3,5-di-tert-butyl salicylic acid monohydrate | 1215504-86-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-di-tert-butyl salicylic acid monohydrate
• 英文别名: 3,5-Ditert-butyl-2-hydroxybenzoic acid hydrate, AldrichCPR；3,5-ditert-butyl-2-hydroxybenzoic acid;hydrate
• CAS: 1215504-86-1
• 化学式: C₁₅H₂₂O₃*H₂O
• 分子量: 268.353
• InChiKey: QHTAUNQRZQQUFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.86
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  58.5
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (SiMe3)3CAlMe2(THF) 、 3,5-di-tert-butyl salicylic acid monohydrate 以 甲苯 为溶剂， 以60%的产率得到[(Me3Si)3CAl(μ-3,5-di-tert-butyl salicylic acid)]2(μ-O)*1.5THF
  参考文献：
  名称：

  [（Me 3 Si）3 CAlMe 2 ]与取代的苯甲酸的反应。稀有有机铝氧烷羧酸盐的分离

  摘要：

  研究了大体积的被三（三甲基甲硅烷基）甲基取代的三烷基铝[（Me 3 Si）3 CAlMe 2 ·THF]（1）与一系列取代的苯甲酸衍生物的反应性。的4-甲基苯甲酸或4-等摩尔反应叔丁基苯甲酸与1在甲苯中在50℃下导致形成环状二聚羧酸铝的[（ME 3 Si）的3的CA1（ME）（μ-O 2 CC 6 H 4 R）] 2（R = Me 2；t Bu 3）。3,5-二异氰酸酯的反应带有1的-丙基水杨酸（H 2 dipsa）导致三聚体有机铝羧酸盐[（Me 3 Si）3 CAl（μ-dipsa）] 3（4）的唯一分离，其中每个铝与两个羧酸盐结合，酚和一个烷基，生成一个12元大环。在甲苯中与1进行反应时，故意但有控制地引入3,5-二叔丁基水杨酸一水合物（H 2 dtbsa·H 2 O）形式的水，导致羧酸盐[[Me 3 Si）3 CAl（μ-O）（μ-Hdtbsa）} 2 ]（5）具有双环结构。化合物5

  DOI：

  10.1016/j.jorganchem.2011.06.024

文献信息

• COMPOUND FOR ORGANIC OPTOELECTRIC DEVICE, COMPOSITION FOR ORGANIC OPTOELECTRIC DEVICE AND ORGANIC OPTOELECTRIC DEVICE AND DISPLAY DEVICE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20180090690A1

  公开（公告）日：2018-03-29

  Disclosed are a compound for an organic optoelectric device represented by Chemical Formula 1, a composition for an organic optoelectric device, an organic optoelectric device including the same, and a display device. Details of Chemical Formula 1 are the same as those defined in the specification.

  公开了一种化学式1所代表的有机光电器件化合物，一种用于有机光电器件的组合物，包括该化合物的有机光电器件和显示装置。化学式1的详细信息与说明书中定义的相同。
• Toner for developing electrostatic latent image, charge control agent for use in the toner, and process for preparing the charge control agent
  申请人：Toyo Ink Manufacturing Co., Ltd.

  公开号：US20010049068A1

  公开（公告）日：2001-12-06

  A toner for developing an electrostatic latent image is disclosed, which contains as a charge control agent a trivalent chromium salt of salicylic acid or a derivative thereof represented by the following general formula; 1 wherein R 1 , R 2 and R 3 each represents a hydrogen atom, a saturated or unsaturated, straight or branched alkyl group or, when taken together, R 1 and R 2 or R 2 and R 3 form a fused ring optionally having a saturated or unsaturated, straight or branched alkyl group, and n represents 0, 1 or 2 . The trivalent chromium salts are formed by adding an aqueous solution of alkali metal salt of salicylic acid or a derivative thereof having a pH of 6.5 to less than 7.0 to an aqueous solution of a chromium(III) halide having a pH of 3.0 to 5.8.

  本发明揭示了一种用于发展静电潜影像的调色剂，其中包含一种三价铬盐的电荷控制剂，该三价铬盐为水杨酸或其衍生物的三价铬盐，其表示为以下通式； 其中，R1、R2和R3分别表示氢原子、饱和或不饱和的直链或支链烷基，或者当它们一起取时，R1和R2或R2和R3形成一个融合环，该融合环可以选择性地具有饱和或不饱和的直链或支链烷基，n表示0、1或2。这些三价铬盐是通过将水杨酸或其衍生物的碱金属盐的pH为6.5至小于7.0的水溶液加入pH为3.0至5.8的三价铬卤化物的水溶液中形成的。
• Compound for organic optoelectric device, composition for organic optoelectric device and organic optoelectric device and display device
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10032999B2

  公开（公告）日：2018-07-24

  Disclosed are a compound for an organic optoelectric device represented by Chemical Formula 1, a composition for an organic optoelectric device, an organic optoelectric device including the same, and a display device. Details of Chemical Formula 1 are the same as those defined in the specification.

  本发明公开了一种由化学式 1 表示的有机光电器件用化合物、一种有机光电器件用组合物、一种包括该化合物的有机光电器件以及一种显示装置。化学式 1 的详细信息与说明书中定义的相同。
• Toner for developing electrostatic latent image and charge control agent for use in the toner
  申请人：TOYO INK MANUFACTURING CO., LTD.

  公开号：EP1225165B1

  公开（公告）日：2005-01-19
• RESIST UNDERLAYER FILM FORMING COMPOSITION AND METHOD FOR FORMING RESIST PATTERN USING THE SAME
  申请人：Ohnishi Ryuji

  公开号：US20140004465A1

  公开（公告）日：2014-01-02

  A resist underlayer film forming composition for lithography, includes: a polymer including a structure of formula (1) below at a terminal of a polymer chain; a cross-linking agent; a compound that promotes a cross-linking reaction; and an organic solvent: (where R 1 , R 2 , and R 3 are each independently a hydrogen atom, a linear or branched hydrocarbon group having a carbon atom number of 1 to 13, or a hydroxy group; at least one of R 1 , R 2 , and R 3 is the hydrocarbon group; m and n are each independently 0 or 1; and a main chain of the polymer is bonded to a methylene group when n is 1 and bonded to a group represented by —O— when n is 0).