(9,10-dioxo-9,10-dihydro-1-anthrylaminato-N)(triphenylphosphine-P)gold | 204253-91-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (9,10-dioxo-9,10-dihydro-1-anthrylaminato-N)(triphenylphosphine-P)gold
• CAS: 204253-91-8
• 化学式: C₃₂H₂₃AuNO₂P
• 分子量: 681.48
• InChiKey: FQKZQRFAYBYNTF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate 、 氨基-9,10-蒽二酮 在 K₂CO₃ 作用下， 以 not given 为溶剂， 生成 (9,10-dioxo-9,10-dihydro-1-anthrylaminato-N)(triphenylphosphine-P)gold
  参考文献：
  名称：

  (9,10-Dioxo-9,10-dihydro-1-anthrylaminato-N)(triphenylphosphine-P)gold

  摘要：

  In the title compound, [Au(C14H8NO2)(C18H15P)],, the AuPPh3 group is located at the amino group. The Au-N and Au-P distances are 2.019(3) and 2.2420(8)Angstrom, respectively. The amino group H atom is involved in an intramolecular hydrogen bond with a carbonyl O atom. The bond-length distribution in the aminoanthraquinone ligand is slightly different from that in the free ligand, manifesting itself as a more pronounced contribution from the quinoid structure.

  DOI：

  10.1107/s0108270197012985