5,5-dimethyl-3-[2-(trifluoromethanesulfonylamino)benzyl]-[1,3]-oxazinan-2-thione | 1028120-11-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5,5-dimethyl-3-[2-(trifluoromethanesulfonylamino)benzyl]-[1,3]-oxazinan-2-thione
• 英文别名: 5,5-Dimethyl-3-[2-(trifluoromethanesulfonylamino)benzyl]-[1,3]-oxazinan-2-thione；N-[2-[(5,5-dimethyl-2-sulfanylidene-1,3-oxazinan-3-yl)methyl]phenyl]-1,1,1-trifluoromethanesulfonamide
• CAS: 1028120-11-7
• 化学式: C₁₄H₁₇F₃N₂O₃S₂
• 分子量: 382.428
• InChiKey: WQSCSSDYECWENI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  99.1
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  5,5-dimethyl-3-[2-(trifluoromethanesulfonylamino)benzyl]-[1,3]-oxazinan-2-thione 、 氯甲酸甲酯 在 碳酸氢钠 作用下， 以 乙腈 为溶剂， 反应 3.0h， 以47%的产率得到5,5-dimethyl-3-(2-[N-(methoxycarbonyl)-N-(trifluoromethanesulfonyl)amino]benzyl)-[1,3]-oxazinane-2-thione
  参考文献：
  名称：

  EP2085392

  摘要：

  公开号：
• 作为产物：
  描述：

  三氟甲磺酸酐 、 3-(2-aminobenzyl)-5,5-dimethyl-[1,3]-oxazinan-2-thione 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 1.0h， 以69%的产率得到5,5-dimethyl-3-[2-(trifluoromethanesulfonylamino)benzyl]-[1,3]-oxazinan-2-thione
  参考文献：
  名称：

  EP2085392

  摘要：

  公开号：

文献信息

• HALOALKYLSULFONANILIDE DERIVATIVES OR SALT THEREOF, HERBICIDE COMPRISING THE DERIVATIVES AS ACTIVE INGREDIENT, AND USE OF THE HERBICIDE
  申请人：Hino Tomokazu

  公开号：US20100016164A1

  公开（公告）日：2010-01-21

  A haloalkylsulfonanilide derivative represented by general formula (I) or a salt thereof wherein R 1 represents a halo(C 1 -C 8 )alkyl group, R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and R 10 represent hydrogen atoms, etc., n represents 1 or 2, A represents an oxygen atom, W represents an oxygen atom, X represents a halogen atom and m represents an integer of 0 to 4, are compounds useful as herbicides having both of remarkable herbicidal effect and characteristics such as excellent crop-weed selectivity. General formula (I):

  一种由通式（I）表示的卤代烷基磺酰苯胺衍生物或其盐，其中R1代表卤代（C1-C8）烷基，R2、R3、R4、R5、R6、R7、R8、R9和R10代表氢原子等，n代表1或2，A代表氧原子，W代表氧原子，X代表卤素原子，m代表0到4的整数，是一种具有显著除草效果和优异的作物-杂草选择性特征的除草剂化合物。通式（I）如下：
• Haloalkylsulfonanilide derivatives or salt thereof, herbicide comprising the derivatives as active ingredient, and use of the herbicide
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：US08048825B2

  公开（公告）日：2011-11-01

  A haloalkylsulfonanilide derivative represented by general formula (I) or a salt thereof wherein R1 represents a halo(C1-C8)alkyl group, R2, R3, R4, R5, R6, R7, R8, R9 and R10 represent hydrogen atoms, etc., n represents 1 or 2, A represents an oxygen atom, W represents an oxygen atom, X represents a halogen atom and m represents an integer of 0 to 4, are compounds useful as herbicides having both of remarkable herbicidal effect and characteristics such as excellent crop-weed selectivity. General formula (I):

  一种由通式（I）表示的卤代烷基磺酰苯胺衍生物或其盐，其中R1代表卤代（C1-C8）烷基，R2、R3、R4、R5、R6、R7、R8、R9和R10代表氢原子等，n代表1或2，A代表氧原子，W代表氧原子，X代表卤素原子，m代表0至4的整数，这些化合物是一种有显著除草作用和优异的作物-杂草选择性特征的除草剂。通式（I）：
• HALOALKYLSULFONANILIDE DERIVATIVE OR SALT THEREOF, HERBICIDE COMPRISING THE DERIVATIVE AS ACTIVE INGREDIENT, AND USE OF THE HERBICIDE
  申请人：Nihon Nohyaku CO., LTD.

  公开号：EP2085392A1

  公开（公告）日：2009-08-05

  A haloalkylsulfonanilide derivative represented by general formula (I) or a salt thereof wherein R1 represents a halo(C1-C8)alkyl group, R2, R3, R4, R5, R6, R7, R8, R9 and R10 represent hydrogen atoms, etc., n represents 1 or 2, A represents an oxygen atom, W represents an oxygen atom, X represents a halogen atom and m represents an integer of 0 to 4, are compounds useful as herbicides having both of remarkable herbicidal effect and characteristics such as excellent crop-weed selectivity. General formula (I):

  由通式(I)代表的卤代烷基磺酰苯胺衍生物或其盐，其中 R1 代表卤代(C1-C8)烷基，R2、R3、R4、R5、R6、R7、R8、R9 和 R10 代表氢原子等，n 代表 1 或 2，A 代表氧原子，W 代表氧原子，X 代表卤素原子，m 代表 0 至 4 的整数。通式(I)：
• US8048825B2
  申请人：——

  公开号：US8048825B2

  公开（公告）日：2011-11-01