2,7-dibromo-2’,3’,6’,7’-tetramethoxy-9,9'-spirobifluorene | 1443550-46-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,7-dibromo-2’,3’,6’,7’-tetramethoxy-9,9'-spirobifluorene
• 英文别名: 2',7'-Dibromo-2,3,6,7-tetramethoxy-9,9'-spirobi[fluorene]；2',7'-dibromo-2,3,6,7-tetramethoxy-9,9'-spirobi[fluorene]
• CAS: 1443550-46-6
• 化学式: C₂₉H₂₂Br₂O₄
• 分子量: 594.299
• InChiKey: DIIPJRITUKACIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,7-二溴-9-芴酮 在 甲烷磺酸 、 molybdenum pentachloride 、 sodium hydride 作用下， 以 四氯化碳 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 61.25h， 生成 2,7-dibromo-2’,3’,6’,7’-tetramethoxy-9,9'-spirobifluorene
  参考文献：
  名称：

  Modular Access to 9,9-Spirobifluorenes by Oxidative Coupling Using Molybdenum Pentachloride

  摘要：

  The strong oxidizing agent molybdenum pentachloride was used for an efficient direct C-C bond formation of 9,9-diarylfluorenes to the corresponding 9,9-spirobifluorenes. Thus, a versatile method that is compatible with labile groups, such as iodo moieties, was established. By this approach important building blocks for light emitting polymers were synthesized in high yields.

  DOI：

  10.1055/s-0033-1338297

文献信息

• Modular Access to 9,9-Spirobifluorenes by Oxidative Coupling Using Molybdenum Pentachloride
  作者：Siegfried Waldvogel、Simon Trosien、Dieter Schollmeyer

  DOI：10.1055/s-0033-1338297

  日期：——

  The strong oxidizing agent molybdenum pentachloride was used for an efficient direct C-C bond formation of 9,9-diarylfluorenes to the corresponding 9,9-spirobifluorenes. Thus, a versatile method that is compatible with labile groups, such as iodo moieties, was established. By this approach important building blocks for light emitting polymers were synthesized in high yields.