6-carboxy-5-phenyl-2-(2'-pyridyl)-3,4-cyclopentenopyridine | 453557-00-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6-carboxy-5-phenyl-2-(2'-pyridyl)-3,4-cyclopentenopyridine
• 英文别名: 4-phenyl-1-(2-pyridyl)-6,7-dihydro-5H-cyclopenta[c]pyridine-3-carboxylic acid；4-phenyl-1-pyridin-2-yl-6,7-dihydro-5H-cyclopenta[c]pyridine-3-carboxylic acid
• CAS: 453557-00-1
• 化学式: C₂₀H₁₆N₂O₂
• 分子量: 316.359
• InChiKey: JGFFUPRCLUWQRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  63.1
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-carboxy-5-phenyl-2-(2'-pyridyl)-3,4-cyclopentenopyridine 在 氯化亚砜 作用下， 反应 8.0h， 生成 6-ethoxycarbonyl-5-phenyl-2-(2'-pyridyl)-3,4-cyclopentenopyridine
  参考文献：
  名称：

  Kozhevnikov, Dmitry N.; Kozhevnikov, Valery N.; Nikitina, Tatiana V., Mendeleev Communications, 2002, vol. 12, # 1, p. 30 - 32

  摘要：

  DOI：
• 作为产物：
  描述：

  6-cyano-5-phenyl-2-(2'-pyridyl)-3,4-cyclopentenopyridine 在 盐酸 、 硫酸 作用下， 反应 13.0h， 生成 6-carboxy-5-phenyl-2-(2'-pyridyl)-3,4-cyclopentenopyridine
  参考文献：
  名称：

  Kozhevnikov, Dmitry N.; Kozhevnikov, Valery N.; Nikitina, Tatiana V., Mendeleev Communications, 2002, vol. 12, # 1, p. 30 - 32

  摘要：

  DOI：

文献信息

• Kozhevnikov, Dmitry N.; Kozhevnikov, Valery N.; Nikitina, Tatiana V., Mendeleev Communications, 2002, vol. 12, # 1, p. 30 - 32
  作者：Kozhevnikov, Dmitry N.、Kozhevnikov, Valery N.、Nikitina, Tatiana V.、Rusinov, Vladimir L.、Chupakhin, Oleg N.、Neunhoeffer, Hans

  DOI：——

  日期：——
• Luminescent neutral lanthanide complexes of 5-aryl-2,2′-bipyridine-6-carboxylic acids, synthesis and properties
  作者：Alexey P. Krinochkin、Dmitry S. Kopchuk、Dmitry N. Kozhevnikov

  DOI：10.1016/j.poly.2015.09.055

  日期：2015.12

  Luminescent lanthanide complexes of 4-aryl-1-(2-pyridyl)-6,7-dihydro-5H-cyclopenta[c]pyridine-3-carboxylic acids and 5-toly1-2,2'-bipyridine-6-carboxylic acid were prepared. The ligands were synthesized using the "1,2,4-triazine" methodology. In one case, the opportunity of copper complex preparation, followed by exchange of the metal cation from copper to europium to overcome synthetic difficulties, was demonstrated. The ability of tuning the properties of the complexes by means of varying the structure of the ligands was demonstrated. In particular, the introduction of the cyclopentene moiety allowed the preparation of highly soluble complexes in non-polar organic solvents. (C) 2015 Elsevier Ltd. All rights reserved.