8,8,20,20,32,32,44,44-Octamethyl-7,9,19,21,31,33,43,45-octaoxa-2,14,26,38,49,50,51,52-octazatridecacyclo[37.9.1.13,13.115,25.127,37.04,12.06,10.016,24.018,22.028,36.030,34.040,48.042,46]dopentaconta-1,3,5,10,12,14,16,18(22),23,25(51),26,28,30(34),35,37(50),39(49),40,42(46),47-nonadecaene | 672284-70-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 8,8,20,20,32,32,44,44-Octamethyl-7,9,19,21,31,33,43,45-octaoxa-2,14,26,38,49,50,51,52-octazatridecacyclo[37.9.1.13,13.115,25.127,37.04,12.06,10.016,24.018,22.028,36.030,34.040,48.042,46]dopentaconta-1,3,5,10,12,14,16,18(22),23,25(51),26,28,30(34),35,37(50),39(49),40,42(46),47-nonadecaene
• 英文别名: 8,8,20,20,32,32,44,44-octamethyl-7,9,19,21,31,33,43,45-octaoxa-2,14,26,38,49,50,51,52-octazatridecacyclo[37.9.1.13,13.115,25.127,37.04,12.06,10.016,24.018,22.028,36.030,34.040,48.042,46]dopentaconta-1,3,5,10,12,14,16,18(22),23,25(51),26,28,30(34),35,37(50),39(49),40,42(46),47-nonadecaene
• CAS: 672284-70-7
• 化学式: C₄₄H₃₄N₈O₈
• 分子量: 802.803
• InChiKey: ARFYCKIDVNOKST-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  60
• 可旋转键数：
  0
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  183
• 氢给体数：
  2
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  8,8,20,20,32,32,44,44-Octamethyl-7,9,19,21,31,33,43,45-octaoxa-2,14,26,38,49,50,51,52-octazatridecacyclo[37.9.1.13,13.115,25.127,37.04,12.06,10.016,24.018,22.028,36.030,34.040,48.042,46]dopentaconta-1,3,5,10,12,14,16,18(22),23,25(51),26,28,30(34),35,37(50),39(49),40,42(46),47-nonadecaene 在 三氟化硼乙醚 作用下， 以 氯仿 为溶剂， 反应 48.0h， 生成 2,3,9,10,16,17,23,24-octahydroxyphthalocyanine
  参考文献：
  名称：

  [EN] COVALENT ORGANIC FRAMEWORKS AND METHODS OF MAKING SAME
  [FR] STRUCTURES ORGANIQUES COVALENTES ET PROCÉDÉS POUR LEUR FABRICATION

  摘要：

  公开号：

  WO2011127301A3
• 作为产物：
  描述：

  5,6-dicyano-2,2-dimethyl-1,3-benzodioxole 在 lithium methanolate 作用下， 以 various solvent(s) 为溶剂， 以64%的产率得到8,8,20,20,32,32,44,44-Octamethyl-7,9,19,21,31,33,43,45-octaoxa-2,14,26,38,49,50,51,52-octazatridecacyclo[37.9.1.13,13.115,25.127,37.04,12.06,10.016,24.018,22.028,36.030,34.040,48.042,46]dopentaconta-1,3,5,10,12,14,16,18(22),23,25(51),26,28,30(34),35,37(50),39(49),40,42(46),47-nonadecaene
  参考文献：
  名称：

  摘要：

  A series of new metal monophthalocyanine complexes were synthesized from 4,5-iso-propylidenedioxyphthalonitrile and their spectroscopic and electrochemical properties were studied. The removal of the protective isopropylidene groups from these compounds afforded symmetrically substituted octahydroxyphthalocyanines.

  DOI：

  10.1023/a:1025693009575

文献信息

• Straightforward and Controlled Synthesis of Porphyrin–Phthalocyanine–Porphyrin Heteroleptic Triple‐Decker Assemblies
  作者：Daniel González‐Lucas、Shazia C. Soobrattee、David L. Hughes、Graham J. Tizzard、Simon J. Coles、Andrew N. Cammidge

  DOI：10.1002/chem.202002500

  日期：2020.8.21

  A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide‐bridged heteroleptic porphyrin–phthalocyanine triple‐decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple‐decker complex. The bridge directs assembly, but also controls the

  公开了一种通用而直接的方案，用于复杂镧系元素桥联杂卟啉-酞菁三层组装的受控合成。两个卟啉通过中间长度的柔性间隔链连接，依次捕获镧系离子和酞菁以有效地形成三层复合物。桥引导组装，但也控制中央大环的移动性，并进一步赋予所有三个环完全遮盖的布置。
• New diphthalocyanine complexes of rare-earth metals based on 4,5-isopropylidenedioxyphthalonitrile
  作者：A. V. Ivanov、P. A. Svinareva、I. V. Zhukov、L. G. Tomilova、N. S. Zefirov

  DOI：10.1007/s11172-006-0249-4

  日期：2006.2

  A series of the earlier unknown diphthalocyanine complexes of rare-earth metals based on 4,5-isopropylidenedioxyphthalonitrile were prepared. Their compositions and yields depend on the radius of the complexing ion. The synthesized compounds were studied by spectroscopy and electrochemical methods. The redox potentials of the complexes studied change nonlinearly with a decrease in the lanthanide ion radius.

  以 4,5-异亚丙基二氧基邻苯二甲腈为基础，制备了一系列早期未知的稀土金属二酞菁络合物。它们的组成和产量取决于络合离子的半径。通过光谱和电化学方法对合成的化合物进行了研究。所研究的络合物的氧化还原电位随着镧系离子半径的减小而发生非线性变化。
• Covalent Organic Frameworks and Methods of Making Same
  申请人：Dichtel William R.

  公开号：US20140148596A1

  公开（公告）日：2014-05-29

  Crystalline COFs comprising a phthalocyanine moiety and a boron-containing multifunctional linking group joined by boronate ester bonds. A method for making crystalline COFs comprising Lewis acid catalyzed formation of boronate ester bonds between protected catechol subunits and multifunctional linkers comprising boronic acid groups. The COFs can be used in applications such as, for example, electronic devices.
• ——
  作者：A. V. Ivanov、P. A. Svinareva、I. V. Zhukov、L. G. Tomilova、N. S. Zefirov

  DOI：10.1023/a:1025693009575

  日期：——

  A series of new metal monophthalocyanine complexes were synthesized from 4,5-iso-propylidenedioxyphthalonitrile and their spectroscopic and electrochemical properties were studied. The removal of the protective isopropylidene groups from these compounds afforded symmetrically substituted octahydroxyphthalocyanines.
• [EN] COVALENT ORGANIC FRAMEWORKS AND METHODS OF MAKING SAME<br/>[FR] STRUCTURES ORGANIQUES COVALENTES ET PROCÉDÉS POUR LEUR FABRICATION
  申请人：UNIV CORNELL

  公开号：WO2011127301A3

  公开（公告）日：2012-04-19