N-p-Tolylsulfonylethyl-methylamin | 61097-92-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-p-Tolylsulfonylethyl-methylamin
• 英文别名: N-methyl-2-tosylethan-1-amine；N-methyl-2-(4-methylphenyl)sulfonylethanamine
• CAS: 61097-92-5
• 化学式: C₁₀H₁₅NO₂S
• 分子量: 213.301
• InChiKey: MJJAJZHOLKMOCO-UHFFFAOYSA-N

物化性质

• 沸点：
  373.9±42.0 °C(Predicted)
• 密度：
  1.126±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  54.6
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2922399090

反应信息

• 作为产物：
  描述：

  对甲苯基乙烯基砜 、 甲胺 生成 N-p-Tolylsulfonylethyl-methylamin
  参考文献：
  名称：

  消除和加成反应。第二十七部分。将酰胺加到亲电烯烃中

  摘要：

  用强碱和亲电烯烃（丙烯腈或对甲苯基乙烯基砜）处理来自伯胺的酰胺，可得自酰胺的N-烷基化反应的产物。当使用不带有NH键的酰胺时，除非酰胺对质子提取具有稳定的碳负离子，否则不会发生任何反应。然后发生C-烷基化。当N-和C-烷基化可以竞争时，N-烷基化是优选的。

  DOI：

  10.1039/p19760001543

文献信息

• WATER-BASED INK, INK JET RECORDING METHOD, INK CARTRIDGE, RECORDING UNIT, INK JET RECORDING APPARATUS, AND IMAGE FORMING METHOD
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150029241A1

  公开（公告）日：2015-01-29

  A water-based ink of the present invention comprises water, a plurality of different water-soluble organic solvents, and a water-insoluble coloring material, wherein the above water-soluble organic solvents consist of a good solvent to the above water-insoluble coloring material and a poor solvent to the above water-insoluble coloring material, and the total amount (% by mass) of the good solvents in the ink is represented by A and the total amount (% by mass) of the poor solvent in the ink is represented by B, the ratio of A to B ranges from 10:5 to 10:30 both inclusive, and when the respective Ka values of the above water-soluble organic solvents are determined by the Bristow method and compared with each other, a water-soluble organic solvent having the largest Ka value is the poor solvent. The pigment ink has a sufficiently large area factor even with a small amount of ink and provides an image of high OD.
• US7605192B2
  申请人：——

  公开号：US7605192B2

  公开（公告）日：2009-10-20
• US9180680B2
  申请人：——

  公开号：US9180680B2

  公开（公告）日：2015-11-10
• Elimination and addition reactions. Part XXVII. Addition of amides to electrophilic alkenes
  作者：John W. Batty、Peter D. Howes、Charles J. M. Stirling

  DOI：10.1039/p19760001543

  日期：——

  Treatment of amides from primary amines with strong bases and electrophilic alkenes (acrylonitrile or p-tolyl vinyl sulphone) gives products derived from N-alkylation of the amide. When amides without an N–H bond are used, no reaction occurs unless the amide gives a stabilised carbanion on proton abstraction; C-alkylation then occurs. When N- and C-alkylation can compete, N-alkylation is preferred

  用强碱和亲电烯烃（丙烯腈或对甲苯基乙烯基砜）处理来自伯胺的酰胺，可得自酰胺的N-烷基化反应的产物。当使用不带有NH键的酰胺时，除非酰胺对质子提取具有稳定的碳负离子，否则不会发生任何反应。然后发生C-烷基化。当N-和C-烷基化可以竞争时，N-烷基化是优选的。