THEICTHP | 1338495-88-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: THEICTHP
• 英文别名: 1,3,5-tri(2-hydroxyethyl)isocyanurate tris-HEMA phthalate；1-O-[2-[3,5-bis[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxycarbonyl]benzoyl]oxyethyl]-2,4,6-trioxo-1,3,5-triazinan-1-yl]ethyl] 2-O-[2-(2-methylprop-2-enoyloxy)ethyl] benzene-1,2-dicarboxylate
• CAS: 1338495-88-7
• 化学式: C₅₁H₅₁N₃O₂₁
• 分子量: 1041.97
• InChiKey: BPORNFVVGWNQEZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  75
• 可旋转键数：
  36
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  298
• 氢给体数：
  0
• 氢受体数：
  21

反应信息

• 作为产物：
  描述：

  甲基丙烯酸羟乙酯 在 4-二甲氨基吡啶 、 2,6-二叔丁基-4-甲基苯酚 、 N,N'-二环己基碳二亚胺 作用下， 以 丙酮 为溶剂， 反应 5.0h， 生成 THEICTHP
  参考文献：
  名称：

  Polymerizable isocyanurate monomers and dental compositions

  摘要：

  描述了可聚合的异氰酸酯单体和牙科组合物。描述了一种可硬化的牙科组合物，其中包含至少一种在约25°C时为稳定液体的异氰酸酯单体。异氰酸酯单体包括至少一个二价连接基与三价异氰酸环的氮原子键合，其中二价连接基包括从酯，硫酯，醚或硫醚中选择的基团，以及这些基团的组合和一个末端乙烯基不饱和聚合基团。

  公开号：

  US09237990B2

文献信息

• [EN] ADDITION-FRAGMENTATION AGENTS<br/>[FR] AGENTS D'ADDITION-FRAGMENTATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2012112304A1

  公开（公告）日：2012-08-23

  Addition-fragmentation agents of the formula are disclosed formula (I): wherein R1, R2 and R3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-, Q is a linking group have a valence of m +1; Z is an ethylenically unsaturated polymerizable group, m is 1 to 6; each X1 is independently -O- or -NR4-, where R4 is H or C1-C4 alkyl, and n is 0 or 1.

  公开了化学式为（I）的加成-解离剂，其中R1、R2和R3分别独立地是Z-Q-、(杂)烷基或(杂)芳基，但至少其中一个是Zm-Q-，Q是具有价态为m+1的连接基团；Z是乙烯基不饱和可聚合基团，m为1至6；每个X1独立地是-O-或-NR4-，其中R4是H或C1-C4烷基，n为0或1。
• DENTAL COMPOSITIONS COMPRISING ETHYLENICALLY UNSATURATED ADDITION-FRAGMENTATION AGENT
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20150238389A1

  公开（公告）日：2015-08-27

  Dental compositions are described comprising an addition-fragmentation agent of the formula: wherein R 1 , R 2 and R 3 are each independently Z m -Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R 1 , R 2 and R 3 is Z m -Q-; Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group; m is 1 to 6; each X 1 is independently —O— or —NR 4 —, where R 4 is H or C 1 -C 4 alkyl; and n is 0 or 1. Also described are dental articles prepared from a dental composition comprising an addition-fragmentation agent and methods of treating a tooth surface.

  本文描述了一种牙科组合物，其中包括一个式子为的加成-断裂剂：其中R1、R2和R3各自独立地是Zm-Q-、(杂)烷基或(杂)芳基，但至少其中一个是Zm-Q-；Q是具有价为m+1的连接基；Z是乙烯基不饱和可聚合基团；m为1至6；每个X1分别是—O—或—NR4—，其中R4是H或C1-C4烷基；n为0或1。还描述了从含有加成-断裂剂的牙科组合物制备的牙科制品和治疗牙齿表面的方法。
• POLYMERIZABLE ISOCYANURATE MONOMERS AND DENTAL COMPOSITIONS
  申请人：Abuelyaman Ahmed S.

  公开号：US20130012614A1

  公开（公告）日：2013-01-10

  Polymerizable isocyanurate monomers and dental compositions are described. A hardenable dental composition is described comprising at least one isocyanurate monomer that is a stable liquid at about 25° C. The isocyanurate monomer comprises at least one divalent linking group bonded to a nitrogen atom of a trivalent isocyanuric acid ring, wherein the divalent linking group comprises a moiety selected from ester, thioester, ether, or thioether, and combinations of such moieties and a terminal ethylenically unsaturated polymerizable group.

  本文描述了可聚合的异氰酸酯单体和牙科组合物。其中一种可硬化的牙科组合物包括至少一种在大约25℃下稳定液态的异氰酸酯单体。该异氰酸酯单体包括至少一个二价连接基与三价异氰酸环上的氮原子键合，其中该二价连接基包括酯、硫酯、醚或硫醚中的一种基团，或这些基团的组合，并且具有一个末端乙烯基不饱和聚合基团。
• ADDITION-FRAGMENTATION AGENTS
  申请人：Joly Guy D.

  公开号：US20120208965A1

  公开（公告）日：2012-08-16

  Addition-fragmentation agents of the formula are disclosed: wherein R 1 , R 2 and R 3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R 1 , R 2 and R 3 is Z m -Q-, Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group, m is 1 to 6; each X 1 is independently —O— or —NR 4 —, where R 4 is H or C 1 -C 4 alkyl, and n is 0 or 1.

  公开了以下式子的加成-解离剂： 其中， R1，R2和R3分别独立地为Z-Q-，(杂)烷基或(杂)芳基，但至少其中一个为Zm-Q-； Q为连接基团，具有m+1的价； Z为乙烯基不饱和可聚合基团，m为1到6； 每个X1独立地为—O—或—NR4—，其中R4为H或C1-C4烷基，n为0或1。
• Dental compositions comprising a fatty mono(meth)acrylate
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10022306B2

  公开（公告）日：2018-07-17

  Presently described are dental compositions comprising one or more fatty mono(meth)acrylates, methods of use, dental articles, and methods of making dental compositions. It has been found that a relatively low concentration of a fatty mono(meth)acrylate can improve the handling characteristics of a dental composition by reducing the tendency of the composition to stick to a dental instrument and/or by reducing the tendency of a dental composition to string when being manipulated by a dental instrument. In one embodiment, a hardenable dental composition is described comprising a polymerizable resin composition comprising at least one multifunctional ethylenically unsaturated monomer; 0.2 to 10 wt-% of one or more fatty mono(meth)acrylate monomers; and at least 50 wt-% of inorganic oxide filler.

  目前描述的是包含一种或多种脂肪单（甲基）丙烯酸酯的牙科组合物、使用方法、牙科用品和牙科组合物的制造方法。研究发现，相对低浓度的脂肪单（甲基）丙烯酸酯可以改善牙科组合物的操作特性，降低组合物粘附在牙科器械上的倾向和/或降低牙科组合物在牙科器械操作时串连的倾向。在一个实施方案中，描述了一种可硬化牙科组合物，该组合物包含一种可聚合树脂组合物，该树脂组合物包含至少一种多功能乙烯基不饱和单体；0.2-10 wt-%的一种或多种脂肪单（甲基）丙烯酸酯单体；以及至少 50 wt-%的无机氧化物填料。