10-diethylaminomethylanthracene | 35693-48-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 10-diethylaminomethylanthracene
• 英文别名: 9-diethylaminomethylanthracene；(Anthracen-9-ylmethyl)diethylamine at 100K；N-(anthracen-9-ylmethyl)-N-ethylethanamine
• CAS: 35693-48-2
• 化学式: C₁₉H₂₁N
• 分子量: 263.382
• InChiKey: LMUQNGRLTYCQDA-UHFFFAOYSA-N

物化性质

• 沸点：
  402.5±14.0 °C(Predicted)
• 密度：
  1.065±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-甲基蒽 、 二乙胺 生成 10-diethylaminomethylanthracene
  参考文献：
  名称：

  使用叔氨基作为取代基来稳定化合物抵抗单线态氧的攻击

  摘要：

  已经显示出各自具有与烯烃系统绝缘的叔氨基取代基的烯烃，二氢吡喃，呋喃和蒽对于由亚甲基蓝的甲醇溶液的辐照产生的单线态氧特别稳定。稳定性归因于氨基猝灭单线态氧。在2-甲基呋喃和蒽的溶液中添加三乙胺或1,4-二氮杂双环[2,2,2]辛烷也降低了后者化合物的氧化速率，但效率低得多。

  DOI：

  10.1039/p19730000960

文献信息

• [EN] SUBSTITUTED PYRIDONES AS INHIBITORS OF POLY(ADP-RIBOSE) POLYMERASE (PARP)<br/>[FR] PYRIDONES SUBSTITUES INHIBITEURS DE LA POLY(ADP-RIBOSE) POLYMERASE (PARP)
  申请人：AVENTIS PHARMA INC

  公开号：WO2005097750A1

  公开（公告）日：2005-10-20

  The present invention discloses and claims a series of 2,3,5-substituted pyridone derivatives as defined herein. This invention also relates to methods of making these compounds. The compounds of this invention are inhibitors of poly(adenosine 5'-diphosphate ribose) polymerase (PARP) and are therefore useful as pharmaceutical agents, especially in the treatment and/or prevention of a variety of diseases, including diseases associated with the central nervous system and cardiovascular disorders.

  本发明公开并声明了一系列如下定义的2,3,5-取代吡啶酮衍生物。本发明还涉及制备这些化合物的方法。本发明的化合物是多聚腺苷酸二磷酸核糖酶（PARP）的抑制剂，因此在制药剂中特别用于治疗和/或预防各种疾病，包括与中枢神经系统和心血管疾病相关的疾病。
• The first fluorescent sensor for boronic and boric acids with sensitivity at sub-micromolar concentrations
  作者：Wei Wang、Greg Springsteen、Shouhai Gao、Binghe Wang

  DOI：10.1039/b002089n

  日期：——

  An anthracene-based PET sensor which uses a diethanolamine recognition site is selective for boronic and boric acids, showing up to a 19-fold fluorescent intensity enhancement upon binding.

  一种基于蒽的 PET 传感器使用二乙醇胺识别位点，对硼酸和硼酸具有选择性，结合后荧光强度最多可增强 19 倍。
• REVERSIBLE THERMOCHROMIC COMPOSITION, REVERSIBLE THERMOCHROMIC MICROCAPSULE PIGMENT COMPRISING SAME, AND WRITING INSTRUMENT USING SAME
  申请人：THE PILOT INK CO., LTD.

  公开号：EP3950068A1

  公开（公告）日：2022-02-09

  [Problems] Provided are a highly marketable reversibly thermochromic composition that provides a black color during color development by using a fluoran derivative having a specific structure as an electron-donating color-developing organic compound, turns colorless during decoloration, and is excellent in contrast between a colored state and a decolored state and a microcapsule pigment encapsulating the same. [Solution] Disclosed are a reversibly thermochromic composition including: (a) a fluoran derivative having a specific structure as an electron-donating color-developing organic compound; (b) an electron-accepting compound; and (c) a reaction medium which reversibly induces an electron transfer reaction between the component (a) and the component (b) in a specific temperature range, and a reversibly thermochromic microcapsule pigment encapsulating the same.

  [问题]提供了一种极具市场前景的可逆热致变色组合物，该组合物通过使用具有特定结构的芴衍生物作为电子捐赠显色有机化合物，在显色过程中提供黑色，在脱色过程中变成无色，并且在有色状态和脱色状态之间具有极佳的对比度，同时还提供了封装该组合物的微胶囊颜料。 [解决方案]本发明公开了一种可逆热变色组合物，包括：（a）具有特定结构的氟烷衍生物，作为电子捐赠显色有机化合物；（b）电子接受化合物；以及（c）反应介质，该介质可在特定温度范围内可逆地诱导组分（a）和组分（b）之间的电子转移反应，以及封装该组合物的可逆热变色微胶囊颜料。
• Ultraviolet light stable color-changing systems
  申请人：Chromatic Technologies, Inc.

  公开号：US11236247B2

  公开（公告）日：2022-02-01

  Disclosed herein are embodiments of (i) a novel stabilizer including a stable nitroxide free radical which can function as a light-stabilizer and/or a heat-stabilizer, and (ii) compositions including the stable nitroxide free radical.

  本文公开了以下实施例：(i) 一种新型稳定剂，包括可用作光稳定剂和/或热稳定剂的稳定亚硝基自由基；以及 (ii) 包括稳定亚硝基自由基的组合物。
• Reversible thermochromic composition
  申请人：THE PILOT INK CO., LTD.

  公开号：EP0659582B1

  公开（公告）日：1998-05-13