9,10-Dibromo-2,7-ditert-butylanthracene
• CAS: 332083-46-2
• 化学式: C₂₂H₂₄Br₂
• 分子量: 448.241
• InChiKey: VLCAGKYAJTUNNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9,10-dibromo-2,7-di-tert-butylanthracene 、 2,6-二叔丁基-9,10-二溴蒽 、 2-(4-溴苯基)-1,1-二苯基乙烯 在 碘 、 bis-triphenylphosphine-palladium(II) chloride magnesium 、 二异丁基氢化铝 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 1.5h， 生成 9,10-bis[4-(2,2-diphenylethenyl)phenyl]-2,7-di-t-butylanthracene 、 9,10-bis[4-(2,2-diphenylethenyl)phenyl]-2,6-di-t-butylanthracene
  参考文献：
  名称：

  NOVEL SOLUBLE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICES

  摘要：

  一种新型可溶性化合物，是一种具有可溶性取代基和特定中心基团的二亚基芳烃衍生物，在有机溶剂中在20°C时的溶解度为0.5%或更高；以及具有有机薄膜层的有机电致发光器件，该有机薄膜层具有单层或多层，位于阴极和阳极之间，并且至少包含一层含有该新型可溶性化合物。有机薄膜层可以根据湿法工艺形成，可以轻松生产出具有良好发光效率的有机电致发光器件。

  公开号：

  EP1440959A1
• 作为产物：
  描述：

  2,7-di-tert-butylanthracene 在 iron(III) chloride 、 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 反应 3.0h， 以85%的产率得到9,10-dibromo-2,7-di-tert-butylanthracene
  参考文献：
  名称：

  Functionalization of boron-doped tri(9,10-anthrylene)s

  摘要：

  9,10-Dianthryl-9,10-dihydro-9,10-diboraanthracene derivatives bearing two peripheral chloro (3) or bromo (5) substituents have been synthesized. X-ray crystallography reveals a mutually perpendicular orientation of the individual planes within each of the molecules. The two bromo substituents in 5 can be replaced by NMe2 (6) or thiophen-2-yl (7) groups using Me3Sn-NMe2 or nBu(3)Sn-C4H3S and Pd-mediated C-N or C-C coupling protocols. Compounds 3, 5, and 7 show TICT photoluminescence and a pronounced positive solvatochromism in agreement with a charge-separated excited state. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.06.036

文献信息

• Novel soluble compound and organic electroluminescent devices
  申请人：Hosokawa Chishio

  公开号：US20080160344A1

  公开（公告）日：2008-07-03

  A novel soluble compound which is a distyrylarylene derivative having a soluble substituent and a specific central group and having a solubility of 0.5% by weight or greater at 20° C. in an organic solvent; and an organic electroluminescence device having an organic thin film layer which has a single layer or a plurality of layers, is disposed between a cathode and an anode and has at least one layer containing the novel soluble compound. The organic thin film layer can be formed in accordance with a wet process, and the organic electroluminescence device exhibiting a great efficiency of light emission can be produced easily.

  本发明提供一种新型可溶性化合物，其为一种含有可溶性取代基和特定中心基团的二苯乙烯衍生物，其在20℃的有机溶剂中具有0.5%或更高的溶解度；以及一种有机电致发光器件，其具有一个有机薄膜层，该有机薄膜层具有单层或多层，位于阴极和阳极之间，并且至少包含一层含有新型可溶性化合物的层。该有机薄膜层可以通过湿法工艺形成，可以轻松地制备出具有较高发光效率的有机电致发光器件。
• US7357991B2
  申请人：——

  公开号：US7357991B2

  公开（公告）日：2008-04-15
• US7670506B1
  申请人：——

  公开号：US7670506B1

  公开（公告）日：2010-03-02
• NOVEL SOLUBLE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1440959A1

  公开（公告）日：2004-07-28

  A novel soluble compound which is a distyrylarylene derivative having a soluble substituent and a specific central group and having a solubility of 0.5% by weight or greater at 20°C in an organic solvent; and an organic electroluminescence device having an organic thin film layer which has a single layer or a plurality of layers, is disposed between a cathode and an anode and has at least one layer containing the novel soluble compound. The organic thin film layer can be formed in accordance with a wet process, and the organic electroluminescence device exhibiting a great efficiency of light emission can be produced easily.

  一种新型可溶性化合物，是一种具有可溶性取代基和特定中心基团的二亚基芳烃衍生物，在有机溶剂中在20°C时的溶解度为0.5%或更高；以及具有有机薄膜层的有机电致发光器件，该有机薄膜层具有单层或多层，位于阴极和阳极之间，并且至少包含一层含有该新型可溶性化合物。有机薄膜层可以根据湿法工艺形成，可以轻松生产出具有良好发光效率的有机电致发光器件。
• Functionalization of boron-doped tri(9,10-anthrylene)s
  作者：Claas Hoffend、Kai Schickedanz、Michael Bolte、Hans-Wolfram Lerner、Matthias Wagner

  DOI：10.1016/j.tet.2013.06.036

  日期：2013.8

  9,10-Dianthryl-9,10-dihydro-9,10-diboraanthracene derivatives bearing two peripheral chloro (3) or bromo (5) substituents have been synthesized. X-ray crystallography reveals a mutually perpendicular orientation of the individual planes within each of the molecules. The two bromo substituents in 5 can be replaced by NMe2 (6) or thiophen-2-yl (7) groups using Me3Sn-NMe2 or nBu(3)Sn-C4H3S and Pd-mediated C-N or C-C coupling protocols. Compounds 3, 5, and 7 show TICT photoluminescence and a pronounced positive solvatochromism in agreement with a charge-separated excited state. (C) 2013 Elsevier Ltd. All rights reserved.