1,2-bis(4-hydroxyphenyl)-3,4,5,6-tetraphenylbenzene | 1266759-31-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(4-hydroxyphenyl)-3,4,5,6-tetraphenylbenzene
• 英文别名: BHPTPB；1,2-bis(4-hydroxyphenyl)-3,4,5,6-tetrakis(phenyl)benzene；4-[2-(4-Hydroxyphenyl)-3,4,5,6-tetraphenylphenyl]phenol
• CAS: 1266759-31-2
• 化学式: C₄₂H₃₀O₂
• 分子量: 566.699
• InChiKey: AESFCKYRUUEBNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11
• 重原子数：
  44
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  chloro-[2,9,16-tri(4-tert-butyl)subphthalocyaninato]boron(III) 、 1,2-bis(4-hydroxyphenyl)-3,4,5,6-tetraphenylbenzene 以 乙酸乙酯 、 甲苯 为溶剂， 以55%的产率得到1,2-bis[4-[2,9(10),16(17)-tris(tert-butyl)subphthalocyaninatoboron(III)]oxyphenyl]-3,4,5,6-tetraphenylbenzene
  参考文献：
  名称：

  Hexameric subphthalocyanine rosette

  摘要：

  通过对基于六氢氧基苯基苯的亚硫酞菁进行轴向氯原子与酚氧基的取代，合成了一种高度拥挤的六聚体亚硫酞菁阵列，并在极性溶剂中展示了光诱导的对称破缺电荷分离。

  DOI：

  10.1039/c1dt11214g
• 作为产物：
  描述：

  1,2-bis(4-dimethoxybenzene)-3,4,5,6-tetraphenylbenzene 在 三溴化磷 作用下， 以 二氯甲烷 为溶剂， 以97%的产率得到1,2-bis(4-hydroxyphenyl)-3,4,5,6-tetraphenylbenzene
  参考文献：
  名称：

  Hexameric subphthalocyanine rosette

  摘要：

  通过对基于六氢氧基苯基苯的亚硫酞菁进行轴向氯原子与酚氧基的取代，合成了一种高度拥挤的六聚体亚硫酞菁阵列，并在极性溶剂中展示了光诱导的对称破缺电荷分离。

  DOI：

  10.1039/c1dt11214g

文献信息

• Preparation and characterization of proton exchange poly (ether sulfone)s membranes grafted propane sulfonic acid on pendant phenyl groups
  作者：Youngdon Lim、Dongwan Seo、Md. Awlad Hossain、Soonho Lee、Jinseong Lim、Hohyoun Jang、Taehoon Hong、Kim、Whangi Kim

  DOI：10.1016/j.electacta.2013.11.173

  日期：2014.2

  Poly(ether sulfone)s containing hexaphenyl (PHP) was prepared by 1,2-bis(4-hydroxypheny1)-3,4,5,6-tetraphenylbenzene, 4,4-hydroxyphenylsulfone, and 4,4-fluorophenylsulfone, followed bromination on phenyl groups to produce brominated PHP (Br-PHP). Grafted sulfonated poly(ether sulfone)s containing hexaphenyl (GSPHP) were prepared from Br-PEP and 3-bromopropane sulfonic acid with potassium salt and copper powder. The salt form was converted to free acid using 1 M sulfuric acid solution. All these membranes were cast from dimethylacetamide (DMAc). The structural properties of the synthesized polymers were investigated by H-1-NMR spectroscopy. The membranes were studied with regard to ion exchange capacity (IEC), water uptake, Fenton test, and proton conductivity. These grafted polymer membranes were compared with normal sulfonated poly(ether sulfone)s and Nafion (C) 2013 Elsevier Ltd. All rights reserved.