N-[4-(2-甲酰基肼基)苯基]-N'-苯基硫脲 | 63148-78-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-[4-(2-甲酰基肼基)苯基]-N'-苯基硫脲
• 英文名称: 1-[4-(2-Formylhydrazino)phenyl]-3-phenylthiourea
• 英文别名: Thiourea, N-[4-(2-formylhydrazino)phenyl]-N'-phenyl-；N-[4-(phenylcarbamothioylamino)anilino]formamide
• CAS: 63148-78-7
• 化学式: C₁₄H₁₄N₄OS
• 分子量: 286.357
• InChiKey: SKDQTLDBZMLKQA-UHFFFAOYSA-N

物化性质

• 沸点：
  437.3±55.0 °C(Predicted)
• 密度：
  1.408±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  97.3
• 氢给体数：
  4
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-(4-硝基苯基)肼甲醛 在 palladium on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 生成 N-[4-(2-甲酰基肼基)苯基]-N'-苯基硫脲
  参考文献：
  名称：

  FR2320290

  摘要：

  公开号：

文献信息

• Acyl hydrazino thiourea derivatives as photographic nucleating agents
  申请人：Eastman Kodak Company

  公开号：US04031127A1

  公开（公告）日：1977-06-21

  Photographic nucleating agents are disclosed of the formula ##STR1## wherein R is a hydrogen, phenyl, alkylphenyl, cyanophenyl, halophenyl, alkoxyphenyl, alkyl, cycloalkyl, haloalkyl, alkoxyalkyl or phenylalkyl substituent; R.sup.1 is a phenylene or alkyl, halo- or alkoxy substituted phenylene group; R.sup.2 is an alkyl, haloalkyl, alkoxyalkyl or phenylalkyl substituent having up to 18 carbon atoms; a cycloalkyl substituent; phenyl or naphthyl; an alkylphenyl, cyanophenyl, halophenyl or alkoxyphenyl substituent or ##STR2## R.sup.3 is hydrogen, benzyl, alkoxybenzyl, halobenzyl or alkylbenzyl; THE ALKYL MOIETIES, EXCEPT AS OTHERWISE NOTED, IN EACH INSTANCE INCLUDE FROM 1 TO 6 CARBON ATOMS; AND The cycloalkyl moieties have from 3 to 10 carbon atoms.

  揭示了具有以下结构的光致核化剂##STR1##其中R是氢、苯基、烷基苯基、氰基苯基、卤基苯基、烷氧基苯基、烷基、环烷基、卤代烷基、烷氧基烷基或苯基烷基取代基；R.sup.1是苯基或烷基、卤代或烷氧基取代的苯基团；R.sup.2是具有最多18个碳原子的烷基、卤代烷基、烷氧基烷基或苯基烷基取代基；环烷基取代基；苯基或萘基；烷基苯基、氰基苯基、卤基苯基或烷氧基苯基取代基或##STR2##R.sup.3是氢、苄基、烷氧基苄基、卤代苄基或烷基苄基；除非另有说明，每种情况中烷基基团包括1至6个碳原子；环烷基基团具有3至10个碳原子。
• Photographic compositions and elements including internal latent image
  申请人：Eastman Kodak Company

  公开号：US04030925A1

  公开（公告）日：1977-06-21

  A radiation-sensitive composition is disclosed including silver halide grains capable of forming an internal latent image and an acylhydrazinophenylthiourea nucleating agent. This composition can be used as a coating on a support to form a photographic element.

  公开了一种辐射敏感的组合物，其中包括能够形成内部隐像的银卤化物颗粒和酰肼基苯硫脲成核剂。该组合物可用作涂层于支撑体上以形成摄影元素。
• Photographic element containing a temporary barrier layer between reactants and polymeric compositions useful therein
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0009795A2

  公开（公告）日：1980-04-16

  A photographic element containing a temporary barrier layer between reactants and polymeric compositions useful therein are disclosed. The compositions comprise a mixture of (1) from 5 to 95 percent by weight of a polymer comprising from 55 to 85 percent by weight of vinylidene chloride, 5 to 35 percent by weight of an ethylenically unsaturated monomer, and optionally from 0 to 20 percent by weight of an ethylenically unsaturated carboxylic acid, and (2) from 95 to 5 percent by weight of a polymeric carboxy-ester-lactone. A barrier formed from such composition is particularly useful as a process timing layer in color image transfer photographic elements.

  本发明公开了一种在反应物之间含有临时阻挡层的感光元件和对其有用的聚合物组合物。 这些组合物包括以下物质的混合物：(1) 5%至 95%（按重量计）的聚合物，其中包括 55%至 85%（按重量计）的亚乙烯基氯化物、5%至 35%（按重量计）的乙烯基不饱和单体，以及 0%至 20%（按重量计）的乙烯基不饱和羧酸；(2) 95%至 5%（按重量计）的聚合物羧基酯-内酯。 由这种组合物形成的阻挡层尤其可用作彩色图像转移感光元件中的加工定时层。
• Photographic element containing a ballasted, bifunctional benzisoxazolone compound
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0011566A1

  公开（公告）日：1980-05-28

  A photographic element is described which contains a ballasted, bifunctional benzisoxazolone compound of the formula: wherein: R is alkyl or aryl; DEV is a silver halide developing agent; Ball is at least one organic ballasting radical of such molecular size and configuration as to render the compound nondiffusible in the photographic element during development in an alkaline processing composition; and n is a positive integer of 1 to 3. The compound may be employed in a negative-working, color image transfer element to release the developer upon processing. The remainder of the compound functions to scavenge oxidized developer.

  描述了一种感光元件，它含有一种压载的双功能苯并异噁唑酮化合物，其式如下： 其中：R 是烷基或芳基；DEV 是卤化银显影剂；Ball 是至少一个有机压载基，其分子大小和构型使该化合物在碱性冲洗组合物中显影时在感光元件中无法扩散；n 是 1 到 3 的正整数。 该化合物可用于底片工作的彩色图像传输元件中，以便在冲洗时释放显影剂。 该化合物的其余部分具有清除氧化显影剂的功能。
• Photographic element comprising a ballasted 2,5-disulfonamidophenol scavenger compound
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0011567A1

  公开（公告）日：1980-05-28

  A Photographic element is described which comprises a ballasted 2,5-di-sulfonamidophenol compound used to scavenge oxidized electron transfer agents in color image transfer materials. The scavenger compound can be located in an emulsion layer, a dye image-providing material layer or an interlayer.

  描述了一种摄影元件，它包括一种压载的 2,5-二磺酰胺基苯酚化合物，用于清除彩色图像传输材料中的氧化电子转移剂。 清除剂化合物可位于乳剂层、染料图像提供材料层或中间层中。