5-benzoyl-1H-benzo[d][1,2,3]triazole | 107508-46-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-benzoyl-1H-benzo[d][1,2,3]triazole
• 英文别名: 5-(benzoyl)-1H-benzotriazole；5-Benzoylbenzotriazole；2H-benzotriazol-5-yl(phenyl)methanone
• CAS: 107508-46-3
• 化学式: C₁₃H₉N₃O
• 分子量: 223.234
• InChiKey: HHGIHMOGFBYVIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-benzoyl-1H-benzo[d][1,2,3]triazole 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 12.0h， 以70%的产率得到(1H-benzotriazol-5-yl)(phenyl)methanol
  参考文献：
  名称：

  El-Hamouly; Abd-Allah; Tawfik, Egyptian Journal of Chemistry, 2004, vol. 47, # 3, p. 333 - 343

  摘要：

  DOI：
• 作为产物：
  描述：

  3,4-二氨基二苯甲酮 在 溶剂黄146 作用下， 以 水 为溶剂， 反应 0.47h， 以87%的产率得到5-benzoyl-1H-benzo[d][1,2,3]triazole
  参考文献：
  名称：

  使用固定在二氧化硅上的有机硅烷基亚硝酸盐离子液体和两种室温亚硝酸盐离子液体的纳米颗粒简便合成苯并三唑衍生物

  摘要：

  摘要 有机硅烷基亚硝酸盐离子液体纳米粒子固定在二氧化硅上，1-丁基-3-甲基咪唑亚硝酸盐和 1-(3-三甲氧基甲硅烷基丙基)-3-甲基咪唑亚硝酸盐可作为有效试剂制备 1,2 苯并三唑衍生物。 -二氨基苯在温和的无溶剂条件下在室温下。这些离子液体在该过程中作为亚硝基源。1,2-二氨基苯衍生物已经用离子液体处理，在很短的反应时间内以非常好的产率得到相关的二氨基苯。补充材料可用于本文。有关完整的实验和光谱详细信息，请访问出版商的 Synthetic Communications® 在线版。图形概要

  DOI：

  10.1080/00397911.2012.744840

文献信息

• <i>tert</i>-Butyl nitrite mediated nitrogen transfer reactions: synthesis of benzotriazoles and azides at room temperature
  作者：Sadaf Azeez、Priyanka Chaudhary、Popuri Sureshbabu、Shahulhameed Sabiah、Jeyakumar Kandasamy

  DOI：10.1039/c8ob01950a

  日期：——

  A conversion of o-phenylenediamines into benzotriazoles was achieved at room temperature using tert-butyl nitrite. The optimized conditions are also well suited for the transformation of sulfonyl and acyl hydrazines into corresponding azides. This protocol does not require any catalyst or acidic medium. The desired products were obtained in excellent yields in a short span of time.

  的A转换ö苯二胺为苯并三唑类是用在室温下实现叔丁基亚硝酸盐。优化的条件也非常适合将磺酰基和酰基肼转化为相应的叠氮化物。该协议不需要任何催化剂或酸性介质。在短时间内以优异的产率获得了所需的产物。
• On Demand Flow Platform for the Generation of Anhydrous Dinitrogen Trioxide and Its Further Use in <i>N</i> ‐Nitrosative Reactions
  作者：Yuesu Chen、Sébastien Renson、Jean‐Christophe M. Monbaliu

  DOI：10.1002/anie.202210146

  日期：2022.10.10

  A versatile continuous flow platform for the generation of concentrated dinitrogen trioxide (N2O3) solution with accurate and tunable concentration is reported. It unlocks the use of N2O3 in the nitrosative synthesis of heterocycles in flow and batch.

  报道了一种多功能连续流动平台，用于生成浓度精确且可调的浓缩三氧化二氮 (N 2 O 3 ) 溶液。它解锁了 N 2 O 3在流动和间歇亚硝化合成杂环化合物中的用途。
• Chemical-mechanical polishing composition comprising benzotriazole derivatives as corrosion inhibitors
  申请人：BASF SE

  公开号：US10647900B2

  公开（公告）日：2020-05-12

  A chemical-mechanical polishing (CMP) composition is provided comprising (A) one or more compounds selected from the group of benzotriazole derivatives which act as corrosion inhibitors and (B) inorganic particles, organic particles, or a composite or mixture thereof. The invention also relates to the use of certain compounds selected from the group of benzotriazole derivatives as corrosion inhibitors, especially for increasing the selectivity of a chemical mechanical polishing (CMP) composition for the removal of tantalum or tantalum nitride from a substrate for the manufacture of a semiconductor device in the presence of copper on said substrate.

  本发明提供了一种化学机械抛光（CMP）组合物，该组合物包含（A）一种或多种选自苯并三唑衍生物组的化合物，这些化合物可作为腐蚀抑制剂；（B）无机颗粒、有机颗粒或其复合体或混合物。本发明还涉及选自苯并三唑衍生物组的某些化合物作为腐蚀抑制剂的用途，特别是用于提高化学机械抛光（CMP）组合物的选择性，该组合物用于在所述基底上存在铜的情况下，从用于制造半导体器件的基底上去除钽或氮化钽。
• Enhanced conductivity nanocomposites and method of use thereof
  申请人：——

  公开号：US20030151030A1

  公开（公告）日：2003-08-14

  An enhanced conductivity nanocomposite having reduced conductivity path directionality dependence as a means for enhancing the electrical and thermal conductivity. The composition comprises a synergistic blend of metal (and their derivatives) and carbon (preferably nanotubes) powder both average particle sizes in the nanometer to micron size range. The carrier medium is selected from the group of interpolymers, polymers, gaseous and liquid fluids, and phase change materials. The synergistic nanocomposite, when mixed with a conductive medium, exhibits enhanced heat transfer capacity, and electrical and thermal conductivity, stable chemical composition, faster heat transfer rates, and dispersion maintenance which are beneficial to most thermal or electrical transfer systems.

  一种增强导电性的纳米复合材料，其导电路径方向性依赖性降低，是增强导电性和导热性的一种手段。该组合物包括金属（及其衍生物）和碳（最好是纳米管）粉末的协同混合物，这两种粉末的平均粒径在纳米到微米之间。载体介质选自中间聚合物、聚合物、气态和液态流体以及相变材料。协同纳米复合材料与导电介质混合后，具有更强的传热能力、导电性和导热性、稳定的化学成分、更快的传热速率和分散性，这对大多数热传导或电传导系统都是有益的。
• Composition for enhancing thermal conductivity of a heat transfer medium and method of use thereof
  申请人：——

  公开号：US20040069454A1

  公开（公告）日：2004-04-15

  A composition and method for enhancing the thermal conductivity in heat transfer systems. The composition comprises a powder having average particle sizes in the nanometer to micron size range, a coating for imparting corrosion resistance and/or acting as a dispersant, and a heat transfer medium. The heat transfer medium is selected from the group of interpolymers, polymers, gaseous and liquid fluids, and phase change materials. Suitable powders include metals and metal oxides, alloys or blends thereof, and carbon derivatives. The surface of the powder is modified by surface complexes or physical adsorption with a coating compound. The coated powder, when mixed with a heat transfer medium, forms a colloidal dispersion which exhibits enhanced heat transfer capacity and thermal conductivity, stable chemical composition, faster heat transfer rates, and dispersion maintenance which are beneficial to most heat transfer systems.

  一种用于提高传热系统导热性能的组合物和方法。该组合物包括平均粒径在纳米至微米范围内的粉末、赋予耐腐蚀性和/或用作分散剂的涂层以及传热介质。传热介质选自中间聚合物、聚合物、气态和液态流体以及相变材料。合适的粉末包括金属和金属氧化物、合金或其混合物以及碳衍生物。粉末表面通过表面络合物或与涂层化合物的物理吸附进行改性。涂层粉末与传热介质混合后形成胶体分散体，具有更强的传热能力和热传导性、稳定的化学成分、更快的传热速率以及对大多数传热系统有益的分散稳定性。