1-phenyl-1,2-diacetoxy-3-octene | 1346745-34-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-1,2-diacetoxy-3-octene
• CAS: 1346745-34-3
• 化学式: C₁₈H₂₄O₄
• 分子量: 304.386
• InChiKey: FIXFMLHBGJWESF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.97
• 重原子数：
  22.0
• 可旋转键数：
  8.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  52.6
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  1-phenyl-1,2-diacetoxy-3-octene 在 RhBi₄/C 、 溶剂黄146 作用下， 100.0 ℃ 、8.0 MPa 条件下， 反应 40.0h， 以36.4%的产率得到1-phenyl-3,4-diacetoxy-1-octene
  参考文献：
  名称：

  Positional and geometric isomerization of diacetoxy derivatives of 1-phenyl-1(2)-octenes

  摘要：

  Isomerization of 1,2-, 3,4-, and 1,4-diacetoxy derivatives of 1-phenyl-1(2)-octenes in the presence of Pd(3)Sb/C and/or RhBi(4)/C as catalysts was studied. The kinetic and thermodynamic characteristics of the reaction were evaluated.

  DOI：

  10.1134/s1070427211090175
• 作为产物：
  描述：

  1-phenyl-3,4-diacetoxy-1-octene 在 Pd₃Sb/C 、 溶剂黄146 作用下， 100.0 ℃ 、8.0 MPa 条件下， 反应 40.0h， 以34.1%的产率得到1-phenyl-1,2-diacetoxy-3-octene
  参考文献：
  名称：

  Positional and geometric isomerization of diacetoxy derivatives of 1-phenyl-1(2)-octenes

  摘要：

  Isomerization of 1,2-, 3,4-, and 1,4-diacetoxy derivatives of 1-phenyl-1(2)-octenes in the presence of Pd(3)Sb/C and/or RhBi(4)/C as catalysts was studied. The kinetic and thermodynamic characteristics of the reaction were evaluated.

  DOI：

  10.1134/s1070427211090175

文献信息

• Catalytic oxidative acetoxylation of octa-1,3-dienylbenzene
  作者：A. S. Grisha、A. V. de Vekki

  DOI：10.1134/s1070427211070135

  日期：2011.7

  Acetoxylation of octa-1,3-dienylbenzene in glacial acetic acid in the presence of catalysts with intermetallic phases based on Pd and Rh and Group IIIA-VIA elements was studied. The relationship between the total selectivity of the reaction with respect to diacetoxy derivatives and the Aller-Rochow electronegativity of second modifying elements was examined. The most efficient catalytic systems were determined.