1-(3-Phenyl-3-butenyl)pyrrolidine | 37918-82-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(3-Phenyl-3-butenyl)pyrrolidine
• 英文别名: 1-(3-phenylbut-3-en-1-yl)pyrrolidine；1-(3-phenyl-but-3-enyl)-pyrrolidine；1-(3-Phenyl-but-3-enyl)-pyrrolidin；1-(3-Phenylbut-3-enyl)pyrrolidine
• CAS: 37918-82-4
• 化学式: C₁₄H₁₉N
• 分子量: 201.312
• InChiKey: TXZYZZMDWJYILU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(3-Phenyl-3-butenyl)pyrrolidine 在 乙醇 、 镍 作用下， 生成 1-(3-phenyl-butyl)-pyrrolidine
  参考文献：
  名称：

  The Reaction of Formaldehyde and Secondary Amines with Some Olefins

  摘要：

  DOI：

  10.1021/ja01622a057
• 作为产物：
  描述：

  1-methyl-4-((2-phenylallyl)sulfonyl)benzene 、 1-((trimethylsilyl)methyl)pyrrolidine 在 tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate 、 sodium acetate 作用下， 以 乙醇 为溶剂， 反应 4.0h， 以68%的产率得到1-(3-Phenyl-3-butenyl)pyrrolidine
  参考文献：
  名称：

  可见光光氧化还原促进α-甲硅烷基胺的脱甲硅烷基化烯丙基化：合成高烯丙基胺的有效途径

  摘要：

  描述了通过可见光光氧化还原促进 α-甲硅烷基胺与烯丙基砜的去甲硅烷基化烯丙基化，轻松有效地合成高烯丙基胺。衍生自苯胺、环状和无环烷基胺的各种α-甲硅烷基胺与一系列单或二取代的烯丙基砜很好地反应，在非常温和的反应条件下以良好到高产率提供均烯丙基胺。

  DOI：

  10.1016/j.tetlet.2021.153357

文献信息

• Functionalized monomers for synthesis of rubbery polymers
  申请人：——

  公开号：US20040063884A1

  公开（公告）日：2004-04-01

  The present invention relates to a rubbery polymer which is comprised of repeat units that are derived from (1) at least one conjugated diolefin monomer, and (2) at least one functionalized monomer of the structural formula: 1 wherein the R′ groups in repeat units and in different repeat units can be the same or different and represent hydrogen atoms or alkyl groups containing from 1 to about 4 carbon atoms, wherein x represents an integer from 1 to about 10, and wherein the R groups in repeat units and in different repeat units can be the same or different and represent alkyl groups containing from 1 to about 10 carbon atoms or alkoxy groups containing from 1 to about 10 carbon atoms.

  本发明涉及一种橡胶聚合物，其由以下重复单元组成：（1）至少一种共轭二烯单体，和（2）至少一种结构式为的官能化单体，其中重复单元中的R′基和不同重复单元中的R′基可以相同或不同，代表氢原子或含有1至约4个碳原子的烷基基团，其中x代表从1到约10的整数，重复单元中的R基和不同重复单元中的R基可以相同或不同，代表含有1至约10个碳原子的烷基基团或含有1至约10个碳原子的烷氧基团。
• FUNCTIONALIZED MONOMERS FOR SYNTHESIS OF RUBBERY POLYMERS
  申请人：Halasa Farhan Adel

  公开号：US20050131181A1

  公开（公告）日：2005-06-16

  This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of wherein R and R′ can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural formula wherein R and R′ can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.

  本发明揭示了一种合成胺官能化单体的过程，其中包括（1）将二级胺与2,3-二卤代丙烯反应，以产生含有乙烯卤代基的二级胺，其结构式选自以下组中的一种：其中R和R'可以相同或不同，代表含有1至约10个碳原子的烯丙基，烷氧基或烷基基团，X代表卤素原子，m代表4至约10的整数，X代表卤素原子；以及（2）将含有乙烯卤代基的二级胺与乙烯基镁卤反应，以产生具有结构式的单体：其中R和R'可以相同或不同，代表含有1至约10个碳原子的烷基，烯丙基或烷氧基基团，m代表约4至约10的整数。
• Polymers, rubber compositions, and tires
  申请人：The Goodyear Tire & Rubber Company

  公开号：EP2196326A1

  公开（公告）日：2010-06-16

  The present invention relates to polymers, rubber compositions, and tires. The polymers comprise repeat units provided from at least one amine monomer. The amine monomer can be an amine styrene monomer. Examples of amine styrenes monomer are provided. The polymer can be made from the copolymerization of at least one amine monomer and at least one monomer that is used to make synthetic rubber, such as at least one conjugated diolefin monomer. These polymers can be terminated with a terminating group, including, for example, those having a hydrolyzable group. Rubber compositions can be made from the above-described polymers. Tires can be made from the polymers or from the rubber compositions.

  本发明涉及聚合物、橡胶组合物和轮胎。聚合物包括由至少一种胺单体提供的重复单元。胺单体可以是胺苯乙烯单体。本文提供了胺苯乙烯单体的实例。聚合物可由至少一种胺单体和至少一种用于制造合成橡胶的单体（如至少一种共轭二烯烃单体）共聚而成。这些聚合物可以用终止基团终止，例如包括具有可水解基团的聚合物。橡胶组合物可由上述聚合物制成。轮胎可由上述聚合物或橡胶组合物制成。
• Rubber composition, method of manufacturing a rubber composition and pneumatic tire with such a rubber composition
  申请人：The Goodyear Tire & Rubber Company

  公开号：EP2325027A1

  公开（公告）日：2011-05-25

  The present invention is directed to a rubber composition comprising, based on 100 parts by weight of elastomer (phr): (A) from 60 to 90 phr of a polymer comprising: (1) a terminating group provided from a terminating compound          XnSi(OR)mR'4-m-n wherein X is a chlorine atom, a bromine atom or an iodine atom, R is an alkyl group with from 1 carbon to 7 carbons, R' is a alkyl group with from 1 carbon to 20 carbons, an aryl group, a vinyl group or a halogenated alkyl group, m is an integer from 1 to 4, n is an integer from 0 to 2, and wherein the sum of n and m is from 1 to 4; (2) repeat units comprising: (a) a repeat unit provided from a conjugated diolefin monomer, and (b) a repeat unit provided from an amine monomer; (B) from 40 to 10 phr of polybutadiene having a microstructure comprising from 96 to 99 percent cis 1,4-isomeric units, from 0.1 to 1 percent trans 1,4-isomeric units and from 1 to 3 percent vinyl 1,2-isomeric units, and (C) from 50 to 150 phr of silica. It is also directed to a pneumatic tire with such a rubber composition.

  本发明涉及一种橡胶组合物，以 100 重量份的弹性体（phr）为基准，该组合物包括 (A) 60 至 90 phr 的聚合物，包括 (1) 由终止化合物提供的终止基团 XnSi(OR)mR'4-m-n 其中 X 是氯原子、溴原子或碘原子，R 是含 1 至 7 个碳原子的烷基，R'是含 1 至 20 个碳原子的烷基、芳基、乙烯基或卤代烷基，m 是 1 至 4 的整数，n 是 0 至 2 的整数，n 和 m 之和是 1 至 4； (2) 重复单元包括 (a) 由共轭二烯烃单体提供的重复单元，和 (b) 由胺单体提供的重复单元； (B) 40 至 10 phr 的聚丁二烯，其微结构包括 96%至 99%的顺式 1,4-异构单元、0.1%至 1%的反式 1,4-异构单元和 1%至 3%的乙烯基 1,2-异构单元，以及 (C) 50 至 150 phr 的二氧化硅。本发明还涉及使用这种橡胶组合物的充气轮胎。
• CONJUGATED-DIENE-BASED RUBBER
  申请人：Zeon Corporation

  公开号：EP3696204A1

  公开（公告）日：2020-08-19

  Provided is a conjugated diene-based rubber comprising a polymer block (A) containing isoprene monomer unit as the main component and a polymer block (B) containing 1,3-butadiene monomer unit as the main component, wherein at least one of the polymer block (A) and the polymer block (B) contains a unit of a vinyl compound having a functional group interactive with silica, the polymer block (A) has a weight average molecular weight (Mw) in the range of 1,000 to 30,000, and the entire conjugated diene-based rubber has a weight average molecular weight (Mw) in the range of 50,000 to 5,000,000.

  本发明提供了一种共轭二烯基橡胶，它由含有异戊二烯单体单元的聚合物嵌段（A）和含有1,3-丁二烯单体单元的聚合物嵌段（B）组成，其中聚合物嵌段（A）和聚合物嵌段（B）中至少有一个含有乙烯基化合物单元，该乙烯基化合物具有与二氧化硅相互作用的官能团、聚合物嵌段（A）的重量平均分子量（Mw）在 1,000 至 30,000 之间，整个共轭二烯基橡胶的重量平均分子量（Mw）在 50,000 至 5,000,000 之间。