1,10-Diamino-3-(trifluoromethyl)-3,4,4,5,5,6,6,7,7,8,8-undecafluorodecane | 149996-57-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 1,10-Diamino-3-(trifluoromethyl)-3,4,4,5,5,6,6,7,7,8,8-undecafluorodecane
• 英文别名: 1,10-Diamino-3-trifluoromethyl-3,4,4,5,5,6,6,7,7,8,8-undecafluorodecane；3,3,4,4,5,5,6,6,7,7,8-undecafluoro-8-(trifluoromethyl)decane-1,10-diamine
• CAS: 149996-57-6
• 化学式: C₁₁H₁₂F₁₄N₂
• 分子量: 438.207
• InChiKey: VCLATTSWRJFEBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  27
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  1,10-Diamino-3-(trifluoromethyl)-3,4,4,5,5,6,6,7,7,8,8-undecafluorodecane 以51%的产率得到
  参考文献：
  名称：

  Baum Kurt, Malik Aslam A., J. Org. Chem, 59 (1994) N 22, S 6804- 6807

  摘要：

  DOI：
• 作为产物：
  描述：

  1,10-Diazido-3-(trifluoromethyl)-3,4,4,5,5,6,6,7,7,8,8-undecafluorodecane 在 palladium dihydroxide 肼 作用下， 以 甲醇 为溶剂， 反应 21.0h， 以39%的产率得到1,10-Diamino-3-(trifluoromethyl)-3,4,4,5,5,6,6,7,7,8,8-undecafluorodecane
  参考文献：
  名称：

  Difunctional Monomers Based on Perfluoropropylene Telomers

  摘要：

  Telomers of perfluoropropylene with alpha,omega-diiodoperfluoroalkanes were converted to branched-chain difunctional condensation monomers. The reaction of ethylene with the telomers gave alpha,omega-bis(iodoethyl)perfluoroalkanes, which were converted to the corresponding diols by reaction with fuming sulfuric acid. The reaction of the branched-chain alpha,omega-bis(iodoethyl)perfluoroalkane a with sodium azide gave the corresponding alpha,omega-bis(azidoethyl)perfluoroalkanes. Hydrogenation of the alpha,omega-bis(azidoethyl)perfluoroalkanes gave diamines. Phosgenation of the amino groups gave diisocyanates.

  DOI：

  10.1021/jo00101a048

文献信息

• Polyfluorinated, branched-chain diols and diisocyanantes and fluorinated
  申请人：Fluorochem Inc.

  公开号：US05204441A1

  公开（公告）日：1993-04-20

  Branched-chain diols and a method of forming them by reacting 1,4-diiodoperfluorobutane and perfluoropropylene to obtain branched-chain diiodide adducts thereof, reacting the diiodide adducts with ethylene to obtain I--CH.sub.2 CH.sub.2 --R--CH.sub.2 CH.sub.2 --I, wherein R is a branched-chain perfluoroalkyl radical, and hydrolysing the iodo groups to alcohols to obtain HO--CH.sub.2 CH.sub.2 --R--CH.sub.2 CH.sub.2 --OH. These diols can be reacted with branched-chain diisocyanates to form polyurethanes of better processability and lower glass transition temperatures than polyurethanes prepared from linear fluorinated monomers.

  分支链二元醇及其制备方法，通过反应1,4-二碘全氟丁烷和全氟丙烯以获得它们的分支链二碘化物加合物，将二碘加合物与乙烯反应以获得I-CH.sub.2 CH.sub.2-R-CH.sub.2 CH.sub.2-I，其中R是分支链全氟烷基，然后水解碘基以获得HO-CH.sub.2 CH.sub.2-R-CH.sub.2 CH.sub.2-OH。这些二元醇可以与分支链二异氰酸酯反应，形成比从线性氟化单体制备的聚氨酯更易加工和玻璃化转变温度更低的聚氨酯。
• Baum Kurt, Malik Aslam A., J. Org. Chem, 59 (1994) N 22, S 6804- 6807
  作者：Baum Kurt, Malik Aslam A.

  DOI：——

  日期：——
• Fluorinated reactive compositions for golf balls
  申请人：Rajagopalan Murali

  公开号：US20060199937A1

  公开（公告）日：2006-09-07

  A golf ball is disclosued, comprising: a core, the core having a diameter of 1.5 inches to 1.65 inches and a first coefficient of restitution of 0.8 or greater at 125 ft/s; an intermediate layer disposed about the core, the intermediate layer having a first Shore D hardness of 20 to 80 and comprising a blend of two or more ionomers; and an outer cover layer disposed about the intermediate layer; the outer cover layer having a thickness of 0.005 inches to 0.05 inches and a second Shore D hardness of 30 to 70, the outer cover layer being composed of a castable material formed from reactants comprising at least one fluorinated polyfunctional compound, wherein the golf ball has a second coefficient of restitution of 0.8 or greater at 125 ft/s and a compression of 50 to 120.
• US5204441A
  申请人：——

  公开号：US5204441A

  公开（公告）日：1993-04-20
• US7312298B2
  申请人：——

  公开号：US7312298B2

  公开（公告）日：2007-12-25