1,1,2-trimethoxy-2-phenyl propane | 62134-82-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1,2-trimethoxy-2-phenyl propane
• 英文别名: (1,2,2-Trimethoxy-1-methylethyl)benzene；1,1,2-trimethoxypropan-2-ylbenzene
• CAS: 62134-82-1
• 化学式: C₁₂H₁₈O₃
• 分子量: 210.273
• InChiKey: NUCZXZBYACHCFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,1,2-trimethoxy-2-phenyl propane 在 硫酸 作用下， 反应 24.0h， 生成 2-甲氧基-2-苯基丙醛
  参考文献：
  名称：

  Enantioselective α-selenenylation of 2-phenylpropanal

  摘要：

  DOI：

  10.1016/s0040-4039(00)82217-0
• 作为产物：
  描述：

  2-苯基丙醛 生成 1,1,2-trimethoxy-2-phenyl propane
  参考文献：
  名称：

  α-氯代醛亚胺的反应性

  摘要：

  通过将二取代的乙醛与伯胺缩合，然后在四氯化碳中用N-氯代琥珀酰亚胺氯化来制备一系列的仲N-1-（2-氯亚烷基）胺。描述了对这些α-氯醛的N-同源物的反应性的研究。在甲醇中用甲醇钠处理标题化合物得到高产率的α，β-不饱和醛亚胺。然而，N-1-（2-氯-2-甲基亚丙基）胺提供了消除和重排产物的混合物，其通过氮丙啶中间体进行。另一方面，在甲醇中用甲醇盐处理的α-苯基取代的α-氯醛亚胺经历了α取代，这与S N相一致。1机制。强大的亲核试剂，例如甲醇中的硫酚钠和丙酮中的叠氮化钠会引起α取代。α-氯醛亚胺与格氏试剂的反应产生两个醛亚胺单元的偶联或α-烷基化。最后，将α-氯醛亚胺的反应性与相应的氧类似物，即α-氯醛的反应性进行了比较。

  DOI：

  10.1016/0040-4020(76)87034-2

文献信息

• Methoxychlorination and dimethoxylation of alkenes the reactions of substituted styrenes with phenylselenenyl chloride in methanol
  作者：Marcello Tiecco、Lorenzo Testaferri、Marco Tingoli、Donatella Chianelli、Donatella Bartoli

  DOI：10.1016/s0040-4020(01)81734-8

  日期：1988.1

  addition of PhSeCl to α- and β-substituted styrenes in methanol is regio- and stereospecific and affords the products of methoxyselenenylation. These compounds further react with PhSeCl to give the deselenenylation products. In the case of α-substituted styrenes, 1-methoxy, 2-chloroalkanes are produced, whereas with β-substituted styrenes the major reaction products are the 1,2-dimethoxyalkanes and

  在甲醇中向α-和β-取代的苯乙烯中添加PhSeCl具有区域和立体特异性，并提供甲氧基硒烯化的产物。这些化合物进一步与PhSeCl反应，得到去硒烯基化产物。在α-取代的苯乙烯的情况下，产生了1-甲氧基，2-氯代烷烃，而对于β-取代的苯乙烯，主要的反应产物是发生苯基迁移的1,2-二甲氧基烷烃和2,2-二甲氧基烷烃。结果表明，这些反应是通过中间形成烷基苯基氯化二苯酚PhCR（OMe）CHR 1 SeCl 2 Ph来进行的，而中间反应机理取决于起始烯烃的结构。
• Resin composition, method of its composition, and cured formulation
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1626065A1

  公开（公告）日：2006-02-15

  It is an object of the present invention to provide a resin composition which can form cured formulations having various excellent properties such as an insulating property, thermal shock resistance, moldability/formability and strength, and exhibit an excellent appearance inwhich transparency is enhanced, a resin composition whose cured thin film has excellent flame retardancy, good mechanical property and heat resistance, a dispersing element containing an inorganic microfine particle which can give a flame retardancy to a resin, to which the inorganic microfine particle is added, and can reduce a hygroscopic property to the extent possible, a method for producing the same and a cured formulation obtained by using the resin composition. The present invention relates to a resin composition comprising a compound having at least one of a glycidyl group and/or an epoxy group and an inorganic microfine particle, a resin composition comprising three components of a phenolic compound, a compound having at least one of a glycidyl group and/or an epoxy group and an inorganic microfine particle, a flame retardant resin composition comprising a polyhydric phenol and an inorganic microfine particle, and a dispersing element containing an inorganic microfine particle obtained by a hydrolysis condensation reaction of alkoxide and/or metal carboxylate in a dispersion medium.

  本发明的目的是提供一种树脂组合物，该树脂组合物可形成具有各种优异性能（如绝缘性、抗热震性、成型性/可成形性和强度）的固化配方，并表现出优异的外观（其中透明度得到提高）；一种树脂组合物，该树脂组合物的固化薄膜具有优异的阻燃性、本发明涉及一种树脂组合物，其固化薄膜具有优异的阻燃性、良好的机械性能和耐热性；一种含有无机微细颗粒的分散元素，该分散元素可使添加了无机微细颗粒的树脂具有阻燃性，并可尽可能降低吸湿性；一种生产方法；以及一种通过使用该树脂组合物获得的固化配方。本发明涉及一种树脂组合物，该树脂组合物由至少一个具有缩水甘油基和/或环氧基的化合物和无机微细颗粒组成；一种树脂组合物，该树脂组合物由酚类化合物、至少一个具有缩水甘油基和/或环氧基的化合物和无机微细颗粒三部分组成、一种阻燃树脂组合物，包括一种多羟基酚和一种无机微细颗粒，以及一种含有无机微细颗粒的分散元件，该无机微细颗粒是通过烷氧基和/或金属羧酸盐在分散介质中的水解缩合反应获得的。
• Fire retardant resin composition, method of its production, shaped articles comprising the same, and silica
  申请人：Sugioka Takuo

  公开号：US20060167164A1

  公开（公告）日：2006-07-27

  The present invention has for its object to provide a fire retardant resin composition which is not only halogen-free and, hence, eliminating the adverse effect to the environment and human physiology but also reflecting an excellent fire retardancy imparted to a polyphenol having inherently favorable physical properties and heat resistance. The present invention is a fire retardant resin composition comprising a polyphenol compound and an inorganic microfine particle, wherein said polyphenol compound has such a structure that aromatic units each having at least one phenolic hydroxyl group are connected to one another through an organic unit containing two or more carbon atoms, and said inorganic microfine particle is a product of hydrolysis and condensation of an alkoxide compound and/or a carboxylic acid salt compound.

  本发明的目的是提供一种阻燃树脂组合物，该组合物不仅不含卤素，因而消除了对环境和人体生理的不利影响，而且反映了具有固有良好物理性能和耐热性能的多酚所赋予的优异阻燃性。本发明是一种阻燃树脂组合物，包括一种多酚化合物和一种无机微细颗粒，其中所述多酚化合物具有这样一种结构，即每个具有至少一个酚羟基的芳香单元通过含有两个或两个以上碳原子的有机单元相互连接，而所述无机微细颗粒是烷氧基化合物和/或羧酸盐化合物水解和缩合的产物。
• [EN] FIRE RETARDANT RESIN COMPOSITION, METHOD OF ITS PRODUCTION, SHAPED ARTICLES COMPRISING THE SAME, AND SILICA<br/>[FR] COMPOSITION DE RESINE IGNIFUGE, SON PROCEDE DE FABRICATION, ARTICLES FORMES LA COMPRENANT ET SILICE
  申请人：NIPPON CATALYTIC CHEM IND

  公开号：WO2003099934A1

  公开（公告）日：2003-12-04

  The present invention has for its object to provide a fire retardant resin composition which is not only halogen-free and, hence, eliminating the adverse effect to the environment and human physiology but also reflecting an excellent fire retardancy imparted to a polyphenol having inherently favorable physical properties and heat resistance. The present invention is a fire retardant resin composition comprising a polyphenol compound and an inorganic microfine particle, wherein said polyphenol compound has such a structure that aromatic units each having at least one phenolic hydroxyl group are connected to one another through an organic unit containing two or more carbon atoms, and said inorganic microfine particle is a product of hydrolysis and condensation of an alkoxide compound and/or a carboxylic acid salt compound.

  本发明的目的是提供一种阻燃树脂组合物，该组合物不仅不含卤素，从而消除了对环境和人体生理的不良影响，而且还通过一种具有内在良好物理特性和耐热性的聚苯酚表现出优异的阻燃性。本发明是一种阻燃树脂组合物，包含聚苯酚化合物和无机超微细颗粒，其中所述聚苯酚化合物具有这样的结构，即每个具有至少一个苯酚羟基的芳香单元通过包含两个或更多碳原子的有机单元相互连接，所述无机超微细颗粒是由烷氧基化合物和/或羧酸盐化合物水解和缩聚得到的产品。
• TIECCO, MARCELLO;TESTAFERRI, LORENZO;TINGOLI, MARCO;CHIANELLI, DONATELLA;+, TETRAHEDRON, 44,(1988) N 8, 2261-2272
  作者：TIECCO, MARCELLO、TESTAFERRI, LORENZO、TINGOLI, MARCO、CHIANELLI, DONATELLA、+

  DOI：——

  日期：——