3-(biphenyl-2-yloxy)-2-hydroxypropyl acrylate | 91442-28-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(biphenyl-2-yloxy)-2-hydroxypropyl acrylate
• 英文别名: 2-Hydroxy-3-(o-phenylphenoxy)propyl acrylate；[2-hydroxy-3-(2-phenylphenoxy)propyl] prop-2-enoate
• CAS: 91442-28-3
• 化学式: C₁₈H₁₈O₄
• 分子量: 298.339
• InChiKey: CDFFKURPFGASGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  邻苯基苯酚缩水甘油醚 、 丙烯酸 在 2,6-二叔丁基-4-甲基苯酚 、 三苯基膦 作用下， 反应 24.5h， 生成 3-(biphenyl-2-yloxy)-2-hydroxypropyl acrylate 、 1-(biphenyl-2-yloxy)-3-hydroxypropan-2-yl acrylate
  参考文献：
  名称：

  AROMATIC GLYCOL ETHERS AS WRITING MONOMERS IN HOLOGRAPHIC PHOTOPOLYMER FORMULATIONS

  摘要：

  本发明涉及一种光聚合配方，包含特定的芳香族乙二醇醚作为写入单体、基质聚合物和光引发剂。本发明还提供了一种使用创新光聚合配方可获得的未曝光全息介质，以及通过将全息图曝光到创新的未曝光全息介质中获得的曝光全息介质。本发明同样提供了一种包含创新曝光全息介质的视觉显示，用于创新曝光全息介质在生产芯片卡、身份证件、三维图像、产品保护标签、标签、钞票或全息光学元件中的应用，以及特定的芳香族乙二醇醚。

  公开号：

  US20170045816A1

文献信息

• POLYMERIZABLE COMPOSITION, POLYMERIZATION PRODUCT, IMAGE DISPLAY DEVICE, AND METHOD FOR PRODUCING SAME
  申请人：SHOWA DENKO K.K.

  公开号：US20150030836A1

  公开（公告）日：2015-01-29

  In relation to a polymerizable composition for forming a transparent optical resin layer to be interposed between an image display section of an image display device and a light-transmissive protective section thereof, the present invention provides a polymerizable composition that does not give rise to display defects caused by the deformation of the image display section, enables high-luminance, high-contrast image displaying, has excellent heat resistance, and also has a low dielectric constant. This polymerizable composition comprises: (1) a urethane (meth)acrylate obtained by reacting a hydrogenated polyolefin polyol and a compound having an isocyanato group and a (meth)acryloyl group; (2) a (meth)acryloyl-group-containing compound having a hydrocarbon group with a carbon number of 6 or greater; and (3) a photopolymerization initiator.

  本发明涉及一种聚合物组合物，用于形成透明光学树脂层，以介于图像显示装置的图像显示部分和其透光保护部分之间。该聚合物组合物不会因为图像显示部分的变形而产生显示缺陷，能够实现高亮度、高对比度的图像显示，具有优异的耐热性，同时具有低介电常数。该聚合物组合物包括：(1)通过反应氢化聚烯烃多元醇和具有异氰酸酯基和(meth)丙烯酰基的化合物得到的聚氨酯(meth)丙烯酸酯；(2)具有碳数大于等于6的碳氢基团的(meth)丙烯酰基含有化合物；以及(3)光聚合引发剂。
• Polymerizable compositions
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0109073A2

  公开（公告）日：1984-05-23

  Polymerizable compositions capable of giving transparent resin having a high refractive index of at least 1.57 which are useful as optical materials and glass adhesives are disclosed. The compositions comprise a mono(meth)acrylate having a biphenyl skeleton and a di(meth)acrylate having a biphenyl skeleton or a bisphenol skeleton. The compositions cure rapidly, particularly under irradiation of ultraviolet light.

  本发明公开了可聚合的组合物，这些组合物能够产生具有至少 1.57 高折射率的透明树脂，可用作光学材料和玻璃粘合剂。这些组合物包括具有联苯骨架的单（甲基）丙烯酸酯和具有联苯骨架或双酚骨架的二（甲基）丙烯酸酯。这种组合物固化速度快，特别是在紫外线照射下。
• RADIATION CURABLE RESIN COMPOSITION
  申请人：DSM N.V.

  公开号：EP0909399A1

  公开（公告）日：1999-04-21
• OPTICAL POLYMER MATERIAL AND OPTICAL COMPONENT
  申请人：Kuramoto Keiichi

  公开号：US20080233417A1

  公开（公告）日：2008-09-25

  The invention provides an optical polymer material having a low viscosity before curing, a high refractive index of a cured product, little alteration of refractive index under high temperature and high humidity, and an excellent heat resistant shock property and an optical component using the optical polymer material. The optical polymer material is characterized in that the material contains a fluorene compound having four (meth) acryloyl groups and a (meth) acrylate having an aryl group and may further contain -M-O-M- bond (M is a metal atom), an organometallic polymer having an aryl group, a monofunctional (meth)acrylate and/or a polyfunctional (meth)acrylate.
• POLYMERIZABLE COMPOSITION, POLYMERIZATION PRODUCT, ADHESIVE SHEET, METHOD FOR MANUFACTURING AN IMAGE DISPLAY DEVICE, AND IMAGE DISPLAY DEVICE
  申请人：SHOWA DENKO K.K.

  公开号：US20150050432A1

  公开（公告）日：2015-02-19

  A polymerizable composition is disclosed wherein the polymerizable composition includes a first component selected from the group composed of compounds produced by an ester exchange reaction between a hydrogenated polyolefin polyol and an acrylic acid ester, compounds produced by an ester exchange reaction between a hydrogenated polyolefin polyol and a methacrylic acid ester, compounds produced by a dehydration condensation reaction between a hydrogenated polyolefin polyol and an acrylic acid, and compounds produced by a dehydration condensation reaction between a hydrogenated polyolefin polyol and a methacrylic acid, a second component selected from the group composed of compounds containing a hydrocarbon group with a carbon number more than or equal to 6 and an acryloyl group and compounds containing a hydrocarbon group with a carbon number more than or equal to 6 and a methacryloyl group, and a third component selected from the group composed of photopolymerization initiators.