zinc meso-bipyridinium-β-octaethylporphyrin perchlorate | 174718-20-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: zinc meso-bipyridinium-β-octaethylporphyrin perchlorate
• 英文别名: zinc-10-[4,4'-bipyridinium-perchlorate]-porphyrinate；ZnOEP-meso-bpyClO4
• CAS: 174718-20-8
• 化学式: C₄₆H₅₁N₆Zn*ClO₄
• 分子量: 852.792
• InChiKey: IHZMGGBJGCZBRU-VBGSBRCQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc meso-bipyridinium-β-octaethylporphyrin perchlorate 以 1,2-二氯乙烷 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  A Polycationic Zinc-5,15-dichlorooctaethylporphyrinate-viologen Wire

  摘要：

  Electropolymerization of zinc-10-bipyridinium-octaethyl-porphyrinate by cyclic scanning between -0.6 and +1.6 V yields a zigzag configured polymer, which appears as swollen, vesicular bilayer on atomic force micrographs. The same procedure leads to micrometer-long wire-shaped linear polymers, if the 5,15-methine bridge carbon atoms are blocked by chlorine substituents. The wires come in two parallel strands originating from antiparallel face-to-face dimers in the solution.

  DOI：

  10.1021/ja984404r
• 作为产物：
  描述：

  4,4'-联吡啶 、 (2,3,7,8,12,13,17,18-octaethylporphyrinato)zinc(II) 以78%的产率得到zinc meso-bipyridinium-β-octaethylporphyrin perchlorate
  参考文献：
  名称：

  Electrosynthesis and Characterization of Symmetrical and Unsymmetrical Linear Porphyrin Dimers and Their Precursor Monomers

  摘要：

  The electrochemical synthesis of linear symmetrical octaethylporphyrin-octaethylporphyrin and unsymmetrical tetraphenylporphyrin-octaethylporphyrin dimeric porphyrins with one viologen as a spacer and of their precursor porphyrin monomers is reported. The mechanism of the electrochemical substitution leading to the dimeric porphyrins is discussed. These new compounds have been characterized by H-1 NMR, UV-vis spectroscopy, FAB mass spectroscopy, and microanalysis. Electrochemical data are reported, and the redox behavior is analyzed for the monomers and the dimers in terms of pi-pi interactions between the two porphyrin centers. ESR measurements were carried out on the unsymmetrical Cu-Zn and Cu-Cu dimeric metalloporphyrins which displayed intermolecular metal interactions.

  DOI：

  10.1021/ja9523956