<2-(diphenylphosphino)phenyl>dimethylphosphine | 153041-64-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: <2-(diphenylphosphino)phenyl>dimethylphosphine
• 英文别名: (2-Dimethylphosphanylphenyl)-diphenylphosphane
• CAS: 153041-64-6
• 化学式: C₂₀H₂₀P₂
• 分子量: 322.326
• InChiKey: GDWVYEJMRVYEER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(1,2-diphenylethylene-1,2-ditholate) nickel(IV) 、 <2-(diphenylphosphino)phenyl>dimethylphosphine 以 not given 为溶剂， 以26%的产率得到{Ni(1,2-diphenylethene-1,2-dithiolato(2-)-S,S')(C6H4(PMe2)(PPh2)-1,2)}
  参考文献：
  名称：

  镍叔膦配合物的电化学，电子自旋共振和核磁共振研究。第1部分。单核和二核二硫镍镍和二卤化镍物质

  摘要：

  合成，表征和31个[镍{S的P NMR参数2 Ç 2（CN）2 }（PR 3）2 ]（PR 3 = PMePh 2或PBU Ñ博士2）和[{的Ni（S 2 c ^ 2 R 2）（L–L）} n ]络合物（L–L =含有亚乙烯基或邻亚苯基间磷键的二叔膦，n = 1或2，R = CN或Ph）。[{Ni（S 2 C 2 R 2）（L–L）}}的31 P NMR数据n ]配合物表明，环对化学位移的贡献很大，单核物种为正（n= 1），双核物种接近零或为负（n= 2）。配合物的电化学研究及其电生成产物的ESR研究表明，由于（i）配位环大小，（ii）磷间键合和（iii）磷取代基的变化，电化学和ESR参数也发生了变化。氧化还原产物的ESR光谱标识为[Ni {S 2 C 2（CN） 2 } {C 6 H 4（PMePh）（PPh 2）-1,2}}。+表现出两个化学上不等价的31 P核。双核配合物（ n =

  DOI：

  10.1039/dt9930003593
• 作为产物：
  描述：

  二甲基苯基磷 、 (2-chlorophenyl)diphenylphosphine 在 sodium 作用下， 生成 <2-(diphenylphosphino)phenyl>dimethylphosphine
  参考文献：
  名称：

  Bowmaker, Graham A.; Williams, Julian P., Australian Journal of Chemistry, 1994, vol. 47, # 3, p. 451 - 460

  摘要：

  DOI：

文献信息

• Material for organic electroluminescent elements, and organic electroluminescent element using same
  申请人：NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.

  公开号：US10283721B2

  公开（公告）日：2019-05-07

  Disclosed are an organic electroluminescent device (organic EL device) having improved luminous efficiency, sufficiently secured driving stability, and a simple construction, and a material for an organic EL device. The material for an organic EL device includes a carborane compound having a structure in which at least one carborane ring and at least one dibenzothiophene ring are present, and the at least one carborane ring is bonded to the at least one dibenzothiophene ring at position 1, 2, or 3. In addition, the organic EL device includes, between an anode and a cathode laminated on a substrate, at least one organic layer, in which the at least one organic layer includes the carborane compound.

  揭示了一种具有改善发光效率、充分保证驱动稳定性和简单结构的有机电致发光器件（有机EL器件），以及有机EL器件的材料。用于有机EL器件的材料包括一种碳硼烷化合物，其结构中至少存在一个碳硼烷环和至少一个二苯并噻吩环，且至少一个碳硼烷环与至少一个二苯并噻吩环在1、2或3位置上结合。此外，有机EL器件在衬底上层叠的阳极和阴极之间包括至少一个有机层，其中至少一个有机层包括碳硼烷化合物。
• METHOD FOR PRODUCING PHOSPHINOBENZENE BORANE DERIVATIVE, METHOD FOR PRODUCING 1,2-BIS(DIALKYLPHOSPHINO)BENZENE DERIVATIVE, AND TRANSITION METAL COMPLEX
  申请人：Nippon Chemical Industrial Co., Ltd.

  公开号：US20210155641A1

  公开（公告）日：2021-05-27

  A method for producing a phosphinobenzene borane derivative comprises a reaction step (A) of obtaining liquid A containing a 1,2-dihalogenobenzene represented by the following general formula (1): obtaining liquid B containing a phosphine borane compound obtained by deprotonating a hydrogen-phosphine borane compound represented by the following general formula (2): and then adding the liquid B to the liquid A to be allowed to react to thereby obtain the phosphinobenzene borane derivative represented by the following general formula (3): According to the present invention, there can be provided the industrially advantageous method for producing the phosphinobenzene borane derivative.