4,4'-Methylenebis(1-methyl-3-phenylurea) | 63761-07-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-Methylenebis(1-methyl-3-phenylurea)
• 英文别名: 1-methyl-3-[4-[[4-(methylcarbamoylamino)phenyl]methyl]phenyl]urea
• CAS: 63761-07-9
• 化学式: C₁₇H₂₀N₄O₂
• 分子量: 312.371
• InChiKey: URHYYNIWSKTHNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  82.3
• 氢给体数：
  4
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 4,4'-Methylenebis(1-methyl-3-phenylurea) 在 Ag₂O 作用下， 以 二氯甲烷 为溶剂， 以75%的产率得到[Pt(1,5-cyclo-octadiene)(MeNC(O)NC6H4)]2CH2
  参考文献：
  名称：

  Synthesis and characterisation of platinum (II) ureylene complexes, and the X-ray structure of (Ad = 1-adamantyl, COD = 1,5-cyclo-octadiene)

  摘要：

  Reaction of [PtCl2(COD)] or cis-[PtCl2(PPh(3))(2)] with a range of mono- and di-substituted ureas, together with urea itself, and an excess of silver(I) oxide gives ureylene complexes 3 and 4 containing the Pt-N-C(O)-N four-membered ring system. The complexes have been fully characterised by multinuclear NMR and IR spectroscopies, electrospray mass spectrometry, and a single-crystal X-ray structure of the complex [Pt{PhNC(O)NAd)(COD)] (Ad = 1-adamantyl, COD = 1,5-cyclo-octadiene).

  DOI：

  10.1016/s0022-328x(96)06532-1
• 作为产物：
  描述：

  甲胺 、 4,4'-二苯甲烷二异氰酸酯、2,4'-二苯甲烷二异氰酸酯和2,2'-二苯甲烷二异氰酸酯的混合物 以 乙醚 为溶剂， 生成 4,4'-Methylenebis(1-methyl-3-phenylurea)
  参考文献：
  名称：

  Synthesis and characterisation of platinum (II) ureylene complexes, and the X-ray structure of (Ad = 1-adamantyl, COD = 1,5-cyclo-octadiene)

  摘要：

  Reaction of [PtCl2(COD)] or cis-[PtCl2(PPh(3))(2)] with a range of mono- and di-substituted ureas, together with urea itself, and an excess of silver(I) oxide gives ureylene complexes 3 and 4 containing the Pt-N-C(O)-N four-membered ring system. The complexes have been fully characterised by multinuclear NMR and IR spectroscopies, electrospray mass spectrometry, and a single-crystal X-ray structure of the complex [Pt{PhNC(O)NAd)(COD)] (Ad = 1-adamantyl, COD = 1,5-cyclo-octadiene).

  DOI：

  10.1016/s0022-328x(96)06532-1

文献信息

• [EN] BISUREA GELLING AGENTS AND COMPOSITIONS<br/>[FR] AGENTS GÉLIFIANTS DE TYPE BIURÉE ET COMPOSITIONS ASSOCIÉES
  申请人：MILLIKEN & CO

  公开号：WO2013033300A1

  公开（公告）日：2013-03-07

  Bisurea gelling agents that impart a number of unexpected benefits within various gelled formulations and exhibit great versatility in terms of gelling capabilities for many types of solvents are provided. Such gelling agents should include pendant groups, such as sterically hindering alkyl groups attached to polyoxyalkylenated moieties that allow the gelling agent to be compatible with the target liquid system at elevated temperatures, while controlling and/or limiting the network formation and strength during the cooling cycle. The result is that a reliable, hard gel is formed that does not crash out of solution easily and that does not exhibit unwanted cracking or precipitating out within the final formulation. Alternatively, novel gelling agents having two urea groups but that are asymmetrical in configuration have been produced in order to provide the same control in temperature, compatibility, and efficiency. Final gelled formulations, such as antiperspirant sticks and other like consumer items, are provided as well within this invention.

  本文提供了一种Bisurea凝胶剂，它在各种凝胶配方中带来了许多意想不到的好处，并且在凝胶能力方面表现出极大的多样性，适用于许多类型的溶剂。这种凝胶剂应包括挂链基团，例如附加到聚氧烷基化物上的空间阻碍烷基基团，使凝胶剂在升高的温度下与目标液体系统兼容，同时在冷却周期中控制和/或限制网络形成和强度。结果是形成了可靠的坚硬凝胶，不易从溶液中崩解，不会在最终配方中出现不必要的开裂或沉淀。另外，为了提供相同的温度、兼容性和效率控制，还制备了具有两个脲基但配置不对称的新型凝胶剂。本发明还提供了最终的凝胶配方，例如止汗膏和其他类似的消费品。
• BIODEGRADABLE RESIN COMPOSITIONS AND MOLDED OBJECTS THEREOF
  申请人：Kaneka Corporation

  公开号：EP1826241A1

  公开（公告）日：2007-08-29

  The present invention has its object to provide a resin composition excellent in impact resistance, tensile properties and transparency using a plant-derived biodegradable polymer obtained by positive fixation of carbon dioxide on the earth and, moldings thereof, and, further, provide a resin composition and moldings thereof improved in processability and thermal stability. The present invention relates to a resin composition which comprises (A), an aliphatic polyester type biodegradable polymer and (B) at least one copolymer selected from the group consisting of composite rubber graft copolymers (b1) and core-shell type graft copolymers (b2); or, a resin composition which comprises (A) an aliphatic polyester type biodegradable polymer and (C) at least one compound selected from the group consisting of sorbitol compounds (c1) having a particular chemical structure and urea bond-containing substituted urea compounds (c2).

  本发明的目的是提供一种具有优异抗冲击性、拉伸性能和透明度的树脂组合物，该树脂组合物使用了一种通过二氧化碳在地球上的正固定作用而获得的植物源生物可降解聚合物及其模塑件，此外，还提供了一种在加工性和热稳定性方面均有所改善的树脂组合物及其模塑件。 本发明涉及 一种树脂组合物 它包括 (A) 脂肪族聚酯型可生物降解聚合物和 (B) 至少一种选自复合橡胶接枝共聚物 (b1) 和芯壳型接枝共聚物 (b2) 组的共聚物；或 树脂组合物 其中包括 (A) 脂肪族聚酯型可生物降解聚合物和 (C) 至少一种选自具有特定化学结构的山梨醇化合物（c1）和含脲键的取代脲化合物 （c2）的化合物。
• BIODEGRADABLE RESIN COMPOSITION AND MOLDED ARTICLE PRODUCED FROM THE SAME
  申请人：Kaneka Corporation

  公开号：EP1881035A1

  公开（公告）日：2008-01-23

  Disclosed is a resin composition excellent in molding processability which comprises a plant-derived biodegradable plastic produced by actively fixing carbon dioxide present in the earth. A resin composition excellent in molding processability, comprising (A) a biodegradable (3-hydroxyalkanoate) copolymer having a recurring unit represented by the formula (1): [-CHR-CH2-CO-O-] (wherein R represents an alkyl group represented by the formula CnH2n+1 and n is an integer of 1 to 15) and 0.1 to 100 parts by weight, based on 100 parts by weight of (A) the biodegradable (3-hydroxyalkanoate) copolymer, of (B) an acrylic modifier having a weight average molecular weight (Mw) of 500,000 to 10,000,000.

  本发明公开了一种成型加工性极佳的树脂组合物，该树脂组合物包含一种植物来源的可生物降解塑料，该植物来源的可生物降解塑料是通过积极固定地球中的二氧化碳而产生的。一种成型加工性优异的树脂组合物，包括 (A) 可生物降解的（3-羟基烷酸）共聚物，该共聚物具有由式 (1) 代表的循环单元：[-CHR-CH2-CO-O-]（其中 R 代表由式 CnH2n+1 表示的烷基，n 为 1 至 15 的整数）和 0.1 至 100 重量份（以 100 重量份的(A)可生物降解（3-羟基烷酸）共聚物为基数）的(B)丙烯酸改性剂，其重量平均分子量（Mw）为 500,000 至 10,000,000。
• HIGH THERMAL CONDUCTIVITY THERMOPLASTIC RESIN COMPOSITION WITH EXCELLENT INJECTION MOLDABILITY
  申请人：Kaneka Corporation

  公开号：EP3018172A1

  公开（公告）日：2016-05-11

  A highly thermally conductive thermoplastic resin composition of the present invention contains: (A) a thermoplastic polyester resin having a weight average molecular weight of 50,000 to 200,000; (B) a polyalkylene terephthalate block copolymer composed of a polyether segment and a polyethylene terephthalate segment which includes an ethylene terephthalate unit as a main component; and (C) a highly thermally conductive inorganic compound, the highly thermally conductive thermoplastic resin composition containing, with respect to 100 parts by weight of (A) the thermoplastic polyester resin, 20 parts by weight to 200 parts by weight of (B) the polyalkylene terephthalate block copolymer and 20 parts by weight to 250 parts by weight of (C) the highly thermally conductive inorganic compound.

  本发明的一种高导热性热塑性树脂组合物含有(A) 热塑性聚酯树脂，其重量平均分子量在 50,000 至 200,000 之间；(B) 聚对苯二甲酸乙二醇酯嵌段共聚物，由聚醚段和聚对苯二甲酸乙二醇酯段组成，其中包括作为主要成分的对苯二甲酸乙二醇酯单元；(C) 高导热性无机化合物，该高导热性热塑性树脂组合物中，相对于 100 重量份的(A)热塑性聚酯树脂，含有 20 至 200 重量份的(B)聚对苯二甲酸乙二醇酯嵌段共聚物和 20 至 250 重量份的(C)高导热性无机化合物。
• High thermal conductivity thermoplastic resin composition with excellent injection moldability
  申请人：Kaneka Corporation

  公开号：US10030138B2

  公开（公告）日：2018-07-24

  A highly thermally conductive thermoplastic resin composition of the present invention contains: (A) a thermoplastic polyester resin having a weight average molecular weight of 50,000 to 200,000; (B) a polyalkylene terephthalate block copolymer composed of a polyether segment and a polyethylene terephthalate segment which includes an ethylene terephthalate unit as a main component; and (C) a highly thermally conductive inorganic compound, the highly thermally conductive thermoplastic resin composition containing, with respect to 100 parts by weight of (A) the thermoplastic polyester resin, 20 parts by weight to 200 parts by weight of (B) the polyalkylene terephthalate block copolymer and 20 parts by weight to 250 parts by weight of (C) the highly thermally conductive inorganic compound.

  本发明的一种高导热性热塑性树脂组合物含有(A) 热塑性聚酯树脂，其重量平均分子量在 50,000 至 200,000 之间；(B) 聚对苯二甲酸乙二醇酯嵌段共聚物，由聚醚段和聚对苯二甲酸乙二醇酯段组成，其中包括作为主要成分的对苯二甲酸乙二醇酯单元；(C) 高导热性无机化合物，该高导热性热塑性树脂组合物中，相对于 100 重量份的(A)热塑性聚酯树脂，含有 20 至 200 重量份的(B)聚对苯二甲酸乙二醇酯嵌段共聚物和 20 至 250 重量份的(C)高导热性无机化合物。