[4-[[dimethyl-[[4-[(E)-2-pyridin-3-ylethenyl]phenyl]methyl]silyl]methyl]phenyl]methyl-dimethyl-[[4-[(E)-2-pyridin-3-ylethenyl]phenyl]methyl]silane | 915698-89-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [4-[[dimethyl-[[4-[(E)-2-pyridin-3-ylethenyl]phenyl]methyl]silyl]methyl]phenyl]methyl-dimethyl-[[4-[(E)-2-pyridin-3-ylethenyl]phenyl]methyl]silane
• CAS: 915698-89-4
• 化学式: C₄₀H₄₄N₂Si₂
• 分子量: 608.974
• InChiKey: QGCOPIUQHCLPIU-KAVGSWPWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.96
• 重原子数：
  44
• 可旋转键数：
  12
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [4-[[dimethyl-[[4-[(E)-2-pyridin-3-ylethenyl]phenyl]methyl]silyl]methyl]phenyl]methyl-dimethyl-[[4-[(E)-2-pyridin-3-ylethenyl]phenyl]methyl]silane 以 氘代苯 为溶剂， 生成 3-[(2S,3R,4S,5R)-11,11,18,18-tetramethyl-4-pyridin-3-yl-11,18-disilapentacyclo[18.2.2.26,9.213,16.02,5]octacosa-1(22),6(28),7,9(27),13,15,20,23,25-nonaen-3-yl]pyridine 、
  参考文献：
  名称：

  Intramolecular photocycloaddition of β-stilbazoles tethered by silyl chains

  摘要：

  Intramolecular (2+2) photocycloaddition of beta-stilbazoles tethered by silyl chains took place with high efficiency. Complexation with dicarboxylic acid or catechol further enhanced both the efficiency and stereoselectivity. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.09.021
• 作为产物：
  描述：

  1,4-对二氯苄 在 palladium dichloride 四氯化碳 、 palladium diacetate 、 magnesium 、 三乙胺 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 生成 [4-[[dimethyl-[[4-[(E)-2-pyridin-3-ylethenyl]phenyl]methyl]silyl]methyl]phenyl]methyl-dimethyl-[[4-[(E)-2-pyridin-3-ylethenyl]phenyl]methyl]silane
  参考文献：
  名称：

  Intramolecular photocycloaddition of β-stilbazoles tethered by silyl chains

  摘要：

  Intramolecular (2+2) photocycloaddition of beta-stilbazoles tethered by silyl chains took place with high efficiency. Complexation with dicarboxylic acid or catechol further enhanced both the efficiency and stereoselectivity. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.09.021

文献信息

• Intramolecular photocycloaddition of β-stilbazoles tethered by silyl chains
  作者：Hajime Maeda、Ryu-ichiro Hiranabe、Kazuhiko Mizuno

  DOI：10.1016/j.tetlet.2006.09.021

  日期：2006.11

  Intramolecular (2+2) photocycloaddition of beta-stilbazoles tethered by silyl chains took place with high efficiency. Complexation with dicarboxylic acid or catechol further enhanced both the efficiency and stereoselectivity. (c) 2006 Elsevier Ltd. All rights reserved.