1-Acryloylamino-anthrachinon | 4420-29-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-Acryloylamino-anthrachinon
• 英文别名: N-(9,10-dioxoanthracen-1-yl)prop-2-enamide
• CAS: 4420-29-5
• 化学式: C₁₇H₁₁NO₃
• 分子量: 277.279
• InChiKey: NUNGQDWKSCLIDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  氨基-9,10-蒽二酮 以 1,4-二氧六环 为溶剂， 生成 1-Acryloylamino-anthrachinon
  参考文献：
  名称：

  Voloshin,G.A.; Boldyrev,B.G., Journal of Organic Chemistry USSR (English Translation), 1968, vol. 4, # 7, p. 1228 - 1232

  摘要：

  DOI：

文献信息

• Ethylenically-unsaturated blue anthraquinone dyes
  申请人：Pearson Clay Jason

  公开号：US20050044644A1

  公开（公告）日：2005-03-03

  This invention pertains to certain novel colorant compounds containing one or more ethylenically-unsaturated, photopolymerizable radicals that may be copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers. Suitable compositions having the present colorants copolymerized therein include, e.g., polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for preparing the photopolymerizable colorant compounds. The ethylenically unsaturated colorant compounds may be suitable for use in coatings that are applied to wood, glass, metal, thermoplastics and the like.

  本发明涉及某些新颖的着色剂化合物，其中含有一个或多个乙烯基不饱和的光聚合基团，可以与乙烯基不饱和单体共聚合（或固化），以产生着色组合物，例如着色丙烯酸聚合物。在其中共聚合了现有着色剂的适当组合物包括，例如，由丙烯酸酯和甲基丙烯酸酯制成的聚合物，着色聚苯乙烯以及从其他乙烯基不饱和单体衍生的类似着色聚合材料。本发明还涉及制备光聚合着色剂化合物的过程。乙烯基不饱和着色剂化合物可以适用于涂覆于木材，玻璃，金属，热塑性塑料等表面的涂层中。
• Ethylenically-unsaturated red anthraquinone dyes
  申请人：Pearson Clay Jason

  公开号：US20050049425A1

  公开（公告）日：2005-03-03

  This invention pertains to certain novel red anthraquinone colorant compounds containing one or more ethylenically-unsaturated (e.g., vinyl), photopolymerizable radicals that may be copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers. Suitable compositions having the present colorants copolymerized therein include, e.g., polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The novel colorants possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers and good color strength. The present invention also pertains to processes for preparing the photopolymerizable colorant compounds. The ethylenically unsaturated colorant compounds may be suitable for use in coatings that are applied to wood, glass, paper, metal, thermoplastics and the like.

  本发明涉及某些新颖的红色蒽醌着色剂化合物，其中包含一种或多种乙烯基不饱和（例如乙烯基）的光聚合基团，这些基团可以与乙烯基不饱和单体共聚合（或固化），以产生彩色组合物，例如彩色丙烯酸聚合物。适当的组合物中包括聚丙烯酸酯和甲基丙烯酸酯制成的聚合物，彩色聚苯乙烯以及从其他乙烯基不饱和单体中衍生的类似彩色聚合物材料。新颖的着色剂具有良好的紫外光（UV）稳定性，良好的乙烯基单体溶解性和良好的色彩强度。本发明还涉及制备光聚合色素化合物的方法。乙烯基不饱和着色剂化合物可适用于涂层，该涂层应用于木材、玻璃、纸张、金属、热塑性塑料等材料上。
• Reactive anthraquinone colorant compounds and polymeric materials reacted therewith
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP1304360A1

  公开（公告）日：2003-04-23

  Disclosed are blue, diol anthraquinone blue colorant compounds having excellent thermal stability and which can be reacted into or copolymerized with polyester thus providing a blue-colored polyesters useful for manufacturing a variety of shaped articles such as photographic film base, particularly roentgenographic (X-ray) film. Also disclosed are blue anthraquinone colorant compounds which contain two ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be derived from the aforesaid diol anthraquinone compounds. The anthraquinone colorant compounds containing two ethylenically-unsaturated may be reacted into or copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored vinyl polymers.

  已公开的蓝色二元醇蒽醌着色剂化合物具有优异的热稳定性，可与聚酯反应或共聚，从而提供一种蓝色聚酯，可用于制造各种形状的物品，如照相胶卷片基，特别是射线照相（X 射线）胶卷。此外，还公开了蓝色蒽醌着色剂化合物，该化合物含有两个乙烯基不饱和（乙烯基）可光聚合基，可从上述二元醇蒽醌化合物中衍生出来。含有两个乙烯基不饱和的蒽醌着色剂化合物可与乙烯基不饱和单体反应或共聚（或固化），生成彩色乙烯基聚合物。
• Anthraquinone colorants containing copolymerizable vinyl groups
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP1310527A2

  公开（公告）日：2003-05-14

  Disclosed are thermally-stable, red, anthraquinone colorants which contain one or more ethylenically-unsaturated, photopolymerizable radicals and which may be copolymerized with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The compounds possess good stability to ultraviolet light, good solubility in vinyl monomers, good color strength and thermal stability. Also disclosed are acrylic polymeric materials, i.e., polymers derived from acrylic acid esters, methacrylic acid esters and/or other copolymerizable vinyl compounds, having copolymerized therein one or more of the colorant compounds of the present invention.

  本发明公开了热稳定的红色蒽醌着色剂，该着色剂含有一个或多个乙烯不饱和、可光聚合的自由基，可与乙烯不饱和单体共聚，生产出有色组合物，如有色丙烯酸聚合物、有色聚苯乙烯以及由其他乙烯不饱和单体衍生的类似有色聚合物材料。这些化合物具有良好的紫外线稳定性、在乙烯基单体中的良好溶解性、良好的着色强度和热稳定性。同时公开的还有丙烯酸聚合物材料，即由丙烯酸酯、甲基丙烯酸酯和/或其它可共聚的乙烯基化合物衍生的聚合物，其中共聚了一种或多种本发明的着色剂化合物。
• Colorant compounds containing copolymerizable vinyl groups
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP1739135A2

  公开（公告）日：2007-01-03

  Disclosed are novel colorant compounds which contain one or more ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic coatings and polymers, e.g., coatings and polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for the preparation of certain of the photopolymerizable colorant compounds.

  本发明公开了新型着色剂化合物，该化合物含有一种或多种乙烯基不饱和（乙烯基）、可光聚合的自由基，可与乙烯基不饱和单体共聚（或固化），以生产彩色组合物，如彩色丙烯酸涂料和聚合物，例如由丙烯酸酯和甲基丙烯酸酯生产的涂料和聚合物、彩色聚苯乙烯以及由其他乙烯基不饱和单体衍生的类似彩色聚合物材料。本发明还涉及某些可光聚合着色剂化合物的制备工艺。