N-phenyl-endo-bicyclo<2.2.1>hept-5-ene-2-carboxamide | 52889-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-phenyl-endo-bicyclo<2.2.1>hept-5-ene-2-carboxamide
• 英文别名: N-Phenylbicyclo[2.2.1]hept-5-ene-2-carboximidic acid；N-phenylbicyclo[2.2.1]hept-5-ene-2-carboxamide
• CAS: 52889-85-7
• 化学式: C₁₄H₁₅NO
• mdl: MFCD00988182
• 分子量: 213.279
• InChiKey: XGBHRXNRYYODNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.357
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-苯基丙烯酰胺 、 环戊二烯 在 2,6-二叔丁基-4-甲基苯酚 作用下， 以 甲苯 为溶剂， 反应 48.0h， 生成 N-phenyl-endo-bicyclo<2.2.1>hept-5-ene-2-carboxamide
  参考文献：
  名称：

  Design of chiral boronate-substituted acrylanilides.

  摘要：

  The [4 + 2] cycloaddition of ortho-boronoanilide dienophile 4 with cyclopentadiene was found to proceed faster than both its para isomer 8 and the unsubstituted derivative 6, thereby confirming that self-activation by internal coordination is operative in the case of 4. Chiral boronic esters derivatives 9-13 provided a small level of remote 1,8-stereoinduction transmitted through a putative tetrahedral stereogenic boronate complex. These results show that dialkoxyboronic esters can operate as weak, internal Lewis acids and activate carbonyl-containing functionalities in cycloaddition reactions. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00400-5

文献信息

• Visible Light-Promoted Goldberg Reaction Driven by a Preponderant Facet of CuO Nanocrystals
  作者：Ze Xu、Weiwei Wang、Yuanqing Xu、Shaojia Song、Jianghao Yu、Weiyu Song、Hao Xu、Hua Fu、Zhenxing Li

  DOI：10.1021/acscatal.3c03629

  日期：2023.11.3

  A visible light-promoted Goldberg reaction driven by a preponderant facet of CuO nanocrystals has been developed, making aryl halides even with electron-donating groups feasible. The mechanism investigations showed that this transformation’s absorption energy and reaction heat decreased obviously on the surface of CuO nanocrystals for the substantial influence of facet and morphology. Also, the CuO

  由 CuO 纳米晶体的优势面驱动的可见光促进的戈德堡反应已经被开发出来，使得芳基卤化物甚至具有给电子基团也是可行的。机理研究表明，由于晶面和形貌的显着影响，这种转变的吸收能和反应热在CuO纳米晶表面明显降低。此外，CuO 纳米板表现出比其他形态更高的氧化性。可见光激发的曙红 Y 通过单电子转移在有效催化循环中调节 CuO 纳米板的优选氧化态。基于光氧化还原和氧化铜纳米晶体催化的协同效应，最终完成了可见光戈德堡耦合。此外，利用该方法还合成了多种药物和农化分子。该工作揭示了纳米级氧化铜(II)材料在光氧化还原催化有机合成中的高反应活性和独特优势。
• Method for preparing modified resins and their applications
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0698620A1

  公开（公告）日：1996-02-28

  There are herein disclosed a method for preparing a modified resin which comprises thermal/reaction by the use of a norbornenyl group-containing compound typified by norbornenecarboguanamine or its derivative, a method for preparing an epoxy-modified resin which comprises the step of reacting the above-mentioned modified resin and an epoxide, a flame-retarding method, a thermal stabilization method, a compatibilizing method and a surface modification method which comprise utilizing the modified resin, as well as a coating resin composition and an adhesive resin composition containing the modified resin. According to the preparation methods of the present invention, the deterioration of a material scarcely occurs, and a functional group which is excellent in flame retardancy, thermal stability, compatibility and the like can be introduced to the resins. By the utilization of these techniques, there can be obtained a flame-retardant material having a good char formability, a thermally stable material whose molded articles can inhibit heat deterioration, a material excellent in miscibility between different kinds of resins, a surface-modified material which is excellent in adhesion and coating properties and the like.

  本发明公开了一种制备改性树脂的方法，该方法包括通过使用以降冰片烯碳胍胺或其衍生物为代表的含降冰片烯基化合物进行热/反应；一种制备环氧改性树脂的方法，该方法包括使上述改性树脂与环氧化物反应的步骤、包括利用改性树脂的阻燃方法、热稳定方法、相容方法和表面改性方法，以及含有改性树脂的涂料树脂组合物和粘合剂树脂组合物。 根据本发明的制备方法，材料几乎不会变质，而且可以在树脂中引入阻燃性、热稳定性、相容性等性能优异的官能团。利用这些技术，可以获得一种具有良好炭化成型性的阻燃材料、一种热稳定性材料（其成型制品可抑制热变质）、一种在不同种类树脂之间具有良好混溶性的材料、一种在粘附性和涂覆性等方面具有良好性能的表面改性材料。
• US4068063A
  申请人：——

  公开号：US4068063A

  公开（公告）日：1978-01-10
• US4176220A
  申请人：——

  公开号：US4176220A

  公开（公告）日：1979-11-27
• US5674947A
  申请人：——

  公开号：US5674947A

  公开（公告）日：1997-10-07