1,4-dimethyl-2,3-bis(chloromethyl)benzene | 54617-16-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-dimethyl-2,3-bis(chloromethyl)benzene
• 英文别名: 1,4-Dimethyl-2,5-dichlormethylbenzol；2,3-bis-chloromethyl-1,4-dimethyl-benzene；2,3-Bis-chlormethyl-1,4-dimethyl-benzol；2,3-bis(chloromethyl)-1,4-dimethylbenzene
• CAS: 54617-16-2
• 化学式: C₁₀H₁₂Cl₂
• 分子量: 203.111
• InChiKey: IVGNPAAPUGCMPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 对二甲苯 在 盐酸 作用下， 生成 1,4-dimethyl-2,3-bis(chloromethyl)benzene 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  v. Braun; Nelles, Chemische Berichte, 1934, vol. 67, p. 1094,1096

  摘要：

  DOI：

文献信息

• Sulphonation process
  申请人：Camelot Technologies Inc.

  公开号：EP0497056A1

  公开（公告）日：1992-08-05

  Crosslinked styrenic polymers may be sulphonated in a controlled manner in an organic solvent at elevated temperature using SO₃ in the presence of a trialkyl phosphate. The process does not introduce further crosslinking into the polymer permitting it to have an extremely high water uptake. The resulting polymer is useful as a hydrogel.

  交联苯乙烯聚合物可在有机溶剂中，在三烷基磷酸酯存在下，在高温下使用 SO₃ 以受控方式进行磺化。该工艺不会对聚合物产生进一步的交联，从而使其具有极高的吸水性。这种聚合物可用作水凝胶。
• Identification of alkylarene chloromethylation products using gas-chromatographic retention indices
  作者：I. G. Zenkevich、A. A. Makarov

  DOI：10.1134/s1070363207040196

  日期：2007.4

  Gas-chromatographic retention indices on standard nonpolar polydimethylsiloxane stationary phases allow identification of products formed by known organic reactions even without using mass-spectrometric data. The efficiency of this approach was demonstrated by the example of identification of previously uncharacterized chloromethyl derivatives of alkylarenes, including structural isomers of compounds containing several chloromethyl groups, directly in reaction mixtures. Chromatographic analysis of such reaction mixtures allows identification of positional isomers of the starting alkylarenes even when they are present simultaneously. The retention indices were determined for the first time for more than 50 alkyl-(chloromethyl)arenes, by-products of chloromethylation, and chloromethyl derivatives of the simplest alkyl phenyl ketones.
• US3947471A
  申请人：——

  公开号：US3947471A

  公开（公告）日：1976-03-30
• US5280082A
  申请人：——

  公开号：US5280082A

  公开（公告）日：1994-01-18