N,N'-[Methylenedi(4,1-phenylene)]bis(N-phenylaniline) | 136482-43-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-[Methylenedi(4,1-phenylene)]bis(N-phenylaniline)
• 英文别名: N,N-diphenyl-4-[[4-(N-phenylanilino)phenyl]methyl]aniline
• CAS: 136482-43-4
• 化学式: C₃₇H₃₀N₂
• 分子量: 502.659
• InChiKey: XKCPSCKPIANTKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  39
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-[Methylenedi(4,1-phenylene)]bis(N-phenylaniline) 在 对甲苯磺酸 、 zinc(II) chloride sodium tetrahydroborate 、 乙醇 、 三氯氧磷 作用下， 以 四氢呋喃 、 邻二氯苯 为溶剂， 反应 22.0h， 生成 4-[[4-[4-(oxan-2-yloxymethyl)-N-[4-(oxan-2-yloxymethyl)phenyl]anilino]phenyl]methyl]-N,N-bis[4-(oxan-2-yloxymethyl)phenyl]aniline
  参考文献：
  名称：

  [EN] NEW TETRAHYDROPYRANYL COMPOUND AND METHOD FOR PRODUCING THE TETRAHYDROPYRANYL COMPOUND
  [FR] NOUVEAU COMPOSÉ TÉTRAHYDROPYRANYLE ET PROCÉDÉ DE PRODUCTION DU COMPOSÉ TÉTRAHYDROPYRANYLE

  摘要：

  提供以下通式（1）所代表的四氢吡喃基化合物：通式（1）中，X表示取代或未取代的烷基、氧原子以及取代或未取代的芳香烃基中的任意一个；R1、R2、R3、R4、R5和R6分别表示氢原子、甲基和乙基中的任意一个；n表示1到4之间的整数。

  公开号：

  WO2011158950A1
• 作为产物：
  描述：

  bis(4-(diphenylamino)phenyl)methylium tetrafluoroborate 在 二氢吡啶 作用下， 以 二氯甲烷 为溶剂， 生成 N,N'-[Methylenedi(4,1-phenylene)]bis(N-phenylaniline)
  参考文献：
  名称：

  1,4-二氢吡啶的氢化物给体能力：与π亲核试剂和硼氢化物阴离子的比较

  摘要：

  二氢吡啶像吲哚怎么样？两组化合物的亲核参数N相似，因此它们是亚胺催化的α，β-不饱和醛的亚胺催化反应的合适底物。1,4-二氢吡啶的N参数是由氢化物转移至苯甲酸铵离子的速率得出的（请参阅方案）。

  DOI：

  10.1002/anie.200804263

文献信息

• Towards a Comprehensive Hydride Donor Ability Scale
  作者：Markus Horn、Ludwig H. Schappele、Gabriele Lang-Wittkowski、Herbert Mayr、Armin R. Ofial

  DOI：10.1002/chem.201202839

  日期：2013.1.2

  Rates of hydride transfer from several hydride donors to benzhydrylium ions have been measured at 20 °C and used for the determination of empirical nucleophilicity parameters N and sN according to the linear free energy relationship log k20 °C=sN(N+E). Comparison of the rate constants of hydride abstraction by tritylium ions with those calculated from the reactivity parameters sN, N, and E showed fair

  从几个氢化物供体到benzhydrylium离子氢化物转移率在20℃下被测量和用于经验亲核性参数的确定Ñ和š Ñ根据线性自由能关系日志 ķ 20℃ =小号Ñ（Ñ + Ë）。ity离子对氢化物提取速率常数与根据反应性参数s N，N和E计算得出的速率常数的比较显示出合理的一致性。因此，有可能将大量关于三苯甲烷离子氢化物提取的文献数据转化为N和相应氢化物供体的s N参数，并为氢化物供体建立覆盖20个数量级以上的反应性标度。
• DELAYED FLUORESCENCE MATERIAL AND ORGANIC LIGHT EMITTING DEVICE HAVING THE DELAYED FLUORESCENCE MATERIAL
  申请人：RESEARCH & BUSINESS FOUNDATION SUNGKYUNKWAN UNIVERSITY

  公开号：US20180114924A1

  公开（公告）日：2018-04-26

  A delayed fluorescence material is disclosed. The delayed fluorescence material has a molecular structure that includes an electron donor unit that donates electrons; and an electron acceptor unit that is coupled to the electron donor unit and accepts electrons, wherein the electron acceptor unit includes an indolocarbazole group having at least one acceptor functional-group bound to the indolocarbazole group. Thus, the delayed fluorescence material exhibits high structural and thermal stability as well as high quantum efficiency.

  公开了一种延迟荧光材料。该延迟荧光材料具有分子结构，包括捐赠电子的电子给体单元；以及与电子给体单元耦合并接受电子的电子受体单元，其中电子受体单元包括至少一个与吲哚并咔唑基团结合的受体功能基团。因此，该延迟荧光材料表现出高结构和热稳定性以及高量子效率。
• METHYLOL COMPOUND, ALDEHYDE COMPOUND, METHOD FOR PREPARING THE METHYLOL COMPOUND USING THE ALDEHYDE COMPOUND, AND PHOTORECEPTOR USING THE METHYLOL COMPOUND
  申请人：Tanaka Yuuji

  公开号：US20110081607A1

  公开（公告）日：2011-04-07

  A methylol compound having a specific formula such that two triphenylamine groups each having two methylol groups are connected with each other by an oxygen atom, a methylene group, a vinylene group, or an ethylene group. The methylol compound is preferably prepared by subjecting a corresponding aldehyde compound to a reduction reaction in the presence of a reducing agent. The methylol compound is preferably used as a charge transport material.
• TETRAHYDROPYRANYL COMPOUND AND METHOD FOR PRODUCING THE TETRAHYDROPYRANYL COMPOUND
  申请人：Tanaka Yuuji

  公开号：US20120142948A1

  公开（公告）日：2012-06-07

  To provide a tetrahydropyranyl compound represented by General Formula (1) below: General Formula (1) where X denotes any one of a substituted or unsubstituted alkyl group, an oxygen atom, and a substituted or unsubstituted aromatic hydrocarbon group, R 1 , R 2 , R 3 , R 4 , R 5 and R 6 each denote any one of a hydrogen atom, a methyl group and an ethyl group, and n denotes an integer of 1 to 4.
• CHARGE-TRANSPORTING VARNISH
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20170104161A1

  公开（公告）日：2017-04-13

  A charge-transporting thin film, which enables the achievement of an organic EL element having excellent durability in cases where the charge-transporting thin film is applied to a hole injection layer of the element, is obtained using a charge-transporting varnish that contains a charge-transporting substance, a nonionic fluorine-containing surfactant and an organic solvent, and wherein the nonionic fluorine-containing surfactant has, for example, a perfluoroalkenyl group-containing perfluorohydrocarbon structure represented by one of formulae (1)-(3) and an alkylene oxide structure.