(10S)-11,11,11-trifluoro-10-phenylmethoxyundecanal | 783372-16-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (10S)-11,11,11-trifluoro-10-phenylmethoxyundecanal
• CAS: 783372-16-7
• 化学式: C₁₈H₂₅F₃O₂
• 分子量: 330.391
• InChiKey: XCMSHMUDIYLUOD-KRWDZBQOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  23
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (10S)-11,11,11-trifluoro-10-phenylmethoxyundecanal 、 4,4'-bis[(methyl)triphenylphosphonium bromide]-1,1'-dibenzene 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  The synthesis of enantiomerically pure novel liquid crystal compounds containing the bis(trifluoromethyl)alkanediol moiety

  摘要：

  The synthesis of two types of novel liquid crystals, which possess the optically active bis(trifluoromethyl)alkanediol moiety has been accomplished using the lipase-catalyzed reaction and the Wittig reaction as key reactions. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2004.07.021
• 作为产物：
  描述：

  (S)-11-(tert-Butyl-dimethyl-silanyloxy)-1,1,1-trifluoro-undecan-2-ol 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 生成 (10S)-11,11,11-trifluoro-10-phenylmethoxyundecanal
  参考文献：
  名称：

  The synthesis of enantiomerically pure novel liquid crystal compounds containing the bis(trifluoromethyl)alkanediol moiety

  摘要：

  The synthesis of two types of novel liquid crystals, which possess the optically active bis(trifluoromethyl)alkanediol moiety has been accomplished using the lipase-catalyzed reaction and the Wittig reaction as key reactions. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2004.07.021

文献信息

• The synthesis of enantiomerically pure novel liquid crystal compounds containing the bis(trifluoromethyl)alkanediol moiety
  作者：Yumiko Takagi、Fumi Yamana、Yousuke Sumino、Hideyuki Ito、Takashi Yoshida、Takashi Kato、Kazutoshi Miyazawa、Toshiyuki Itoh

  DOI：10.1016/j.tetasy.2004.07.021

  日期：2004.9

  The synthesis of two types of novel liquid crystals, which possess the optically active bis(trifluoromethyl)alkanediol moiety has been accomplished using the lipase-catalyzed reaction and the Wittig reaction as key reactions. (C) 2004 Elsevier Ltd. All rights reserved.