N-decylsalicylideneimine | 18644-78-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N-decylsalicylideneimine
• 英文别名: 2-(Decylimino-methyl)-phenol；2-(Decyliminomethyl)phenol
• CAS: 18644-78-5
• 化学式: C₁₇H₂₇NO
• 分子量: 261.407
• InChiKey: GHTZIEFKJMBESC-UHFFFAOYSA-N

物化性质

• 沸点：
  379.2±25.0 °C(Predicted)
• 密度：
  0.93±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  nickel(II) acetate tetrahydrate 、 N-decylsalicylideneimine 以 乙醇 为溶剂， 生成 [nickel(II)bis(N-decylsalicylideneiminate)]
  参考文献：
  名称：

  Tribochemically active chelate complexes of salicylideneimines

  摘要：

  N-Alkylsalicylideneimines and their complexes with 3d metals were obtained by chemical (from metal salts) and electrochemical methods (from metals in the zero oxidation state). The compounds obtained were characterized by IR and H-1 NMR spectroscopy and X-ray diffraction analysis. According to crystallographic data, nickel bis(chelate) exists in the trans-planar configuration. A friction test revealed that the tribotechnical characteristics of lubricating formulations are substantially enhanced in the presence of N-alkylsalicylideneiminates.

  DOI：

  10.1134/s1070328409020067
• 作为产物：
  描述：

  1-氨基癸烷 、 水杨醛 在 甲醇 作用下， 生成 N-decylsalicylideneimine
  参考文献：
  名称：

  Copper (II) and Nickel (II) N-(n-alkyl)salicylaldimine Chelates

  摘要：

  DOI：

  10.1021/jo01357a025

文献信息

• CH445193
  申请人：——

  公开号：——

  公开（公告）日：——
• Synthesis, characterization and anticancer properties of (salicylaldiminato)platinum(II) complexes
  作者：Alyssa E. Patterson、Jessica J. Miller、Brittany A. Miles、Erin L. Stewart、Josée-Marie E.J. Melanson、Christopher M. Vogels、Amanda M. Cockshutt、Andreas Decken、Pier Morin、Stephen A. Westcott

  DOI：10.1016/j.ica.2014.02.028

  日期：2014.5

  Twelve new (salicylaldiminato) platinum(II) complexes have been prepared, characterized and examined for their in vitro cytotoxic properties against three human glioma cell lines LN18, LN405 and Hs683. Initial biotesting was done on platinum complexes 1-6, which display a wide range of physicochemical properties. Whereas introduction of aromatic rings in the complexes did not seem to have a significant impact on bioactivities, the length of the aliphatic group positively correlated with cytotoxicity in all cell lines. Complexes 2 and 3 were found to be particularly potent against LN18 cells as demonstrated by stronger cell growth inhibition when compared to cisplatin. These initial findings led us to develop an additional series of mono (salicylaldiminato) platinum(II) complexes 7-12, which were subjected to additional cytotoxicity studies but were less cytotoxic compared to the bis Schiff base complexes. These organometallic compounds could serve as interesting starting points for the development of novel therapeutic strategies to treat brain tumors. (C) 2014 Elsevier B.V. All rights reserved.
• Structures and properties of di-μ-oxo dimanganese(IV) complexes with bidentate Schiff bases, N-alkyl-substituted-salicylideneamine
  作者：Hitoshi Torayama、Hideyuki Asada、Manabu Fujiwara、Takayuki Matsushita

  DOI：10.1016/s0277-5387(98)00144-2

  日期：1998.11

  Novel di-mu-oxo dimanganese(IV) complexes, [Mn-IV(N-R-X-sal)(2)(mu-O)](2), with bidentate Schiff base ligands, N-alkyl-substituted-salicylideneamine, N-R-X-salH [R= CH3(Me), C2H5 (Et), n-C3H, (Pr), n-C4H9 (Bu), n-C6H13 (Hx), n-C8H17 (Oct), II-C10H21 (Dec), n-C12H25 (Dod), or n-C18H37 (Octd) and X = H or 5,6-benzo]: have been prepared by their reaction with potassium permanganate (KMnO4) in MeCN, while stirring at room temperature. These complexes were characterized by spectroscopy, magnetic susceptibility, thermal analysis and X-ray crystallography. The structures consist of a Mn-2(IV)(mu-O)(2) core with a Mn-Mn separation of 2.731 (4) Angstrom for [Mn-IV(N-Me-sal)(2)(mu-O)](2), 1, 2.769(2) Angstrom for [Mn-2(IV)(N-Et-sal)(2)(mu-O)](2), 2, 2.780(2) Angstrom for [(Mn-IV-Hx-sal)(2)(mu-O)](2), 5, 2.780(2)Angstrom for [Mn-IV(N-Dec-sal)(2)(mu-O)](2), 7, and 2.756(3) Angstrom for [Mn-IV(N-Me-5,6-benzo-sal)(2)(mu-O)](2), 10. The complex 1 is the first di-mu-oxo dimanganese(IV) complex having asymmetrical form in which two manganese ions adopt different configurations each other. Moreover, the complexes 5 and 7 are found to exhibit the longest one among all of the Mn-Mn separation observed for the structurally characterized Mn-2(mu-O)(2) complexes prior to this work. The antiferromagnetic exchange interaction has been found to be J= -83 and -188 cm(-1) for 1 and 7, respectively. (C) 1998 Elsevier Science Ltd. All rights reserved.