1-Azidoselanyl-2,3,4,5,6-pentafluorobenzene | 385808-66-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Azidoselanyl-2,3,4,5,6-pentafluorobenzene
• 英文别名: 1-azidoselanyl-2,3,4,5,6-pentafluorobenzene
• CAS: 385808-66-2
• 化学式: C₆F₅N₃Se
• 分子量: 288.038
• InChiKey: HIQPQQRLLYRXCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.94
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  14.4
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  pentafluorobenzeneselenenyl chloride 在 叠氮基三甲基硅烷 作用下， 以 二氯甲烷 为溶剂， 生成 1-Azidoselanyl-2,3,4,5,6-pentafluorobenzene
  参考文献：
  名称：

  Chemistry of C₆F₅SeLi and C₆F₅SeCl: Precursors to New Pentafluorophenylselenium(II) Compounds

  摘要：

  Pentafluorobenzeneselenenyl chloride, C6F5SeCl, was reacted with various nitrogen and chalcogen substituted trimethylsilyl nucleophiles. The products, C6F5SeSCN, C6F5SeNSO, (C6F5Se)(2)NMe, C6F5SeN(Me)SiMe3, (C6F5Se)(2)S and (C6F5Se)(2)Se, were characterized by spectroscopic methods. The reaction of C6F5SeLi with Me(3)XHal compounds gave the products C6F5SeXMC3 (X = Si, Ge, Sn, Pb). The molecular structure of (C6F5Se)(2)S has been determined by X-ray diffraction.

  DOI：

  10.1515/znb-2004-0511

文献信息

• Klapoetke, Thomas M.; Krumm, Burkhard; Mayer, Peter, Phosphorus, Sulfur and Silicon and the Related Elements, 2001, vol. 171-172, p. 119 - 128
  作者：Klapoetke, Thomas M.、Krumm, Burkhard、Mayer, Peter、Polborn, Kurt、Ruscitti, Oliver P.

  DOI：——

  日期：——
• Chemistry of C₆F₅SeLi and C₆F₅SeCl: Precursors to New Pentafluorophenylselenium(II) Compounds
  作者：Thomas M. Klapötke、Burkhard Krumm、Peter Maye

  DOI：10.1515/znb-2004-0511

  日期：2004.5.1

  Pentafluorobenzeneselenenyl chloride, C6F5SeCl, was reacted with various nitrogen and chalcogen substituted trimethylsilyl nucleophiles. The products, C6F5SeSCN, C6F5SeNSO, (C6F5Se)(2)NMe, C6F5SeN(Me)SiMe3, (C6F5Se)(2)S and (C6F5Se)(2)Se, were characterized by spectroscopic methods. The reaction of C6F5SeLi with Me(3)XHal compounds gave the products C6F5SeXMC3 (X = Si, Ge, Sn, Pb). The molecular structure of (C6F5Se)(2)S has been determined by X-ray diffraction.