[1-Methyl-but-(E)-ylidene]-phenyl-amine | 56037-28-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1-Methyl-but-(E)-ylidene]-phenyl-amine
• CAS: 56037-28-6
• 化学式: C₁₁H₁₅N
• 分子量: 161.247
• InChiKey: KILNUWWYMPVVRK-ZRDIBKRKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.58
• 重原子数：
  12.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  靛红酸酐 、 溶剂黄146 、 [1-Methyl-but-(E)-ylidene]-phenyl-amine 以53%的产率得到
  参考文献：
  名称：

  BHASKAR RAO V.; RATNAM C. V., INDIAN J. CHEM., 1979, B18, NO 5, 409-412

  摘要：

  DOI：
• 作为产物：
  描述：

  N-[(E)-pentan-2-ylideneamino]aniline 以20%的产率得到
  参考文献：
  名称：

  TSUBOI, MASAKI;TAKEBE, KAZUO;FUJITA, IYOMI, NIPPON KAGAKU KAJSI,(1989) N, S. 302-304

  摘要：

  DOI：

文献信息

• Water soluble chiral diphoshpines
  申请人：——

  公开号：US20040102649A1

  公开（公告）日：2004-05-27

  The invention concerns a water soluble compound of formula (a) wherein: A represents naphthyl or phenyl; and Ar 1 and Ar 2 independently represent a saturated or aromatic carbocyclic group; X a , X b are independently selected among an amino group, an ammonium group and an amino group modified by a linear polyoxyalkylene chain, provided that at least one of X a and X b represents ammonium or modified amino.

  本发明涉及一种水溶性化合物，其化学式为（a），其中：A代表萘基或苯基；Ar1和Ar2分别代表饱和或芳香环烃基；Xa，Xb分别独立地选自氨基，铵基和通过线性聚氧烷链修饰的氨基，但至少其中之一代表铵基或修饰氨基。
• Catalytic Hydroamination of Alkynes and Norbornene with Neutral and Cationic Tantalum Imido Complexes
  作者：Laura L. Anderson、John Arnold、Robert G. Bergman

  DOI：10.1021/ol0492851

  日期：2004.7.1

  [reaction: see text] Several tantalum imido complexes have been synthesized and shown to efficiently catalyze the hydroamination of internal and terminal alkynes. An unusual hydroamination/hydroarylation reaction of norbornene catalyzed by a highly electrophilic cationic tantalum imido complex is also reported. Factors affecting catalyst activity and selectivity are discussed along with mechanistic

  [反应：见正文]已合成了几种亚胺钽配合物，并显示可有效催化内部和末端炔烃的加氢胺化反应。还报道了由高度亲电的阳离子钽亚胺配合物催化的降冰片烯的不寻常的加氢/加氢芳基化反应。讨论了影响催化剂活性和选择性的因素，以及从化学计量反应中获得的机理见解。
• Process for preparing chiral diphosphines
  申请人：RHODIA CHIMIE

  公开号：US20030225297A1

  公开（公告）日：2003-12-04

  Compounds of formula VII are described: 1 wherein A represents phenyl or naphthyl and Ar 1 and Ar 2 independently represent a saturated or aromatic carbocyclic group. The compounds may be prepared by reducing the nitrile functions of a compound of formula I: 2

  描述了式 VII 的化合物： 1 其中 A 代表苯基或萘基，且 Ar 1 和 Ar 2 分别代表饱和或芳香碳环基团。这些化合物可通过还原式 I 化合物的腈基官能团来制备： 2
• Enantioselective Hydrogenation of Imines with Chiral (Phosphanodihydrooxazole)iridium Catalysts
  作者：Patrick Schnider、Guido Koch、Roger Prétôt、Guozhi Wang、Frank Michael Bohnen、Carl Krüger、Andreas Pfaltz

  DOI：10.1002/chem.19970030609

  日期：1997.6

  AbstractCationic iridium(I) complexes of chiral phosphanodihydrooxazoles were used as catalysts for the enantioselective hydrogenation of prochiral N‐alkyl and N‐aryl imines. The complexes are air‐stable crystalline solids that can be readily prepared and are easy to handle. The structures of two complexes were determined by X‐ray analysis. For N‐alkyl imines of acetophenone, enantiomeric excesses of up to 79% were obtained. Dialkyl ketimines and cyclic imines showed lower reactivity and selectivity. A remarkable dilution effect was observed for the hydrogenation of the N‐phenyl imine of acetophenone: decreasing the substrate and catalyst concentration led to a significant improvement of the enantioselectivity. Thus, up to 89% ee could be achieved using 0.1 mol% of catalyst. The highest enantioselectivities were obtained in weakly coordinating solvents such as CH2Cl2. Additives such as halides, imides, or amines were found to poison the catalyst. Hydrogen pressures of 100 bar were usually employed, but in some cases identical results were achieved with only 1 bar H2.
• TSUBOI, MASAKI;TAKEBE, KAZUO;FUJITA, IYOMI, NIPPON KAGAKU KAJSI,(1989) N, S. 302-304
  作者：TSUBOI, MASAKI、TAKEBE, KAZUO、FUJITA, IYOMI

  DOI：——

  日期：——