3-(propyloxymethyl)aniline | 80171-97-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(propyloxymethyl)aniline
• 英文别名: Benzenamine, 3-(propoxymethyl)-；3-(propoxymethyl)aniline
• CAS: 80171-97-7
• 化学式: C₁₀H₁₅NO
• 分子量: 165.235
• InChiKey: VGPVTPLWOKFGBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(propyloxymethyl)aniline 在 盐酸 、 sodium sulfide 、 sodium hydrogensulfite 、 sodium hydroxide 、 sodium nitrite 作用下， 以 乙醇 、 水 为溶剂， 反应 8.0h， 生成 4,4'-diamino-2-(propyloxymethyl)azobenzene
  参考文献：
  名称：

  アゾベンゼン誘導体及びその製造方法

  摘要：

  用于制造液晶显示器用聚酰亚胺光配向膜的原料的2-取代4,4'-二氨基偶氮苯类的制造中间体，以及有用的偶氮苯衍生物和其高效制造方法。通用式（1）所示的偶氮苯衍生物。R1代表氢原子，可取代的烷基，可取代的酰基或可取代的醚羰基。R2代表氢原子，可取代的芳基甲基，碱金属氧磺酰甲基或可取代的醚羰基。R3代表硝基，可取代的芳基甲基氨基，碱金属氧磺酰甲基氨基或可取代的醚羰基氨基。【选择图】无

  公开号：

  JP2019156841A
• 作为产物：
  描述：

  1-硝基-3-(丙氧基甲基)苯 在 盐酸 、 铁粉 作用下， 以 乙醇 、 水 为溶剂， 反应 2.0h， 以19.2 g的产率得到3-(propyloxymethyl)aniline
  参考文献：
  名称：

  アゾベンゼン誘導体及びその製造方法

  摘要：

  用于制造液晶显示器用聚酰亚胺光配向膜的原料的2-取代4,4'-二氨基偶氮苯类的制造中间体，以及有用的偶氮苯衍生物和其高效制造方法。通用式（1）所示的偶氮苯衍生物。R1代表氢原子，可取代的烷基，可取代的酰基或可取代的醚羰基。R2代表氢原子，可取代的芳基甲基，碱金属氧磺酰甲基或可取代的醚羰基。R3代表硝基，可取代的芳基甲基氨基，碱金属氧磺酰甲基氨基或可取代的醚羰基氨基。【选择图】无

  公开号：

  JP2019156841A

文献信息

• Polymer composition
  申请人：DSM N.V.

  公开号：EP0538939A1

  公开（公告）日：1993-04-28

  The invention relates to a polymer composition based on a thermoplastic polymer and a polyaniline, characterised in that the thermoplastic polymer contains functional monomeric units and the polyaniline is grafted onto the thermoplastic polymer substantially through the reaction of the terminal NH₂ group of the polyaniline with a functional monomeric unit of the thermoplastic polymer. It has been found that the polymer composition according to the invention has good thermoplastic processability as well as good conductive properties. The polymer composition according to the invention is extremely suitable for the production of all kinds of objects.

  本发明涉及一种基于热塑性聚合物和聚苯胺的聚合物组合物，其特征在于热塑性聚合物含有官能团单体单元，而聚苯胺基本上是通过聚苯胺的末端 NH₂基团与热塑性聚合物的官能团单体单元反应接枝到热塑性聚合物上的。研究发现，本发明的聚合物组合物具有良好的热塑性加工性能和导电性能。本发明的聚合物组合物非常适用于生产各种物品。
• Method for the preparation of a polymeric shaped article containing an electrically conductive polymer
  申请人：DSM N.V.

  公开号：EP0587204A1

  公开（公告）日：1994-03-16

  The invention relates to a method for the preparation of a polymeric shaped article containing an electrically conductive polymer, wherein a base shaped article containing a matrix polymer is contacted with an anode in the presence of an electrolyte-containing medium containing monomer units, which on polymerisation to form an electrically conductive polymer, and wherein a voltage is applied between the anode and a second electrode which is in contact with the electrolyte-containing medium. The method according to the invention is characterised in that the applied base shaped article possesses electrically conducting properties and that the contact between the shaped article and the anode is established by moving the article along the anode, at least part of the article being in contact with the anode. It has appeared that, in the method according to the invention, the shaped article does not adhere to the electrode so that the method may be practised continuously. A further advantage of the shaped article failing to adhere to the electrode is that the method according to the invention generates very little waste. Furthermore, it has appeared that the method according to the invention allows a shaped article to be produced with a very short polymerisation time, the electrically conductive polymer in which being homogeneously distributed. The applied base shaped article does not swell during wetting, so that the mechanical properties of the base shaped article do not deteriorate. As a result, if the method is applied, for instance, continuously, a higher rate of production can be applied.

  本发明涉及一种制备含有导电聚合物的聚合物成型品的方法，其中含有基质聚合物的基质成型品在含有单体单元的含电解质介质存在下与阳极接触，单体单元聚合后形成导电聚合物，在阳极和与含电解质介质接触的第二电极之间施加电压。根据本发明的方法，其特征在于所应用的基底成型品具有导电性能，成型品和阳极之间的接触是通过沿阳极移动成型品来建立的，成型品的至少一部分与阳极接触。根据本发明的方法，成型物品不会粘附在电极上，因此该方法可以连续使用。成型物品不附着在电极上的另一个优点是，根据本发明的方法产生的废料极少。此外，根据本发明的方法可以在很短的聚合时间内生产出异型制品，其中的导电聚合物分布均匀。在润湿过程中，应用的基底成型品不会膨胀，因此基底成型品的机械性能不会降低。因此，如果连续使用该方法，可以提高生产率。
• Dispersion of electrically conductive particles in a dispersing medium
  申请人：DSM N.V.

  公开号：EP0589529A1

  公开（公告）日：1994-03-30

  The invention relates to a dispersion of electrically conductive particles, comprising a binder and an electrically conductive polymer, and a stabiliser in a dispersing medium. The dispersion according to the invention is characterised in that the particles contain a non-ionic stabiliser. It has been found that the stability of the dispersion according to the invention is very good. In addition the dispersion according to the invention is extremely suitable for providing objects with a coating in a simple manner. The applied coating has good electrically conductive properties as well as good coating properties. The applied coating is homogeneously distributed over the coated object. Moreover the applied coating appears to adhere well to the object.

  本发明涉及一种导电微粒的分散体，包括分散介质中的粘合剂、导电聚合物和稳定剂。根据本发明的分散体的特点是颗粒中含有非离子稳定剂。研究发现，本发明的分散液稳定性非常好。此外，本发明的分散体非常适合以简单的方式为物体提供涂层。涂覆的涂层具有良好的导电性能和涂覆性能。涂层均匀地分布在被涂物体上。此外，涂覆的涂层看起来与物体附着良好。
• Aqueous coating dispersion, process for the preparation thereof and use thereof in anticorrosive paint
  申请人：DSM N.V.

  公开号：EP0821040A1

  公开（公告）日：1998-01-28

  The invention relates to an aqueous coating dispersion comprising at least electrically conductive particles, which particles comprise at least a first binder, a conductive polymer and a non-ionic stabiliser, characterised in that the coating dispersion contains 50 to 99 wt. %, relative to the total amount of solids present, of a second binder, which second binder consists of electrically non-conductive particles. The invention also relates to a process for the preparation of the aqueous coating dispersion and to the use thereof in an anticorrosive paint, to the anticorrosive paint based on the aqueous coating dispersion according to the invention and to the metals protected herewith.

  本发明涉及一种水性涂料分散体，该分散体至少包含导电颗粒，该导电颗粒至少包含第一粘合剂、导电聚合物和非离子稳定剂，其特征在于该涂料分散体包含相对于固体总量为50-99重量％的第二粘合剂，该第二粘合剂由不导电颗粒组成。本发明还涉及水性涂料分散体的制备工艺及其在防腐涂料中的应用，以及基于本发明水性涂料分散体的防腐涂料和受其保护的金属。
• Process to make a conductive composition of a fluorinated polymer which contains polyaniline
  申请人：Atofina

  公开号：EP1428857A1

  公开（公告）日：2004-06-16

  The process of the present invention is a process to make a conductive fluorinated polymer composition (also called composite) wherein : a) an aqueous solution of an anilinium salt is mixed with an aqueous dispersion of a fluorinated polymer, b) then an oxidant is added to the mixture of step a) to make a blend of said fluorinated polymer and doped polyaniline (PANI), c) by-products and unreacted aniline are removed by washing with water or an alcohol to get a blend of purified fluorinated polymer and doped PANI, d) eventually the purified fluorinated polymer and doped PANI of step c) can be mixed with an acid, e) water is removed from the purified fluorinated polymer and doped PANI of step c) or d) if any and the remaining powder is melted and shaped in films, pellets or any object.

  本发明的工艺是一种制造导电含氟聚合物组合物（又称复合材料）的工艺，其中： a) 将苯胺盐的水溶液与含氟聚合物的水分散液混合、 b) 然后向步骤 a) 的混合物中加入氧化剂，制成所述含氟聚合物和掺杂聚苯胺（PANI）的混合物、 c) 通过水或酒精洗涤去除副产物和未反应的苯胺，得到纯化的含氟聚合物和掺杂的 PANI 混合物、 d) 最终将步骤 c) 中纯化的含氟聚合物和掺杂的 PANI 与酸混合、 e) 除去步骤 c) 或 d) 中纯化的含氟聚合物和掺杂的 PANI（如有）中的水分，将剩余粉末熔化并制成薄膜、颗粒或任何物体。