1,6-bis-(diphenylphosphino)-3,3,4,4-tetramethyl-3,4-disilahexane | 156736-66-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,6-bis-(diphenylphosphino)-3,3,4,4-tetramethyl-3,4-disilahexane
• 英文别名: 2-[[2-Diphenylphosphanylethyl(dimethyl)silyl]-dimethylsilyl]ethyl-diphenylphosphane
• CAS: 156736-66-2
• 化学式: C₃₂H₄₀P₂Si₂
• 分子量: 542.788
• InChiKey: DCYGFWHAWMHBFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.75
• 重原子数：
  36
• 可旋转键数：
  11
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 1,6-bis-(diphenylphosphino)-3,3,4,4-tetramethyl-3,4-disilahexane 以 四氢呋喃 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Syntheses and Interconversion of [Bis(silyl)alkene]palladium(0) and Bis(silyl)palladium(II) Complexes: A Mechanistic Model for Palladium-Catalyzed Bis-Silylation

  摘要：

  Two palladium complexes, [bis(trialkylsilyl)-alkene]palladium(0) and bis(trialkylsilyl)palladium(II), have been synthesized and structurally determined. The interconversion of these palladium complexes supports the postulated mechanism of palladium-catalyzed bis-silylation of C-C triple bonds.

  DOI：

  10.1021/om00019a055

文献信息

• Syntheses and Interconversion of [Bis(silyl)alkene]palladium(0) and Bis(silyl)palladium(II) Complexes: A Mechanistic Model for Palladium-Catalyzed Bis-Silylation
  作者：Masahiro Murakami、Takashi Yoshida、Yoshihiko Ito

  DOI：10.1021/om00019a055

  日期：1994.7

  Two palladium complexes, [bis(trialkylsilyl)-alkene]palladium(0) and bis(trialkylsilyl)palladium(II), have been synthesized and structurally determined. The interconversion of these palladium complexes supports the postulated mechanism of palladium-catalyzed bis-silylation of C-C triple bonds.