2-{[(4-bromophenyl)methylene]amino}-4-methylphenol | 878193-83-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-{[(4-bromophenyl)methylene]amino}-4-methylphenol
• 英文别名: (E)-2-((4-bromobenzylidene)amino)-4-methylphenol
• CAS: 878193-83-0
• 化学式: C₁₄H₁₂BrNO
• 分子量: 290.159
• InChiKey: LXBPPUIQUCCKHL-CXUHLZMHSA-N

物化性质

• 沸点：
  441.1±45.0 °C(Predicted)
• 密度：
  1.35±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.21
• 重原子数：
  17.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  32.59
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2-{[(4-bromophenyl)methylene]amino}-4-methylphenol 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 eosin Y bis(tetrabutyl ammonium salt) 作用下， 20.0 ℃ 、101.33 kPa 条件下， 以87%的产率得到2-(4-bromophenyl)-5-methylbenzo[d]oxazole
  参考文献：
  名称：

  Synthesis of 2-substituted pyrimidines and benzoxazoles via a visible-light-driven organocatalytic aerobic oxidation: enhancement of the reaction rate and selectivity by a base

  摘要：

  利用有机光催化剂藻红Y双(四丁基铵盐)(TBA-藻红Y)和廉价氧化剂分子氧，已经实现了各种2-取代二氢嘧啶和酚亚胺的高效可见光驱动光催化氧化反应。在碱的辅助下，从底物二氢嘧啶或酚亚胺到TBA-藻红Y激发态的显著增强的光诱导电子转移，使得空气氧化能够选择性地生成2-(甲硫基)嘧啶或2-芳基苯并噁唑。

  DOI：

  10.1039/c4gc00337c
• 作为产物：
  描述：

  对溴苯甲醛 、 邻氨基对甲苯酚 在 三甲基氯硅烷 、 三乙胺 、 水 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以70%的产率得到2-{[(4-bromophenyl)methylene]amino}-4-methylphenol
  参考文献：
  名称：

  三甲基氯硅烷促进(杂)芳族邻二胺或邻氨基苯硫酚与醛合成稠合咪唑和苯并噻唑

  摘要：

  描述了苯并咪唑和苯并噻唑合成的新便利条件。一组苯并咪唑、3H-咪唑并[4,5-b]吡啶、嘌呤、黄嘌呤和苯并噻唑很容易由（杂）芳族邻二胺或邻氨基苯硫酚和醛在 DMF 中使用三甲基氯硅烷作为促进剂和水受体制备剂，然后用空气氧氧化。

  DOI：

  10.1055/s-2006-950289

文献信息

• Mechanism of oil-in-water emulsification using a water-soluble amphiphilic polymer and lipophilic surfactant
  作者：Eri Akiyama、Akio Kashimoto、Hajime Hotta、Tomohito Kitsuki

  DOI：10.1016/j.jcis.2006.03.066

  日期：2006.8

  A new O/W (oil-in-water) emulsification system was developed using the amphiphilic polymer HHM-HEC (hydrophobically-hydrophilically modified hydroxyethyl cellulose) and a lipophilic surfactant. HHM-HEC was used as a thickener and polymeric surfactant, and the addition of small quantities of various types of nonionic lipophilic surfactant (hydrophilic-lipophilic balance < 5) decreased the droplet size of several types of oil due to a lowering of the tension at the water/oil interface. The oil droplets were held by the strong network structure of the aqueous HHM-HEC solution, preserving the O/W phase without inversion. These stable O/W emulsions were prepared without the addition of hydrophilic surfactants and thus show improved water repellency. (c) 2006 Elsevier Inc. All rights reserved.
• Chiral Brønsted Acid Catalyzed Enantioselective Aza-Diels–Alder Reaction of Brassard's Diene with Imines
  作者：Junji Itoh、Kohei Fuchibe、Takahiko Akiyama

  DOI：10.1002/anie.200601345

  日期：2006.7.17
• TRIBENZAZOLE AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING SAME
  申请人：LAPTO CO., LTD.

  公开号：US20220017503A1

  公开（公告）日：2022-01-20

  Provided is a tribenzazole amine derivative represented by Formula 1 that effectively absorbs high energy UV light from an external light source to minimize damage to organic materials present in an organic electroluminescent device, contributing to a substantial improvement in the lifetime of the organic electroluminescent device. Also provided is an organic electroluminescent device using the tribenzazole amine derivative. The organic electroluminescent device includes a first electrode, a second electrode, and an organic layer arranged between the first and second electrodes. The organic layer includes the tribenzazole amine derivative.
• [EN] TRIBENZAZOLE AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING SAME<br/>[FR] DÉRIVÉ D'AMINE TRIBENZAZOLE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT<br/>[KO] 트리벤즈아졸 아민 유도체 및 이를 포함한 유기 전계 발광 소자
  申请人：LAPTO CO LTD

  公开号：WO2020122359A1

  公开（公告）日：2020-06-18

  UV영역의 고에너지 외부 광원을 효과적으로 흡수하여 유기 전계 발광 소자 내부의 유기물들의 손상을 최소화함으로써 유기 전계 발광 소자의 실질적인 수명 향상에 기여하는 트리벤즈아졸 아민 유도체를 제공한다. 본 발명에 따른 유기 전계 발광 소자는, 제1 전극; 제2 전극; 및 상기 제1 전극과 제2 전극 사이에 배치된 유기물층;을 포함하고, 상기 유기물층은 본 발명에 따른 화학식 1로 표시되는 트리벤즈아졸 아민 유도체를 포함한다.