3,3'-(1,3-phenylenebis(oxy))bis(1-morpholinopropan-2-ol) | 40376-75-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,3'-(1,3-phenylenebis(oxy))bis(1-morpholinopropan-2-ol)
• 英文别名: 1,3-Bis-(3-morpholino-2-hydroxy-propyloxy)-benzol；3,3'-di-morpholin-4-yl-1,1'-m-phenylenedioxy-bis-propan-2-ol；Cambridge id 6073055；1-[3-(2-hydroxy-3-morpholin-4-ylpropoxy)phenoxy]-3-morpholin-4-ylpropan-2-ol
• CAS: 40376-75-8
• 化学式: C₂₀H₃₂N₂O₆
• 分子量: 396.484
• InChiKey: HEKXJKVSWLBHQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  28
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  83.9
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  吗啉 、 间苯二酚二缩水甘油醚 在 iron oxide 作用下， 以 neat (no solvent) 为溶剂， 反应 20.0h， 以50%的产率得到3,3'-(1,3-phenylenebis(oxy))bis(1-morpholinopropan-2-ol)
  参考文献：
  名称：

  磁性纳米 Fe3O4 催化胺对环氧化物的无溶剂立体和区域选择性氨解；一种合成β-氨基醇的绿色方法

  摘要：

  我们报告了使用磁性纳米 Fe3O4 作为温和的多相催化剂，用于环氧化物与胺的氨解。该方法构成了一种在无溶剂和环境反应条件下形成具有非常高立体选择性和区域选择性的各种 β-氨基醇的绿色方法。手性环氧化物与胺的氨解得到相应的手性 β-氨基醇，立体化学完全反转。磁性纳米Fe3O4催化剂易于回收和循环利用。

  DOI：

  10.1055/s-0033-1340844

文献信息

• Phenylurethane compounds and methods for producing same, asymmetric urea compounds and methods for producing same, barbituric acid derivative, and diazo thermal recording material containing the derivative
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20020161225A1

  公开（公告）日：2002-10-31

  Phenylurethane compounds of the following general formula (1); asymmetric urea compounds of the following general formula (10) obtained from the phenylurethane compounds; barbituric acid derivatives of general formula (18) produced from the asymmetric urea compounds, which have specific substituents and are useful in diazo thermal recording materials; and diazo thermal recording materials containing the barbituric acid derivative. 1

  以下为翻译结果： 以下是具有以下通式（1）的苯基脲化合物；从苯基脲化合物获得的具有以下通式（10）的不对称脲化合物；从不对称脲化合物产生的具有特定取代基的巴比妥酸衍生物，可用于重氮热记录材料；以及含有巴比妥酸衍生物的重氮热记录材料。
• Heat-sensitive recording material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0809145A1

  公开（公告）日：1997-11-26

  A heat-sensitive recording material having excellent lightfastness and raw stock storability is disclosed. The material includes a support and a heat-sensitive recording layer provided on the support, and the heat-sensitive recording layer contains a diazo compound and a coupler. The coupler contains at least one species of pyrazolone compounds represented by the following formula (1): wherein Ar represents a phenyl group, a naphthyl group, or an aromatic heterocyclic group, any one of which may have a substituent bonded to the nucleus, said substituent may be a halogen atom, a cyano group, a trifluoromethyl group, an alkyl group, an aryl group, an alkoxycarbonyl group, a carbamoyl group, or a sulfamoyl group; R1 and R2 independently represent an alkyl group, an alkenyl group, or an aryl group, or R1 and R2 may be linked to each other so as to form a heterocycle.

  本发明公开了一种热敏记录材料，它具有优异的耐光性和原材料储存性。该材料包括一个支架和一个设置在支架上的热敏记录层，热敏记录层包含一个重氮化合物和一个耦合剂。耦合剂包含至少一种由下式（1）表示的吡唑酮化合物： 其中 Ar 代表苯基、萘基或芳香杂环基，其中任何一个基团的核上都可以键合一个取代基，所述取代基可以是卤素原子、氰基、三氟甲基、烷基、芳基、烷氧羰基、氨基甲酰基或氨基磺酰基；R1 和 R2 独立地代表一个烷基、一个烯基或一个芳基，或者 R1 和 R2 可以相互连接以形成一个杂环。
• Borate compound, and photopolymerizable composition and recording material which contain the same
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP1035124A1

  公开（公告）日：2000-09-13

  The present invention provides a novel borate compound and a recording material comprising thereof in a photopolymerizable composition in a recording layer. The novel borate compound is represented by the following general formula (I): General formula (I) wherein R1 represents an alkyl group which may have a substituent; R2, R3 and R4 each represents an aryl group represented by the following general formula (II); and Z+ represents a group capable of forming a cation, General formula (II) wherein R5 represents an electron donative group; and R6 to R9 each represents a substituent, the total Hammett substituent σ constant of R5 to R9 being from 0 to 1.

  本发明提供了一种新型硼酸盐化合物和一种记录材料，在记录层中的可光聚合组合物中含有该化合物。新型硼酸盐化合物由以下通式（I）表示： 通式（I） 其中 R1 代表可具有取代基的烷基；R2、R3 和 R4 分别代表由以下通式（II）表示的芳基；Z+ 代表可形成阳离子的基团、 通式 (II) 其中 R5 代表一个电子捐赠基团；R6 至 R9 各代表一个取代基，R5 至 R9 的总 Hammett 取代基 σ 常数为 0 至 1。
• Photopolymerizable composition and recording material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：EP1298490A2

  公开（公告）日：2003-04-02

  The present invention provides a photopolymerizable composition containing a polymerizable compound having an ethylenically unsaturated bond, a compound represented by the following general formula (I), and a radical generating agent capable of generating a radical by interacting with the compound represented by the following general formula (I). General Formula (I); In the general formula (I), R1, R2, and R3 each individually represent a hydrogen atom or a monovalent substituent; R4 represents at least one member selected from the group consisting of: a hydrogen atom, an aliphatic group, an aromatic group, and a heterocyclic group; Z1 represents a substituent necessary for allowing the compound represented by the general formula (I) to become a dye; and X- represents a group capable of forming an anion. The invention also provides a recording material in which a recording layer containing the photopolymerizable composition is provided on a support.

  本发明提供了一种可光聚合组合物，该组合物含有一种具有乙烯不饱和键的可聚合化合物、一种由以下通式(I)表示的化合物，以及一种能够通过与以下通式(I)表示的化合物相互作用而生成自由基的自由基生成剂。通式（I）； 在通式（I）中，R1、R2 和 R3 分别代表氢原子或一价取代基；R4 代表至少一个选自氢原子、脂肪族基团、芳香族基团和杂环基团的成员；Z1 代表使通式（I）所代表的化合物成为染料所必需的取代基；X- 代表能够形成阴离子的基团。本发明还提供了一种记录材料，在该记录材料中，含有可光聚合组合物的记录层被设置在支持物上。
• Azomethine dye precursor, image-forming material, and image-forming method
  申请人：——

  公开号：US20010019806A1

  公开（公告）日：2001-09-06

  The present invention related to an azomethine dye precursor represented by the following general formula (1) and the image-forming material and image-forming method using the azomethine dye precursor: wherein Ar represents an aryl group or a heterocyclic group which may each have a substituent; X represents a bivalent group linking a carbon atom and a nitrogen atom; and Cp represent a coupler residue which may or may not form a ring. General formula 1

  本发明涉及由以下通式（1）表示的偶氮亚甲基染料前体以及使用该偶氮亚甲基染料前体的成象材料和成象方法： 其中 Ar 代表芳基或杂环基，它们可以各自具有一个取代基；X 代表连接碳原子和氮原子的二价基团；Cp 代表耦合剂残基，它可以形成环，也可以不形成环。 通式 1