silver 1,1,1,5,5,5-hexafluoroacetylacetonate | 76122-00-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: silver 1,1,1,5,5,5-hexafluoroacetylacetonate
• 英文别名: Silber(I)-1,1,1,5,5,5-Hexafluoroacetylacetonat；Ag(1,1,1,5,5,5-Hexafluoroacetylacetonat)；Ag(hexafluoroacetylacetonate)
• CAS: 76122-00-4
• 化学式: C₅HAgF₆O₂
• 分子量: 314.92
• InChiKey: NBVYPKVMRPXDNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  双(二甲基膦)甲烷 、 silver 1,1,1,5,5,5-hexafluoroacetylacetonate 以 二氯甲烷 为溶剂， 以>90的产率得到bis(μ-bis(dimethylphosphino)methane)di(hexafluoroacetylacetonato) disilver(I)
  参考文献：
  名称：

  Yuan, Zheng; Dryden, Neil H.; Vittal, Jagadese J., Canadian Journal of Chemistry, 1994, vol. 72, # 7, p. 1605 - 1609

  摘要：

  DOI：
• 作为产物：
  描述：

  六氟乙酰丙酮 、 silver nitrate 在 三乙胺 作用下， 以98%的产率得到silver 1,1,1,5,5,5-hexafluoroacetylacetonate
  参考文献：
  名称：

  nBu3P-银 (I) -β-二酮酸盐：合成、气相研究和用作 CVD 前体

  摘要：

  nBu3P-Silver (I) -β-Diketonates：合成、气相研究及其作为 CVD 前体的用途银 (I) 盐 [AgX] 的合成（3a，X = 乙酰丙酮酸盐，acac；3b，X = 1 , 1,1,5,5,5-六氟乙酰丙酮酸盐, hfac; 3c, X = 1,3-diphenyl-1,3-propanedionate, dipa) 通过 [AgNO3] (1) 与 HX (2a, X = acac; 2b, X = hfac; 2c, X = dipa) 或 [Ag2O] (4) 与 2b。nBu3P (5) 与 3a - 3c 的添加比例分别为 1:1 和 2:1，得到磷烷银 (I) β-二酮酸盐 [(nBu3P) mAgX] (m = 1: 6a, X = acac; 6b, X = hfac; 6c, X = dipa.m = 2: 7a, X = acac; 7b, X

  DOI：

  10.1002/zaac.200500143

文献信息

• Mono- and bi-dentate carboxylato complexes of ruthenium(IV)
  作者：Brian Kavanagh、Jonathan W. Steed、Derek A. Tocher

  DOI：10.1039/dt9930000327

  日期：——

  Treatment of the ruthenium(IV) chloro-bridged dimer [Ru(eta3:eta3-C10H16)Cl(mu-Cl)}2] 1 with sodium acetate or silver acetate at room temperature in acetone gives the chelate complex [Ru(eta3:eta3-C10H16)Cl(O2CMe)] 2. Refluxing 1 in trifluoroacetic acid, or reaction of 1 at room temperature with Ag[CF3CO2] gives the monodentate, dicarboxylate species [Ru(eta3:eta3-C10H16)(O2CCF3)2(OH2)] 3, which contains a tightly bound water ligand. A range of chloro and fluoro substituted carboxylato complexes has been prepared (5-9) and the 'cross-over' point between mono- and bi-dentate co-ordination determined. The hexafluoro beta-diketonate complex [Ru(eta3:eta3-C10H16)ClF3CC(O)CHC(O)CF3}] 10, exhibits the expected bidentate mode of co-ordination. Reaction of 1 with thioacetic acid over short reaction times yields the adduct [Ru(eta3:eta3-C10H16)Cl2SC(OH)Me}] 11. The corresponding chelate species [Ru(eta3:eta3-C10H16)Cl(SOCMe)] 12, is formed over longer reaction times. Analogous reactions with thiopivalic and thiobenzoic acids result only in the isolation of the chelate products [Ru(eta3:eta3-C10H16) Cl(SOCR)] (R = Bu(t) 13 or Ph 14). The structures of complexes 2 and 3 have been verified by X-ray crystallography.
• Lang; Leschke; Melter, Zeitschrift fur Anorganische und Allgemeine Chemie, 2003, vol. 629, # 12-13, p. 2371 - 2380
  作者：Lang、Leschke、Melter、Walfort、Koehler、Schulz、Gessner

  DOI：——

  日期：——