3-Hexyl-2-methylthiophene | 949030-50-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 3-Hexyl-2-methylthiophene
• CAS: 949030-50-6
• 化学式: C₁₁H₁₈S
• 分子量: 182.33
• InChiKey: YMFSMRXRGBLGQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-Hexyl-2-methylthiophene 、 羟基甲苯磺酰碘苯 在 potassium bromide 作用下， 以 甲醇 、 水 为溶剂， 生成 Bromo-(4-hexyl-5-methylthiophen-2-yl)-phenyl-lambda3-iodane
  参考文献：
  名称：

  由单电子转移氧化过程引发的二芳基溴化铵异常的ipso取代

  摘要：

  芳族取代：用芳族亲核试剂2处理溴化二芳基碘鎓1，可以得到各种含杂芳基的联芳基3，收率很高。在本位在杂芳基环3'-取代过程1通过芳族阳离子基团，其由单电子转移（SET）氧化引发的形成发生2。（HFIP =六氟异丙醇）

  DOI：

  10.1002/anie.200907281

文献信息

• PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, DYE-ADSORBED ELECTRODE, AND METHOD FOR PRODUCING DYE-SENSITIZED SOLAR CELL
  申请人：FUJIFILM Corporation

  公开号：US20150248969A1

  公开（公告）日：2015-09-03

  A photoelectric conversion element, having a photoconductor layercontaining semiconductor fine particles carrying a metal complex dye of Formula (I); a metal complex dye, a dye solution, a dye-adsorbed electrode, a dye-sensitized solar cell, and a method for producing the solar cell: M ( LA )( LD )( LX ) mX ·( CI ) mY Formula (I) M represents a metal ion, LA represents a ligand of Formula (AL), LD represents a bidentate or tridentate ligand, at least one of coordinating atoms being an anion; LX represents a monodentate ligand; CI represents a counter ion; mX is 0 or 1; mY is 0 to 3; Rings A to C represent a heterocycle; Z 1 and Z 2 represent a carbon or nitrogen atom; Anc1 to Anc3 represent an acidic group; X 1 to X 3 represent a single bond or linking group; R 1 to R 3 represent a substituent; l1, l3, l2, m1, m3, m2, n1, n2, and n3 each are an integer.

  一种光电转换元件，具有包含携带公式（I）金属络合染料的半导体细粒子的光电导层；一种金属络合染料，染料溶液，染料吸附电极，染料敏化太阳能电池，以及生产太阳能电池的方法：M（LA）（LD）（LX）mX·（CI）mY公式（I）中，M代表金属离子，LA代表公式（AL）的配体，LD代表双齿或三齿配体，至少一个配位原子是阴离子；LX代表单齿配体；CI代表计数离子；mX为0或1；mY为0到3；环A到C代表杂环；Z1和Z2代表碳或氮原子；Anc1到Anc3代表酸性基团；X1到X3代表单键或连接基团；R1到R3代表取代基；l1、l3、l2、m1、m3、m2、n1、n2和n3各自为整数。
• CATHODE CATALYST FOR AIR SECONDARY BATTERY AND AIR SECONDARY BATTERY
  申请人：Koshino Nobuyoshi

  公开号：US20140066290A1

  公开（公告）日：2014-03-06

  The present invention provides a cathode catalyst for an air secondary cell having both excellent oxygen reduction activity and excellent water oxidation activity, and an air secondary cell that uses the catalyst. The present invention relates to a cathode catalyst for an air secondary cell in which the catalyst contains a polynuclear metal complex.

  本发明提供了一种空气二次电池的阴极催化剂，具有优异的氧还原活性和优异的水氧化活性，并且使用该催化剂的空气二次电池。本发明涉及一种空气二次电池的阴极催化剂，其中该催化剂包含多核金属配合物。
• METAL COMPLEX DYE, PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, DYE ADSORPTION LIQUID COMPOSITION FOR DYE-SENSITIZED SOLAR CELL, SEMICONDUCTOR ELECTRODE FOR DYE-SENSITIZED SOLAR CELL, AND METHOD FOR PRODUCING DYE-SENSITIZED SOLAR CELL
  申请人：Fujifilm Corporation

  公开号：EP2826821A1

  公开（公告）日：2015-01-21

  A metal complex dye represented by the following formula (I), photoelectric conversion element, and dye-sensitized solar cell.         M(LD)(LA)·(Y)mY     formula (I) wherein, in formula (I), M represents Fe2+, Ru2+ or Os2+; LD represents a tridentate ligand represented by the following formula (A); LA represents a specific tridentate ligand wherein three cyclic coordinating groups different from LA are linked; wherein, in formula (A), Ar1 and Ar2 each independently represent specific heterocyclic groups such as a benzene ring group or a triazole ring group or the like. Y represents a counter ion required for neutralizing an electric charge, and mY represents an integer of 0 to 2.

  由下式（I）表示的金属络合染料、光电转换元件和染料敏化太阳能电池。 M(LD)(LA)-(Y)mY式（I） 其中，在式 (I) 中，M 代表 Fe2+、Ru2+ 或 Os2+； LD 代表下式（A）所代表的三叉配体； LA 代表一种特定的三叉配体，其中连接有三个不同于 LA 的环状配位基团； 其中，在式 (A) 中，Ar1 和 Ar2 各自独立地代表特定的杂环基团，例如苯环基团或三唑环基团或类似基团。Y 代表中和电荷所需的反离子，mY 代表 0 至 2 的整数。
• PHOTOELECTRIC CONVERSION ELEMENT AND DYE-SENSITIZED SOLAR CELL
  申请人：FUJI-FILM Corporation

  公开号：EP2903077A1

  公开（公告）日：2015-08-05

  A photoelectric conversion element includes a conductive substrate, a photosensitive layer containing an electrolyte, a charge transfer layer containing an electrolyte, and a counter electrode, in which the photosensitive layer contains semiconductor particles loaded with a metal complex dye represented by the following Formula (1). A dye-sensitized solar cell uses the photoelectric conversion element.         M(LD)(LA)(X)m·CI     Formula (1) In the formula (1), M represents a divalent or trivalent metal ion; LD represents a bidentate or tridentate ligand having an aryl group or an heterocyclic group; and the ligand has 1 to 3 atoms that are coordinated with M by becoming an anion. LA represents a tridentate ligand represented by a specific formula; X represents a monodentate ligand; CI represents a counter ion necessary for neutralizing a charge; and m represents 0 or 1.

  一种光电转换元件包括导电基板、含有电解质的光敏层、含有电解质的电荷转移层和对电极，其中光敏层含有装有下式（1）表示的金属络合染料的半导体颗粒。染料敏化太阳能电池使用光电转换元件。 M(LD)(LA)(X)m-CI 公式 (1) 式（1）中，M 代表二价或三价金属离子；LD 代表具有芳基或杂环基的双叉或三叉配体；配体具有 1 至 3 个原子，通过成为阴离子与 M 配位。LA 代表由特定式子表示的三叉配体；X 代表单齿配体；CI 代表中和电荷所需的反离子；m 代表 0 或 1。
• METAL COMPLEX DYE, PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, DYE SOLUTION, AND DYE-ADSORBED ELECTRODE
  申请人：FUJIFILM Corporation

  公开号：EP2903078A1

  公开（公告）日：2015-08-05

  A photoelectric conversion element, containing: an electrically conductive support, a photoconductor layer containing an electrolyte, a charge-transfer layer containing an electrolyte, and a counter electrode; wherein the photoconductor layer contains semiconductor fine-particles carrying a metal complex dye represented by Formula (I); and a metal complex dye, a dye-adsorbed electrode and a dye solution for producing the same, and a dye-sensitized solar cell:         M(LD)(LA)(X)mX·(CI)mY     Formula (I) wherein M represents Fe2+, Ru2+ or Os2+; LD represents a ligand represented by Formula (DL); LA represents a bidentate or tridentate ligand having a nitrogen-containing aromatic heterocyclic skeleton and at least one acidic group; X represents a monodentate or bidentate ligand; CI represents a counter ion for neutralizing an electric charge; mX represents an integer of 0 to 3; and mY represents an integer of 0 to 2; wherein Z represents ring-forming atoms; D represents a coordinating atom selected from an oxygen atom and a nitrogen atom; E represents a single bond, -O-, - N(R1)-, -C(R2)2-, -C(=R3)-, -C(=O)-, -C(=NR1)-, or -C(R2)2-C(=O)-; R1 and R2 represent a hydrogen atom, an alkyl group, an aryl group, a heteroaryl group, an alkoxy group, or an aryloxy group; R3 represents an alkylidene group, an alkenylidene group, or a cycloalkylidene group; R represents a substituent; m and n represent an integer of 1 or more; wherein at least one coordinating atom is a coordinating atom A and, among Rs in the number of n, at least one is a substituent W; and the coordinating atom A is an oxygen or nitrogen atom which does not have an unsaturated bonding arm, and the substituent W is an ethenyl group, ethynyl group, aryl group, or heteroaryl group, substituted with a monovalent alkyl group having 2 or more carbon atoms or with a substituent having the alkyl group.

  一种光电转换元件，包含：导电支架、含有电解质的光电导体层、含有电解质的电荷转移层和对电极；其中，光电导体层含有携带由式（I）表示的金属络合染料的半导体细颗粒；以及金属络合染料、染料吸附电极和用于生产该染料的染料溶液，以及染料敏化太阳能电池： M(LD)(LA)(X)mX-(CI)mY 式(I) 其中 M 代表 Fe2+、Ru2+ 或 Os2+；LD 代表由式（DL）表示的配体；LA 代表具有含氮芳香杂环骨架和至少一个酸性基团的双齿或三齿配体；X 代表单齿或双齿配体；CI 代表用于中和电荷的反离子；mX 代表 0 至 3 的整数；以及 mY 代表 0 至 2 的整数； 其中 Z 代表成环原子；D 代表选自氧原子和氮原子的配位原子；E 代表单键、-O-、-N(R1)-、-C(R2)2-、-C(＝R3)-、-C(＝O)-、-C(＝NR1)- 或-C(R2)2-C(＝O)-；R1 和 R2 代表氢原子、烷基、芳基、杂芳基、烷氧基或芳氧基；R3 代表亚烷基、亚烯基或亚环烷基；R 代表取代基；m和n代表1或更多的整数；其中至少一个配位原子是配位原子A，在n个数的Rs中，至少一个是取代基W；配位原子A是不具有不饱和键臂的氧原子或氮原子，取代基W是被具有2个或更多碳原子的一价烷基或具有烷基的取代基取代的乙烯基、乙炔基、芳基或杂芳基。