3,3'-<(1-Methylethylidene)bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetrafluoropropanamine) | 131043-03-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-<(1-Methylethylidene)bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetrafluoropropanamine)
• 英文别名: 3-[4-[2-[4-(3-Amino-1,1,2,2-tetrafluoropropoxy)phenyl]propan-2-yl]phenoxy]-2,2,3,3-tetrafluoropropan-1-amine
• CAS: 131043-03-3
• 化学式: C₂₁H₂₂F₈N₂O₂
• 分子量: 486.405
• InChiKey: IZMTWFMQIIQATE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  33
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  3,3'-<(1-Methylethylidene)bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetrafluoropropanamine) 、 氯甲酸甲酯 在 sodium hydroxide 作用下， 以 乙醚 为溶剂， 生成 Dimethyl 3,3'-<(1-methylethylidene)bis(4,1-phenyleneoxy)>bis<(2,2,3,3-tetrafluoropropyl)carbamate>
  参考文献：
  名称：

  Fluorinated bifunctional derivatives of bisphenol A

  摘要：

  Bisphenol A reacted as its disodium salt with tetrafluoroethylene and carbon dioxide followed by dimethyl sulfate to give in high yield a symmetrical dimethyl ester assembled from seven structural elements. This diester was transformed into the corresponding diol, diamide, diamine, diisocyanate, and bis(methyl carbamate). Analogous diesters were prepared by using bisphenol A and chlorotrifluoroethylene as well as hexafluorobisphenol A and tetrafluoroethylene. Both of these esters were transformed into other bifunctional derivatives. Catalytic hydrogenation of the diol derived from bisphenol A and tetrafluoroethylene was accompanied by hydrogenolysis of the aryl-oxygen bonds.

  DOI：

  10.1021/jo00001a030
• 作为产物：
  描述：

  Dimethyl 3,3'-<(1-methylethylidene)bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetafluoropropionate) 在 硼烷四氢呋喃络合物 、 氨 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 1.0h， 生成 3,3'-<(1-Methylethylidene)bis(4,1-phenyleneoxy)>bis(2,2,3,3-tetrafluoropropanamine)
  参考文献：
  名称：

  Fluorinated bifunctional derivatives of bisphenol A

  摘要：

  Bisphenol A reacted as its disodium salt with tetrafluoroethylene and carbon dioxide followed by dimethyl sulfate to give in high yield a symmetrical dimethyl ester assembled from seven structural elements. This diester was transformed into the corresponding diol, diamide, diamine, diisocyanate, and bis(methyl carbamate). Analogous diesters were prepared by using bisphenol A and chlorotrifluoroethylene as well as hexafluorobisphenol A and tetrafluoroethylene. Both of these esters were transformed into other bifunctional derivatives. Catalytic hydrogenation of the diol derived from bisphenol A and tetrafluoroethylene was accompanied by hydrogenolysis of the aryl-oxygen bonds.

  DOI：

  10.1021/jo00001a030

文献信息

• ARNOLD-STANTON, REGINA;LEMAL, DAVID M., J. ORG. CHEM., 56,(1991) N, C. 146-151
  作者：ARNOLD-STANTON, REGINA、LEMAL, DAVID M.

  DOI：——

  日期：——