chloropalladium(1+);tributyl-[(E)-prop-1-enyl]stannane;triphenylphosphane | 351336-73-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chloropalladium(1+);tributyl-[(E)-prop-1-enyl]stannane;triphenylphosphane
• CAS: 351336-73-7
• 化学式: C₃₃H₄₆ClPPdSn
• 分子量: 734.285
• InChiKey: BLJYBIGJSANZRL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chloropalladium(1+);tributyl-[(E)-prop-1-enyl]stannane;triphenylphosphane 、 三苯基膦 在 氘代甲醇 作用下， 以 氘代甲醇 、 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and destannylation of η3-1-stannylallylpalladium(II) complexes

  摘要：

  Reaction of 1-tributylstannyl-3-chloropropene with a Pd(PPh3) species, generated in situ from Pd-2(dba)(3) and two equivalents of PPh3, afforded Pd(eta (3)-Bu3SnCHCHCH2)Cl(PPh3) (1). Complex 1 undenvent PPh3 promoted protodestannylation with acetic acid or diethyl malonate to give an unsubstituted eta (3)-allylpalladium moiety as either a detectable product or a reaction intermediate. The reaction of 1 with PPh3 and 0.5 equivalent of PdCl2(PhCN)(2) afforded the dinuclear complex (mu -1-3-eta (3):4-6-eta (3)- CH2CHCHCHCHCH2) {PdCl(PPh3}(2) (4) containing a hexatriene ligand, a formal vinylcarbene dimer. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00801-9
• 作为产物：
  描述：

  三苯基膦 、 tris(dibenzylideneacetone)dipalladium (0) 、 (E)-3-n-tributylstannylprop-2-enyl chloride 以 二氯甲烷 为溶剂， 以21%的产率得到chloropalladium(1+);tributyl-[(E)-prop-1-enyl]stannane;triphenylphosphane
  参考文献：
  名称：

  Synthesis and destannylation of η3-1-stannylallylpalladium(II) complexes

  摘要：

  Reaction of 1-tributylstannyl-3-chloropropene with a Pd(PPh3) species, generated in situ from Pd-2(dba)(3) and two equivalents of PPh3, afforded Pd(eta (3)-Bu3SnCHCHCH2)Cl(PPh3) (1). Complex 1 undenvent PPh3 promoted protodestannylation with acetic acid or diethyl malonate to give an unsubstituted eta (3)-allylpalladium moiety as either a detectable product or a reaction intermediate. The reaction of 1 with PPh3 and 0.5 equivalent of PdCl2(PhCN)(2) afforded the dinuclear complex (mu -1-3-eta (3):4-6-eta (3)- CH2CHCHCHCHCH2) {PdCl(PPh3}(2) (4) containing a hexatriene ligand, a formal vinylcarbene dimer. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00801-9