anti-sesquinorbornatriene | 97806-44-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: anti-sesquinorbornatriene
• 英文别名: (1S,3S,6R,8R)-tetracyclo[6.2.1.13,6.02,7]dodeca-2(7),4,9-triene
• CAS: 97806-44-5
• 化学式: C₁₂H₁₂
• 分子量: 156.227
• InChiKey: KWPLEXGYQPSPLP-YNFQOJQRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  anti-sesquinorbornatriene 在 sodium amalgam 作用下， 生成 anti-1,2,3,4,5,6,7,8-octahydro-1,4,5,8-dimethano-naphthalene anti-sesquinorbornene
  参考文献：
  名称：

  A synthon for C₂polycyclic 1,4,5,8-tetrahydronaphthalenes via double Diels–Alder cycloaddition

  摘要：

  2-Chloro-1,4-benzodithiin-S,S'-tetroxide 1 is a synthon for C2 because its Diels-Alder adducts, after dehydrochlorination, react further with another molecule of diene and the resulting product can be desulfonylated into the same hydrocarbons that would have formed from C2.

  DOI：

  10.1039/c39920001089
• 作为产物：
  描述：

  在 甲醇 、 sodium amalgam 、 NaH₂PO₄ buffer 作用下， 生成 anti-sesquinorbornatriene
  参考文献：
  名称：

  A synthon for C₂polycyclic 1,4,5,8-tetrahydronaphthalenes via double Diels–Alder cycloaddition

  摘要：

  2-Chloro-1,4-benzodithiin-S,S'-tetroxide 1 is a synthon for C2 because its Diels-Alder adducts, after dehydrochlorination, react further with another molecule of diene and the resulting product can be desulfonylated into the same hydrocarbons that would have formed from C2.

  DOI：

  10.1039/c39920001089

文献信息

• anti-1,4,5,8-Tetrahydro-1,4;5,8-dimethanonaphthalene (sesquinorbornadiene), a molecule with three parallel, coplanar, and interacting double bonds
  作者：Ottorino De Lucchi、Giulia Licini、Lucia Pasquato

  DOI：10.1039/c39850000418

  日期：——

  Anti-1,4,5,8-Tetrahydro-1,4;5,8-dimethanonaphthalene (sesquinorbornadiene)(1), a molecule possessing six electrons distributed in three parallel double bonds set in one plane and within an interacting through-space distance, has been synthesized.

  抗-1,4,5,8-四氢-1,4; 5,8-二甲萘基萘（sesquinorbornadiene）（1），一种分子，它具有六个电子，这些电子分布在三个平行的双键中，三个平行的双键设置在一个平面中并且在一个相互作用的贯穿空间内距离，已经合成。
• Consequences of fixing three parallel coplanar double bonds in close proximity with different geometries. Synthesis and spectral parameters of syn- and anti-sesquinorbornatriene
  作者：Leo A. Paquette、Hermann. Kuenzer、Kenneth E. Green、Ottorino. De Lucchi、Giulia. Licini、Lucia. Pasquato、Giovanni. Valle

  DOI：10.1021/ja00272a047

  日期：1986.6
• PAQUETTE L. A.; KUENZER H.; GREEN K. E.; DE LUCCHI O.; LICINI G.; PASQUAT+, J. AMER. CHEM. SOC., 108,(1986) N 12, 3453-3460
  作者：PAQUETTE L. A.、 KUENZER H.、 GREEN K. E.、 DE LUCCHI O.、 LICINI G.、 PASQUAT+

  DOI：——

  日期：——
• A synthon for C₂polycyclic 1,4,5,8-tetrahydronaphthalenes via double Diels–Alder cycloaddition
  作者：Ottorino De Lucchi、Sergio Cossu

  DOI：10.1039/c39920001089

  日期：——

  2-Chloro-1,4-benzodithiin-S,S'-tetroxide 1 is a synthon for C2 because its Diels-Alder adducts, after dehydrochlorination, react further with another molecule of diene and the resulting product can be desulfonylated into the same hydrocarbons that would have formed from C2.