Octylimino-cyclohexan | 6114-65-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Octylimino-cyclohexan
• CAS: 6114-65-4
• 化学式: C₁₄H₂₇N
• 分子量: 209.375
• InChiKey: LLPOSFBHNUAHAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.75
• 重原子数：
  15.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  Octylimino-cyclohexan 在 bis(η5-cyclopentadinyl)dihydridomolybdenum ytterbium(III) triflate 作用下， 以 甲苯 为溶剂， 反应 92.0h， 以40%的产率得到N-n-octylcyclohexylamine
  参考文献：
  名称：

  Reductions of CO and CN groups with the systems composed of (η5-C5H5)2MoH2 and acids

  摘要：

  Selective reductions of organic compounds, such as carbonyl compounds and imines, using a system composed of Cp2MoH2 and acids are examined. This system can reduce the substrates under mild conditions. Extremely high diastereoselectivity was achieved in the reduction of 4-t-butylcyclohexanone. The reactivity of imines depends on their structure. Aromatic imines are found to be more reactive than aliphatic imines. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00782-7
• 作为产物：
  描述：

  辛胺 、 环己酮 在 氢氧化钾 作用下， 生成 Octylimino-cyclohexan
  参考文献：
  名称：

  Mayer,R. et al., Journal fur praktische Chemie (Leipzig 1954), 1966, vol. 31, p. 312 - 319

  摘要：

  DOI：

文献信息

• SYNTHESIS OF SOME NEW CYCLIC AMINOPHOSPHONATES AND THEIR PHYSIOLOGICAL ACTIVITIES
  作者：J. S. Wieczorek、R. Gancarz、K. Bielecki、E. Grzyś、J. Sarapuk

  DOI：10.1080/10426500108040237

  日期：2001.8.1

  The synthesis of 19 newly synthesized cyclic aminophosphonic acid derivatives was described and their biological activity studied. It was found, as in the case of the previously described series of acyclic analogues, that the phytotoxicity of the compounds, tested on aquatic plant Spirodela oligorrhiza depended mainly on their hydrophobic parameters. The most pronounced phytotoxicity, the measure of which was concentration of aminophosphonates causing 50% inhibition of plant growth (EC50), exhibited compounds with not too long hydrocarbon substituent on the nitrogen atom (8-10 carbon atoms) and branched propyl groups on the phosphorus atom. The test had preliminary character and permitted to eliminate the less promising compounds for further studies.