trans-isothiocyanato(pyridine)bis(dimethylglyoximato)cobalt(III) | 30235-61-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: trans-isothiocyanato(pyridine)bis(dimethylglyoximato)cobalt(III)
• CAS: 30235-61-1
• 化学式: C₁₄H₁₉CoN₆O₄S
• 分子量: 426.402
• InChiKey: CILIMKHNKIJSMG-DVTASQICSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  盐酸 、 trans-isothiocyanato(pyridine)bis(dimethylglyoximato)cobalt(III) 在 vanadium(II) perchlorate 作用下， 以 水 、 二甲基亚砜 为溶剂， 生成 tetrachlorocobaltate(II)(2-)
  参考文献：
  名称：

  Balasubramanian, P. N.; Vijayaraghavan, V. R., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1981, vol. 20, # 9, p. 892 - 895

  摘要：

  DOI：
• 作为产物：
  描述：

  吡啶 、 [Co(dimethylglyoxime)₂(NCS)₂] 以 甲醇 为溶剂， 反应 1.0h， 以50%的产率得到trans-isothiocyanato(pyridine)bis(dimethylglyoximato)cobalt(III)
  参考文献：
  名称：

  Proton reduction using cobalt glyoximes with isothiocyanate and aniline axial ligands

  摘要：

  Cobaloxime model complexes containing aniline derivatives and isothiocyanate as the axial ligands Co(dmgH)(2)XY (dmgH = dimethylglyoxime, X = NCS, Cl and Y = aniline, pyridine) have been synthesized and used as proton reduction catalysts. Using acetic acid as the proton source in acetonitrile, cyclic voltammetry studies have shown that these complexes are comparable to the well-known Co(dmgH)(2)(pyridine)CI complex as a potent catalyst in terms of the overpotential and catalytic efficiency of proton reduction. In particular, we have shown that aniline derivatives can be used as possible pyridine alternatives in cobaloximes in our continuing search for an even more efficient proton reduction catalyst. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2015.04.030