benzhydryl-trimethyl-ammonium; hydroxide | 32245-28-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzhydryl-trimethyl-ammonium; hydroxide
• 英文别名: Benzhydryl-trimethyl-ammonium; Hydroxid；Benzhydryl-trimethylammonium hydroxide；benzhydryl(trimethyl)azanium;hydroxide
• CAS: 32245-28-6
• 化学式: C₁₆H₂₀N*HO
• 分子量: 243.349
• InChiKey: PKCUXRCKJVIKKP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.31
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二苯基溴甲烷 在 甲醇 作用下， 生成 benzhydryl-trimethyl-ammonium; hydroxide
  参考文献：
  名称：

  Sommelet, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1922, vol. 175, p. 1151

  摘要：

  DOI：

文献信息

• Modified cellulose compound and photopolymerizable resin composition containing the same
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP0894808A1

  公开（公告）日：1999-02-03

  A modified cellulose compound and a photopolymerizable resin composition containing the same are disclosed, the modified cellulose compound being obtained by reacting a hydroxyl group of cellulose or a cellulose derivative with an isocyanate group of a specific (meth)acryloyloxyalkylene isocyanate compound. The photopolymerizable resin composition has excellent adhesion to a substrate and high flexibility, and the modified cellulose compound has properties of easily decomposing and volatilizing even after baking.

  本发明公开了一种改性纤维素化合物和含有改性纤维素化合物的可光聚合树脂组合物，改性纤维素化合物是通过纤维素或纤维素衍生物的羟基与特定（甲基）丙烯酰氧基烷基异氰酸酯化合物的异氰酸酯基反应而获得的。这种可光聚合的树脂组合物对基材具有极佳的粘附性和高柔韧性，而且改性纤维素化合物即使在烘烤后也具有易于分解和挥发的特性。
• PHOTOSENSITIVE RESIN COMPOSITION AND FLEXOGRAPHIC RESIN PLATE
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP0950923A1

  公开（公告）日：1999-10-20

  The present invention provides a photosensitive resin composition which comprises an urethane resin obtained by reacting (A) a carboxyl group-containing polymer having an acid value of 30 mg KOH/g or more and a glass transition temperature of 30°C or more, (B) a compound having two isocyanate groups in one molecule, (C) a compound having two hydroxyl groups in one molecule and (D) a photopolymerizable unsaturated monomer having one hydroxyl group in one molecule, and a photopolymerization initiator, and a resin plate for flexography using the photosensitive resin composition, whereby the photosensitive resin composition having water developing properties, high in sensitivity and impact resilience, and excellent in water resistance, ink resistance and press life of a hardened portion forming a line pattern area of a printing plate material and the resin plate for flexography prepared by the use of the photosensitive resin composition can be provided.

  本发明提供了一种感光树脂组合物，它包括由以下物质反应得到的聚氨酯树脂：(A)酸值大于等于30毫克KOH/克且玻璃化温度大于等于30℃的含羧基聚合物；(B)一个分子中含有两个异氰酸酯基团的化合物；(C)一个分子中含有两个羟基的化合物；(D)一个分子中含有一个羟基的可光聚合不饱和单体、和一种光聚合引发剂，以及一种使用该感光树脂组合物的柔性版印刷用树脂版，从而可以提供具有水显影特性、高灵敏度和高冲击回弹性，以及在形成印刷版材料的线条图案区域的硬化部分和使用该感光树脂组合物制备的柔性版印刷用树脂版中具有优异的耐水性、耐油墨性和印刷寿命的感光树脂组合物。
• Photopolymerizable composition
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP1168080A2

  公开（公告）日：2002-01-02

  A photopolymerizable composition comprising (A) a polymer binder, (B) a photopolymerizable monomer and (C) a photopolymerization initiator, wherein the component (B) is at least one compound represented by the following formula (1):

  一种可光聚合组合物，包括 (A) 聚合物粘合剂、(B) 可光聚合单体和 (C) 光聚合引发剂，其中组分 (B) 至少是由下式 (1) 代表的一种化合物：
• Photosensitive composition for sandblasting and photosensitive film using the same
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP1205803A1

  公开（公告）日：2002-05-15

  A photosensitive composition for sandblasting comprising the components of: (A) a photopolymerizable urethane (meth)acrylate oligomer comprising (meth)acryloyl group; (B) an acrylic copolymer; and (C) a photopolymerization initiator, wherein the component (B) comprises, as a monomer unit, one of copolymerizable monomers comprising one of a benzene ring and a cyclohexyl group.

  一种喷砂用光敏组合物，其组分包括(A) 含(甲基)丙烯酰基的可光聚合聚氨酯(甲基)丙烯酸酯低聚物；(B) 丙烯酸共聚物；和 (C) 光聚合引发剂，其中组分(B)作为单体单元包括含苯环和环己基的可共聚单体之一。
• Photosensitive resin composition and resin plate for flexography
  申请人：Tokyo Ohka Kogyo Co., Ltd.

  公开号：US20010033981A1

  公开（公告）日：2001-10-25

  The present invention provides a photosensitive resin composition which comprises an urethane resin obtained by reacting (A) a carboxyl group-containing polymer having an acid value of 30 mg KOH/g or more and a glass transition temperature of 30° C. or more, (B) a compound having two isocyanate groups in one molecule, (C) a compound having two hydroxyl groups in one molecule and (D) a photopolymerizable unsaturated monomer having one hydroxyl group in one molecule, and a photopolymerization initiator, and a resin plate for flexography using the photosensitive resin composition, whereby the photosensitive resin composition having water developing properties, high in sensitivity and impact resilience, and excellent in water resistance, ink resistance and press life of a hardened portion forming a line pattern area of a printing plate material and the resin plate for flexography prepared by the use of the photosensitive resin composition can be provided.

  本发明提供了一种光敏树脂组合物，该组合物包括一种聚氨酯树脂，该聚氨酯树脂是由以下物质反应得到的：(A)一种含羧基的聚合物，其酸值为30毫克KOH/克或以上，玻璃化温度为30摄氏度或以上或更高的含羧基聚合物、(B) 一个分子中含有两个异氰酸酯基团的化合物、(C) 一个分子中含有两个羟基的化合物和(D) 一个分子中含有一个羟基的可光聚合不饱和单体，以及光聚合引发剂，和使用该感光树脂组合物的柔性版印刷用树脂版、由此，可以提供具有水显影特性、高灵敏度和高冲击回弹性，以及优异的耐水性、耐油墨性和印刷寿命的感光树脂组合物，其硬化部分形成印刷版材料的线条图案区域，以及使用该感光树脂组合物制备的柔性版印刷用树脂版。