N'',N'''-bis(4''-aminophenyl)-N,N'-bis(4'-aminophenyl)-1,4-benzenediamine | 189000-38-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N'',N'''-bis(4''-aminophenyl)-N,N'-bis(4'-aminophenyl)-1,4-benzenediamine
• 英文别名: 1,4-Benzenediamine, N1,N4-bis[4-[(4-aminophenyl)amino]phenyl]-；4-N-[4-[4-[4-(4-aminoanilino)anilino]anilino]phenyl]benzene-1,4-diamine
• CAS: 189000-38-2
• 化学式: C₃₀H₂₈N₆
• 分子量: 472.593
• InChiKey: JYQXKZCYYZENQY-UHFFFAOYSA-N

物化性质

• 沸点：
  773.9±50.0 °C(Predicted)
• 密度：
  1.319±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  N'',N'''-bis(4''-nitrophenyl)-N,N'-bis(4'-aminophenyl)-1,4-benzenediamine 在 palladium on activated charcoal 氢气 作用下， 以 甲醇 为溶剂， 以67.5%的产率得到N'',N'''-bis(4''-aminophenyl)-N,N'-bis(4'-aminophenyl)-1,4-benzenediamine
  参考文献：
  名称：

  High-Pressure Synthesis of Oligoanilines

  摘要：

  通过高压促进芳香胺与氟硝基苯的 SNAr 反应，然后还原硝基，可以清洁、高产地制备苯胺低聚物。

  DOI：

  10.1055/s-2003-42434

文献信息

• Linear 1,4-coupled oligoanilines of defined length: preparation and spectroscopic properties
  作者：Izabela Różalska、Paulina Kułyk、Irena Kulszewicz-Bajer

  DOI：10.1039/b404828h

  日期：——

  A facile synthetic method involving SNAr coupling of 4-fluoronitrobenzene to arylamines, followed by reduction of the nitro groups, has been developed. The method allows the preparation of symmetric (NH2/NH2 end-capped) and asymmetric (Ph/NH2 end-capped) oligoanilines of even or odd chain lengths. The preparation of the NH2/NH2 end-capped trimer to octamer and Ph/NH2 end-capped trimer to pentamer is described. The effect of the chain length on the spectroscopic properties of the oxidized oligomers has been investigated by UV-Vis-NIR spectroscopy.

  我们开发了一种简便的合成方法，涉及 4-氟硝基苯与芳基胺的 SNAr 偶联，然后还原硝基。该方法可制备偶数或奇数链长的对称（NH2/NH2 端封端）和不对称（Ph/NH2 端封端）寡苯胺。介绍了从 NH2/NH2 端封端三聚体到八聚体和从 Ph/NH2 端封端三聚体到五聚体的制备过程。紫外-可见-近红外光谱法研究了链长对氧化低聚物光谱特性的影响。
• CHARGE-TRANSPORTING VARNISH AND ORGANIC ELECTRO- LUMINESCENT DEVICES MADE BY USING THE SAME
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1728827A1

  公开（公告）日：2006-12-06

  A charge-transporting varnish containing either a charge-transporting substance consisting of a charge-transporting oligoaniline or a charge-transporting organic material consisting of the charge-transporting substance and a charge-accepting dopant and at least one polymer selected from among polyimides and polyimide precursors; and charge-transporting thin films and organic EL devices, made by using the varnish. The varnish can give thin films which little suffer from defects and have high uniformity and flatness and excellent mechanical strengths, heat resistance, and transparency. In particular, the varnish realizes excellent EL characteristics such as low driving voltage, high emission efficiency, and long service life, when used in organic EL devices.

  一种电荷传输清漆，含有由电荷传输低聚苯胺组成的电荷传输物质或由电荷传输物质和电荷接受掺杂剂组成的电荷传输有机材料，以及至少一种从聚酰亚胺和聚酰亚胺前体中选出的聚合物；以及使用该清漆制成的电荷传输薄膜和有机电致发光器件。清漆可制成几乎没有缺陷、均匀度和平整度高、机械强度、耐热性和透明度优异的薄膜。特别是在用于有机 EL 器件时，清漆可实现低驱动电压、高发射效率和长使用寿命等优异的 EL 特性。
• Charge-transporting varnish and organic electro-luminescent devices made by using the same
  申请人：Ono Go

  公开号：US20070187672A1

  公开（公告）日：2007-08-16

  A charge-transporting varnish containing either a charge-transporting substance consisting of a charge-transporting oligoaniline or a charge-transporting organic material consisting of the charge-transporting substance and a charge-accepting dopant and at least one polymer selected from among polyimides and polyimide precursors; and charge-transporting thin films and organic EL devices, made by using the varnish. The varnish can give thin films which little suffer from defects and have high uniformity and flatness and excellent mechanical strengths, heat resistance, and transparency. In particular, the varnish realizes excellent EL characteristics such as low driving voltage, high emission efficiency, and long service life, when used in organic EL devices.
• STABLE, WATER-SOLUBLE NEAR INFRARED DYES
  申请人：COHEN MURRAY S.

  公开号：US20120248389A1

  公开（公告）日：2012-10-04

  The synthesis of stable, water-soluble tris and tetrakis aminium dyes. More particularly, carboxylic-acid modified tris and tetrakis dye intermediates, as well as salts and near-infrared dyes formed therefrom, as well as compositions including the dyes.
• US8822039B2
  申请人：——

  公开号：US8822039B2

  公开（公告）日：2014-09-02