1-[(Z)-1,3,3-Trimethyl-1,3-dihydro-indol-(2Z)-ylidenemethylimino]-1H-naphthalen-2-one | 141480-64-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-[(Z)-1,3,3-Trimethyl-1,3-dihydro-indol-(2Z)-ylidenemethylimino]-1H-naphthalen-2-one
• CAS: 141480-64-0
• 化学式: C₂₂H₂₀N₂O
• 分子量: 328.414
• InChiKey: WXHGLVYAXBDLGH-YWMIBRPGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.34
• 重原子数：
  25.0
• 可旋转键数：
  1.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  32.67
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  1,3,3-三甲基吲哚-奈谔嗪 以 甲醇 为溶剂， 生成 merocyanine 、 1-[(Z)-1,3,3-Trimethyl-1,3-dihydro-indol-(2Z)-ylidenemethylimino]-1H-naphthalen-2-one 、 1-[(E)-1,3,3-Trimethyl-1,3-dihydro-indol-(2E)-ylidenemethylimino]-1H-naphthalen-2-one 、 1-[(E)-1,3,3-Trimethyl-1,3-dihydro-indol-(2Z)-ylidenemethylimino]-1H-naphthalen-2-one
  参考文献：
  名称：

  Schneider, Siegfried, Zeitschrift fur physikalische Chemie (Neue Folge), 1987, vol. 154, p. 91 - 120

  摘要：

  DOI：

文献信息

• Photochromic Polymer and Composition Comprising Photochromic Polymer
  申请人：Evans Richard Alexander

  公开号：US20110147681A1

  公开（公告）日：2011-06-23

  A photochromic polymer comprising at least one siloxane oligomer and at least two photochromic groups covalently linked to one or both terminuses of the siloxane oligomer and compositions containing photochromic siloxane polymers with narrow polydispersity. The photochromic polymer enhances switching speed in rigid host polymers.

  一种光致变色聚合物，包括至少一个硅氧烷寡聚物和至少两个光致变色基团，与硅氧烷寡聚物的一个或两个端点共价连接，并且含有具有狭窄聚分散度的光致变色硅氧烷聚合物的组合物。该光致变色聚合物可以提高刚性主体聚合物的切换速度。
• Photochromic compositions and articles comprising siloxane, alkylene or substituted alkylene oligomers
  申请人：Evans Alexander Richard

  公开号：US20070187656A1

  公开（公告）日：2007-08-16

  This invention relations to a polymerizable composition for forming a photochromic article of glass transition temperature of at least 50 ° C. on curing, the composition comprising: (a) a polymerizable composition comprising a monomer component or resin formed therefrom; and (b) a photochromic dye monomer comprising a photochromic moiety and at least one oligomeric group having at least one group reactive with the monomer component during or following curing wherein the oligomer group comprises a multiplicity of monomer units selected from siloxane, alkylene and substituted alkylene.

  本发明涉及一种可聚合组合物，用于形成玻璃化转变温度至少为50℃的光致变色物品，所述组合物包括：(a)一种聚合物组合物，包括单体组分或由其形成的树脂；以及(b)一种光致变色染料单体，包括一个光致变色基团和至少一个具有至少一个与单体组分在固化期间或固化后反应的寡聚物基团，其中寡聚物基团包括从硅氧烷、烷基和取代烷基中选择的多种单体单元。
• Photochromic Compositions and Light Transmissible Articles
  申请人：Evans Alexander Richard

  公开号：US20080006798A1

  公开（公告）日：2008-01-10

  The invention relates to a photochromic polymeric composition comprising a polymer matrix and a photochromic compound which is an adduct comprising a photochromic moiety and at least one pendant oligomer group to provide a rate of fade of the photochromic polymeric composition which is significantly changed when compared with the corresponding composition comprising the photochromic compound without said pendent oligomer. The invention also relates to a photochromic compound which is an adduct comprising a photochromic moiety and at least one pendent oligomer.

  本发明涉及一种光致变色聚合物组合物，包括聚合物基质和光致变色化合物。该化合物是一种加合物，包括光致变色基团和至少一个挂链寡聚物基团，以提供与不含上述挂链寡聚物的光致变色化合物相比，光致变色聚合物组合物的退色速率显著改变的速率。本发明还涉及一种光致变色化合物，它是一种加合物，包括光致变色基团和至少一个挂链寡聚物基团。
• PHOTOCHROMIC COMPOSITIONS AND ARTICLES COMPRISING SILOXANE, ALKYLENE OR SUBSTITUTED ALKYLENE OLIGOMERS
  申请人：Advanced Polymerik Pty Ltd

  公开号：EP1740629B1

  公开（公告）日：2011-03-30
• US7247262B2
  申请人：——

  公开号：US7247262B2

  公开（公告）日：2007-07-24