1-amino-10,12-pentacosadiyne | 86228-33-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-amino-10,12-pentacosadiyne
• 英文别名: 10,12-pentacosadiynylamine；10,12-Pentacosadiynamine；pentacosa-10,12-diyn-1-amine
• CAS: 86228-33-3
• 化学式: C₂₅H₄₅N
• 分子量: 359.639
• InChiKey: BXJGBWFGDHRYLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  26
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.84
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  顺,顺-已二烯二酸 、 1-amino-10,12-pentacosadiyne 以 甲醇 为溶剂， 生成 (Z,Z)-muconic 10,12-pentacosadiynylammonium
  参考文献：
  名称：

  PHOTORESPONSIVE POLYMER, BUILT-UP TYPE DIACETYLENE POLYMER, CRYSTALS OF AMMONIUM CARBOXYLATES, AND PROCESSES FOR PRODUCTION OF THEM

  摘要：

  公开号：

  EP1431266B1
• 作为产物：
  描述：

  10,12-二十五碳二炔酸 在 ammonium hydroxide 、 lithium aluminium tetrahydride 、 氯化亚砜 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 21.0h， 生成 1-amino-10,12-pentacosadiyne
  参考文献：
  名称：

  Lipophilic peptide nucleic acids containing a 1,3-diyne function: synthesis, characterization and production of derived polydiacetylene liposomes

  摘要：

  Adenine-, cytosine- and thymine-containing peptide nucleic acid (PNA) monomers have been synthesized in which either diacetylenic or stearoyl moieties are attached to the N-or C-terminus; the diacetylenic group is embedded within a long hydrocarbon chain. A range of analogous lipophilic functionalized PNA oligomers have been prepared using either solid phase synthesis or a post-synthetic solution phase procedure following cleavage of the PNA oligomer from the solid Support. Selected functionalized PNA monomers and oligomers have been incorporated into liposomal polydiacetylenes and characterized by UV-vis absorption spectroscopy. Preliminary investigations show that blue PDA-liposomes containing thymine-based PNAs can be formed and that production of liposomes with other PNA systems are viable. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.07.021

文献信息

• Polydiacetylene-nested porphyrin as a potential light harvesting component in bulk heterojunction solar cells
  作者：Chawanwit Reanprayoon、Jacek Gasiorowski、Mongkol Sukwattanasinitt、Niyazi Serdar Sariciftci、Patchanita Thamyongkit

  DOI：10.1039/c3ra45373a

  日期：——

  A meso-substituted zinc-porphyrin embedded in a polydiacetylene web was prepared and tested for its potential in bulk heterojunction solar cells (BHJ-SCs). Light assisted formation of the polyenynes from diacetylenes coupled to the meso-position of the porphyrin were observed after UV-radiation, as evidenced by double and triple bond Raman-bands at 1446 and 2080 cm−1, respectively, and via UV absorption enhancement at 530–600 nm. Using cyclic voltammetry, Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) energy levels were determined to be in an appropriate range for the photoactive materials in BHJ-SCs. Indeed, photoluminescence quenching indicated energy and/or charge transfer when the target material was used as a donor in combination with phenyl-C61-butyric acid methyl ester as acceptor in a blend. A photovoltaic effect of the BHJ-SCs was observed.

  研究人员制备了嵌入聚二乙炔网的中位取代锌卟啉，并测试了其在体异质结太阳能电池（BHJ-SC）中的应用潜力。在紫外线照射后，观察到由二乙炔与卟啉的介位耦合形成的光辅助聚烯炔，分别在 1446 和 2080 cm-1 处的双键和三键拉曼带以及 530-600 nm 处的紫外线吸收增强证明了这一点。利用循环伏安法，最高占位分子轨道（HOMO）和最低未占位分子轨道（LUMO）能级被确定在 BHJ-SC 中光活性材料的适当范围内。事实上，当目标材料作为供体与苯基-C61-丁酸甲酯作为受体混合使用时，光致发光淬灭表明了能量和/或电荷转移。BHJ-SCs 具有光伏效应。
• A polydiacetylene–nested porphyrin conjugate for dye-sensitized solar cells
  作者：Nuttapol Pootrakulchote、Chawanwit Reanprayoon、Jacek Gasiorowski、Niyazi Serdar Sariciftci、Patchanita Thamyongkit

  DOI：10.1039/c5nj01583a

  日期：——

  A novel polydiacetylene–nested porphyrin photosensitizer was prepared and explored for its potential in dye-sensitized solar cells.

  一种新型的聚二炔-嵌套卟啉光敏剂已经制备并探索其在染料敏化太阳能电池中的潜力。
• Photoresponsive polymer, built-up type diacetylene polymer, crystals of ammonium carboxylates, and processes for production of them
  申请人：Matsumoto Akikazu

  公开号：US20050038284A1

  公开（公告）日：2005-02-17

  A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH 2 NH 2 , where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by -Ar-N═N-Ar′-, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtaind. Also obtained is a crystal of ammonium carboxylate including at least one kind of carboxyl acid and at least one kind of amine, at least one kind of compound selected from (i) the at least one kind of carboxyl acid and (ii) the at least one kind of amine being a diacetylene derivative. The crystal of ammonium carboxylate is subjected to light or heat, to obtain a built-up type diacetylene polymer.

  将羧酸晶体和至少一种从胺和氨组成的化合物混合，无需液体介质。羧酸是共轭二烯，例如（Z，Z）-巴苯二酸，共轭二烯包括一个羧基。从胺和氨组成的至少一种含氮化合物是由RCH2NH2表示的一级胺，其中R是芳基，或者是包含五个或更多碳原子的正常烷基。此外，这样的胺是一个双价基团，由-Ar-N═N-Ar'表示，其中Ar和Ar'是独立的芳香族碳氢化合物双价基团，插入到聚巴苯二酸等聚合物的层状晶体中，该层状晶体包括一个羧基。通过这种方式，获得了一种新型光响应性聚合物。同时，获得了至少包含一种羧酸和至少一种胺的羧酸铵晶体，其中来自（i）至少一种羧酸和（ii）至少一种胺的化合物中的至少一种是二乙炔衍生物。将羧酸铵晶体暴露于光或热以获得堆积型二乙炔聚合物。
• Photoresponsive polymer,built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them
  申请人：Matsumoto Akikazu

  公开号：US20090253870A1

  公开（公告）日：2009-10-08

  A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH 2 NH 2 , where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained. Also obtained is a crystal of ammonium carboxylate including at least one kind of carboxyl acid and at least one kind of amine, at least one kind of compound selected from (i) the at least one kind of carboxyl acid and (ii) the at least one kind of amine being a diacetylene derivative. The crystal of ammonium carboxylate is subjected to light or heat, to obtain a built-up type diacetylene polymer.

  将羧酸晶体和至少一种从胺和氨组成的化合物混合在无液介质的情况下。羧酸是共轭二烯，例如(Z,Z)-巨环酸，共轭二烯包括一个羧基。从胺和氨组成的至少一种含氮化合物是由RCH2NH2表示的一级胺，其中R是芳基，或者是含有五个或更多碳原子的正常烷基。此外，这样的胺是一个双价基团，由—Ar—N═N—Ar′—表示，其中Ar和Ar′是独立的芳香族碳氢双价基团，被插入在聚合物的分层晶体中，例如聚巨环酸，分层晶体包括一个羧基。通过这种方式，获得了一种新型的光响应聚合物。同时获得了一种羧酸铵晶体，包括至少一种羧酸和至少一种胺，从(i)至少一种羧酸和(ii)至少一种胺中选出的至少一种化合物是二乙炔衍生物。将羧酸铵晶体经过光或热处理，获得一个堆积型二乙炔聚合物。
• Process for manufacturing a sub-nanometer-thick coating on an amorphous material, exhibiting nanometer-scale chemical patterns
  申请人：Purdue Research Foundation

  公开号：US11193042B2

  公开（公告）日：2021-12-07

  The present invention generally relates to a method for creating a chemically structured surface with structural elements as small as 1 nm, on a material that does not itself display a high degree of ordering, using thin molecular layers that minimize the material added through the coating. In particular, the present invention discloses a method for assembling a chemical pattern on a surface, comprising pattern elements with scales that can be as small as 1 nm, and then transferring that pattern to another substrate, on which the pattern would not form natively. In the described method, the patterned monolayer is comprised of polymerizable amphiphiles such as diyne phospholipids or diynoic acids, which are transferred from the ordering substrate using a transferring material such as poly(dimethylsiloxane).

  本发明一般涉及一种在本身不显示高度有序化的材料上，使用薄分子层创建化学结构表面的方法，该化学结构表面的结构元素可小至 1 纳米，通过涂层最大限度地减少添加的材料。具体而言，本发明公开了一种在表面上组装化学图案的方法，该图案由刻度可小至 1 纳米的图案元素组成，然后将该图案转移到另一种基底上，而该基底上不会自然形成该图案。在所述方法中，图案单层由可聚合的双亲化合物组成，如二炔磷脂或二炔酸，使用聚（二甲基硅氧烷）等转移材料将其从有序基底转移。