(E)-1-phenyl-2-(O-benzoyloxime)-1,2-propandione | 28867-82-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-1-phenyl-2-(O-benzoyloxime)-1,2-propandione
• 英文别名: 1-phenyl-1,2-propanedione-2-(O-benzoyl)oxime；1-phenyl-1,2-propandione 2-O-benzoyloxime；1-phenyl-1,2-propanedion-2-O-benzoyloxime；[(1-Oxo-1-phenylpropan-2-ylidene)amino]benzoate；[(E)-(1-oxo-1-phenylpropan-2-ylidene)amino] benzoate
• CAS: 28867-82-5
• 化学式: C₁₆H₁₃NO₃
• 分子量: 267.284
• InChiKey: ZNZDJSGUWLGTLA-SFQUDFHCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  55.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (E)-1-phenyl-2-(O-benzoyloxime)-1,2-propandione 以 乙腈 为溶剂， 以19%的产率得到(Z)-1-phenyl-2-(O-benzoyloxime)-1,2-propandione
  参考文献：
  名称：

  Application of FT-Raman spectroscopy to the study of polymerization photoinitiators Part 1: On the conformation of 1-phenyl-2-(O-benzoyloxime)-1,2-propandiones

  摘要：

  This paper reports for the first time the FT-Raman and FTIR spectra of the (E) and (Z) isomers of the photoinitiator 1-phenyl-2-(O-benzoyloxime)-1,2-propandione. The methods employed for the determination of the configurational and conformational structures of these O-acyl-alpha-oxooximes is discussed. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s1386-1425(97)00169-8
• 作为产物：
  描述：

  2-异亚硝基苯丙酮 在 N-甲基咪唑 、 N,N,N',N'-tetramethylchloroformamidinium hexafluorophosphate 作用下， 以 乙腈 为溶剂， 以44 %的产率得到(E)-1-phenyl-2-(O-benzoyloxime)-1,2-propandione
  参考文献：
  名称：

  C-C 键断裂诱导的 C- 至 N-酰基转移用于酰胺的合成

  摘要：

  开发了一种制备酰胺的新方法，使用 C-C 键断裂引发 C- 到 N- 酰基转移，采用活化酮作为酰化试剂和胺亲核试剂。该反应在常用于肽键形成的偶联试剂系统下进行。该方法使得能够在温和条件下使用线性和环状酮底物实际制备酰胺。

  DOI：

  10.1021/acs.orglett.4c01154

文献信息

• CURABLE COMPOSITION, CURED PRODUCT, COLOR FILTER, METHOD FOR PRODUCING COLOR FILTER, SOLID-STATE IMAGING ELEMENT, AND IMAGE DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20200385582A1

  公开（公告）日：2020-12-10

  Provided are a curable composition including a compound represented by Formula 1 and having a maximum absorption wavelength in a range of 600 nm or more and less than 700 nm, or a polymer having a structure represented by Formula 2 and having a maximum absorption wavelength in a range of 600 nm or more and less than 700 nm; a polymerizable compound; and a chromatic colorant different from the compound represented by Formula 1 and the polymer represented by Formula 2, as well as a cured product of the curable composition; a color filter including the cured product; a method for producing a color filter; a solid-state imaging element; and an image display device.

  提供一种可治愈的组合物，包括由式1表示的化合物，其最大吸收波长在600纳米或更大且小于700纳米范围内，或者具有由式2表示的结构的聚合物，其最大吸收波长在600纳米或更大且小于700纳米范围内；一种可聚合的化合物；和一种与式1表示的化合物和式2表示的聚合物不同的色素染料，以及所述可治愈组合物的固化产物；包括所述固化产物的彩色滤光片；生产彩色滤光片的方法；固态成像元件；和图像显示装置。
• COMPOSITION, CURED PRODUCT, COLOR FILTER, METHOD FOR PRODUCING COLOR FILTER, SOLID-STATE IMAGING ELEMENT, IMAGE DISPLAY DEVICE, AND COMPOUND
  申请人：FUJIFILM Corporation

  公开号：US20200392343A1

  公开（公告）日：2020-12-17

  Provided are a composition including a compound represented by Formula 1 and having a maximum absorption wavelength in a range of 600 nm or more and less than 750 nm and a polymerizable compound; as well as a cured product of the composition, a color filter including the cured product, a method for producing the color filter, a solid-state imaging element including the color filter, an image display device including the color filter, and a compound. In Formula 1, Z's each independently represent a specific group, n represents an integer of 4 to 16, and R's each independently represent a hydrogen atom or a monovalent substituent which is different from Z, m represents an integer of 0 to 12, and m+n is 16.

  提供了一个组合物，包括由式1表示的化合物，其具有最大吸收波长在600纳米或更大且小于750纳米的范围内，以及一种可聚合的化合物；以及该组合物的固化产物，包括该固化产物的彩色滤光片，制备该彩色滤光片的方法，包括该彩色滤光片的固态成像元件，包括该彩色滤光片的图像显示装置，以及一种化合物。在式1中，Z分别独立表示特定基团，n表示4到16的整数，R分别独立表示氢原子或与Z不同的一价取代基，m表示0到12的整数，且m+n为16。
• COLORING COMPOSITION, METHOD FOR PRODUCING FILM, METHOD FOR PRODUCING COLOR FILTER, METHOD FOR PRODUCING SOLID-STATE IMAGING ELEMENT, AND METHOD FOR PRODUCING IMAGE DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20200263037A1

  公开（公告）日：2020-08-20

  A coloring composition includes a metal azo pigment, a polymerizable compound, and a solvent, the metal azo pigment includes at least one kind of an anion selected from an azo compound represented by Formula (I) or an azo compound having a tautomeric structure of the azo compound represented by Formula (I), two or more kinds of metal ions, and a melamine compound, and in Formula (I), R 1 and R 2 each independently represent OH or NR 5 R 6 , R 3 and R 4 each independently represent ═O or ═NR 7 , and R 5 to R 7 each independently represent a hydrogen atom or an alkyl group.

  一种着色组合物包括金属偶氮颜料、可聚合化合物和溶剂，金属偶氮颜料包括至少一种从由化学式（I）表示的偶氮化合物或具有由化学式（I）表示的偶氮化合物的互变异构体结构中选择的阴离子，两种或两种以上的金属离子和三聚氰胺化合物，其中在化学式（I）中，R1和R2各自独立地表示OH或NR5R6，R3和R4各自独立地表示═O或═NR7，R5到R7各自独立地表示氢原子或烷基基团。
• CURABLE COMPOSITION, CURED FILM, OPTICAL FILTER, SOLID IMAGE PICKUP ELEMENT, IMAGE DISPLAY DEVICE, INFRARED SENSOR, DISPERSING AUXILIARY AGENT, DISPERSION, AND METHOD OF MANUFACTURING DISPERSION
  申请人：FUJIFILM Corporation

  公开号：US20200115382A1

  公开（公告）日：2020-04-16

  Provided are a curable composition, a cured film, an optical filter, a solid image pickup element, an image display device, an infrared sensor, a dispersing auxiliary agent, a dispersion, and a method of manufacturing a dispersion. With the curable composition, a cured film having excellent moisture resistance in which the formation of an aggregate derived from a compound having a colorant skeleton is suppressed can be formed. This curable composition includes: a compound A having a structure in which at least one functional group selected from an acid group having a pKa of 3 or lower and a Clog P value of −1.1 or higher, an anionic group obtained by dissociating one or more hydrogen atoms from the acid group, or a salt of the acid group is bonded to a π-conjugated structure of a colorant skeleton and having a maximum absorption wavelength in a wavelength range of 650 to 1200 nm; a curable compound; and a solvent.

  提供了一种可治愈的组合物、治愈膜、光学滤光片、固态图像拾取元件、图像显示装置、红外传感器、分散辅助剂、分散液以及一种制备分散液的方法。利用这种可治愈的组合物，可以形成具有优异耐潮性的治愈膜，其中抑制了由具有色素骨架的化合物衍生的聚集体的形成。这种可治愈的组合物包括：一种化合物A，其结构中至少有一种功能基团，选自具有pKa值为3或更低和Clog P值为-1.1或更高的酸基团、从该酸基团中解离出一个或多个氢原子得到的阴离子基团，或该酸基团的盐，与色素骨架的π共轭结构结合，并在650至1200纳米波长范围内具有最大吸收波长；一种可治愈的化合物；和一种溶剂。
• COMPOSITION, FILM, NEAR INFRARED CUT FILTER, LAMINATE, PATTERN FORMING METHOD, SOLID IMAGE PICKUP ELEMENT, IMAGE DISPLAY DEVICE, INFRARED SENSOR, AND COLOR FILTER
  申请人：FUJIFILM Corporation

  公开号：US20180305552A1

  公开（公告）日：2018-10-25

  The composition includes two or more near infrared absorbing compounds having an absorption maximum in a wavelength range of 650 to 1000 nm and having a solubility of 0.1 mass % or lower in water at 23° C., in which the two or more near infrared absorbing compounds include a first near infrared absorbing compound having an absorption maximum in a wavelength range of 650 to 1000 nm, and a second near infrared absorbing compound having an absorption maximum in a wavelength range of 650 to 1000 nm which is shorter than the absorption maximum of the first near infrared absorbing compound, and a difference between the absorption maximum of the first near infrared absorbing compound and the absorption maximum of the second near infrared absorbing compound is 1 to 150 nm.

  该组合物包括两种或更多在波长范围为650到1000纳米具有吸收峰值的近红外吸收化合物，并且在23°C下其在水中的溶解度为0.1质量%或更低。其中，这两种或更多的近红外吸收化合物包括第一种在波长范围为650到1000纳米具有吸收峰值的近红外吸收化合物，以及第二种在波长范围为650到1000纳米具有比第一种近红外吸收化合物吸收峰值更短的吸收峰值的近红外吸收化合物，第一种近红外吸收化合物的吸收峰值与第二种近红外吸收化合物的吸收峰值之间的差值为1到150纳米。