[[3,5-Bis[bis(trimethylsilyl)methyl]-2-oxoboranylphenyl]-trimethylsilylmethyl]-trimethylsilane | 193344-16-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [[3,5-Bis[bis(trimethylsilyl)methyl]-2-oxoboranylphenyl]-trimethylsilylmethyl]-trimethylsilane
• CAS: 193344-16-0
• 化学式: C₂₇H₅₉BOSi₆
• 分子量: 579.089
• InChiKey: MSDYZTNVLGDCAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.88
• 重原子数：
  35
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [[3,5-Bis[bis(trimethylsilyl)methyl]-2-oxoboranylphenyl]-trimethylsilylmethyl]-trimethylsilane 在 水 作用下， 生成 [2,4,6-Tris[bis(trimethylsilyl)methyl]phenyl]boronic acid
  参考文献：
  名称：

  A novel approach to an oxoborane and its Lewis base complex

  摘要：

  Reaction of dimethyl sulfoxide (DMSO) with 1,3,2,4-dithiastannaboretane 3 bearing an extremely bulky aryl group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt), an the baron atom gave an oxoborane (Tbt-B=O; 4), which formed a complex with DMSO stable in solution. The formation of the complex was confirmed by B-11 NMR and a [3+2] cycloaddition reaction with 2,4,6-tri-t-butylbenzonitrile oxide. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00929-5
• 作为产物：
  描述：

  4-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2,2-diphenyl-1,3,2,4-dithiastannaboretane 在 二甲基亚砜 作用下， 以 苯 为溶剂， 反应 12.0h， 生成 [[3,5-Bis[bis(trimethylsilyl)methyl]-2-oxoboranylphenyl]-trimethylsilylmethyl]-trimethylsilane
  参考文献：
  名称：

  A novel approach to an oxoborane and its Lewis base complex

  摘要：

  Reaction of dimethyl sulfoxide (DMSO) with 1,3,2,4-dithiastannaboretane 3 bearing an extremely bulky aryl group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt), an the baron atom gave an oxoborane (Tbt-B=O; 4), which formed a complex with DMSO stable in solution. The formation of the complex was confirmed by B-11 NMR and a [3+2] cycloaddition reaction with 2,4,6-tri-t-butylbenzonitrile oxide. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00929-5