6-丙基-苯并[1,3]二氧代l-5-胺 | 69797-90-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并间二氧杂环戊烯类
• 中文名称: 6-丙基-苯并[1,3]二氧代l-5-胺
• 英文名称: LDN-0073854
• 英文别名: 6-propyl-benzo[1,3]dioxol-5-ylamine；1,3-Benzodioxol-5-amine, 6-propyl-；6-propyl-1,3-benzodioxol-5-amine
• CAS: 69797-90-6
• 化学式: C₁₀H₁₃NO₂
• mdl: MFCD03768215
• 分子量: 179.219
• InChiKey: DDSCEGQNNBUNEF-UHFFFAOYSA-N

物化性质

• 沸点：
  162-162.5 °C(Press: 13 Torr)
• 密度：
  1.177±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  44.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  6-丙基-苯并[1,3]二氧代l-5-胺 在 硫酸 作用下， 生成 6-propylbenzo[d][1,3]dioxol-5-ol
  参考文献：
  名称：

  Thoms; Biltz, Archiv der Pharmazie, 1904, vol. 242, p. 90

  摘要：

  DOI：
• 作为产物：
  描述：

  5-nitro-6-propyl-benzo[1,3]dioxole 在 乙醇 、 镍 作用下， 生成 6-丙基-苯并[1,3]二氧代l-5-胺
  参考文献：
  名称：

  氨基-4-吡咯烷基酚的制备和制备

  摘要：

  在制备的5个氨基上的氨基取代基上，氨基氨基-4，氨基氨基4和氨基氨基4取代氨基环戊酸酯，锡基，己醛和二氢-羟基邻氨基苯甲酸，氨基亚锡类似物在二氢上。服从于邻苯二酚的邻苯二甲酰基化甲基碘。Leur氧化一个帐篷。

  DOI：

  10.1002/hlca.19560390112

文献信息

• Oxidation dyeing process using a composition comprising a monoaminobenzene and a metal catalyst
  申请人：L'OREAL

  公开号：US10251827B2

  公开（公告）日：2019-04-09

  The invention relates to a process for dyeing keratin fibers, comprising the use of one or more metal catalysts and of a composition (A) comprising: —one or more oxidizing agents, and —at least one monoaminobenzene of formula (I), or an addition salt or solvate thereof in which the radicals R1 to R5 represent, independently of each other: a hydrogen atom; a halogen atom, a C1-C6 alkyl radical, a C1-C6 alkoxy radical, a carboxylic radical (—COOH), a sulfonic radical (—S03 H); two of the adjacent radicals R1 to R5 possibly forming, with the carbon atoms that bear them, a saturated or unsaturated 5- to 7-membered ring, optionally comprising from 1 to 2 heteroatoms, preferably oxygen, the said ring being optionally fused with a saturated or unsaturated 5- to 6-membered ring; on condition that at least one of the radicals R1 to R5 represents an optionally substituted alkoxy radical and preferably at least one of the other radicals R1 to R5 is a hydrogen atom.

  本发明涉及一种角蛋白纤维染色工艺，包括使用一种或多种金属催化剂和一种组合物（A），组合物（A）包括： -一种或多种氧化剂，和 -至少一种式（I）的单胺苯，或其加成盐或溶液，其中自由基 R1 至 R5 各自代表：氢原子、卤素原子、C1-C6 烷基、C1-C6 烷氧基、羧基 (-COOH)、磺酸基 (-S03 H)；R1 至 R5 中相邻的两个基团可与含有它们的碳原子形成饱和或不饱和的 5 至 7 元环，可选择包含 1 至 2 个杂原子，最好是氧，所述环可选择与饱和或不饱和的 5 至 6 元环融合；条件是 R1 至 R5 自由基中至少有一个代表任选取代的烷氧基，且 R1 至 R5 自由基中至少有一个是氢原子。
• OXIDATION DYEING PROCESS USING A COMPOSITION COMPRISING A MONOAMINOBENZENE AND A METAL CATALYST
  申请人：L'OREAL

  公开号：US20160128922A1

  公开（公告）日：2016-05-12

  The invention relates to a process for dyeing keratin fibres, comprising the use of one or more metal catalysts and of a composition (A) comprising: —one or more oxidizing agents, and —at least one monoaminobenzene of formula (I), or an addition salt or solvate thereof in which the radicals R1 to R5 represent, independently of each other: a hydrogen atom; a halogen atom, a C1-C6 alkyl radical, a C1-C6 alkoxy radical, a carboxylic radical (—COOH), a sulfonic radical (—SO3 H); two of the adjacent radicals R1 to R5 possibly forming, with the carbon atoms that bear them, a saturated or unsaturated 5- to 7-membered ring, optionally comprising from 1 to 2 heteroatoms, preferably oxygen, the said ring being optionally fused with a saturated or unsaturated 5- to 6-membered ring; on condition that at least one of the radicals R1 to R5 represents an optionally substituted alkoxy radical and preferably at least one of the other radicals R1 to R5 is a hydrogen atom.
• [EN] OXIDATION DYEING PROCESS USING A COMPOSITION COMPRISING A MONOAMINOBENZENE AND A METAL CATALYST<br/>[FR] PROCÉDÉ DE COLORATION PAR OXYDATION À L'AIDE D'UNE COMPOSITION COMPRENANT UN MONOAMINOBENZÈNE ET UN CATALYSEUR MÉTALLIQUE
  申请人：OREAL

  公开号：WO2014202787A1

  公开（公告）日：2014-12-24

  The invention relates to a process for dyeing keratin fibres, comprising the use of one or more metal catalysts and o f a composition (A) comprising : - one or more oxidizing agents, and - at least one monoaminobenzene of formula (I), or an addition salt or solvate thereof in which the radicals R1 to R5 represent, independently of each other: a hydrogen atom; a halogen atom, a C1-C6 alkyl radical, a C1-C6 alkoxy radical, a carboxylic radical (-COOH), a sulfonic radical (-S03 H); two of the adjacent radicals R1 to R5 possibly forming, with the carbon atoms that bear them, a saturated or unsaturated 5- to 7-membered ring, optionally comprising from 1 to 2 heteroatoms, preferably oxygen, the said ring being optionally fused with a saturated or unsaturated 5- to 6- membered ring; on condition that at least one of the radicals R1 to R5 represents an optionally substituted alkoxy radical and preferably at least one of the other radicals R1 to R5 is a hydrogen atom.
• Sur la Préparation et les propriétés des amino-4-pyrocatéchols
  作者：P. Rayet、M. Prost、M. Urbain

  DOI：10.1002/hlca.19560390112

  日期：——

  On a préparé des dérivés amino-4, méthylamino-4, éthylamino-4 et propylamino-4 du vératrol substitué en 5 par les groupes méthyle, éthyle, hexadéyle et dihydro-hydnochaulyle, ainsi que des dérivés aminés analogues du dihydro-safrol. Par désalcoylation par l'iodure de méthylmagnesium on obtient les pyrocatéchols correspondants. Leur oxydation a été tentée.

  在制备的5个氨基上的氨基取代基上，氨基氨基-4，氨基氨基4和氨基氨基4取代氨基环戊酸酯，锡基，己醛和二氢-羟基邻氨基苯甲酸，氨基亚锡类似物在二氢上。服从于邻苯二酚的邻苯二甲酰基化甲基碘。Leur氧化一个帐篷。
• Thoms; Biltz, Archiv der Pharmazie, 1904, vol. 242, p. 90
  作者：Thoms、Biltz

  DOI：——

  日期：——